Novel β-Benzyloxy-Substituted Copolymers of Seven-Membered Cyclic Carbonate: Ring-Opening Polymerization with L-Lactide, ε-Caprolactone and Trimethylenecarbonate DOI Open Access
Valeriia A. Serova, Badma N. Mankaev,

Milana U. Agaeva

et al.

Polymers, Journal Year: 2024, Volume and Issue: 16(23), P. 3364 - 3364

Published: Nov. 29, 2024

To prepare novel biodegradable copolymers with functional substituents that are distributed statistically or randomly over the macromolecule chain and have improved characteristics compared to homopolymers, we conducted a series of synthetic experiments cyclic monomer, 5-(benzyloxy)-1,3-dioxepan-2-one (

Language: Английский

Ionic quaternary ammonium-triazole polymers as efficient single-component catalysts for CO2 conversion DOI Creative Commons

Pobporn Promchan,

Atthapon Srifa, Bunyarat Rungtaweevoranit

et al.

Journal of CO2 Utilization, Journal Year: 2024, Volume and Issue: 90, P. 102989 - 102989

Published: Dec. 1, 2024

Language: Английский

Citations

2
Facile synthesis of polycarbonates from biomass-based eugenol: catalyst optimization for selective copolymerization of CO2 and eugenol to achieve polycarbonates DOI Creative Commons

Mani Sengoden,

Gulzar A. Bhat,

Tristan Roland

et al.

RSC Sustainability, Journal Year: 2024, Volume and Issue: 2(5), P. 1431 - 1443

Published: Jan. 1, 2024

A series of Co( iii ) and Cr( )(salen) complexes in the presence onium salts have been examined for coupling CO 2 biomass based eugenol epoxide selective production polycarbonates a partially sustainable process.

Language: Английский

Citations

1
Ionic Liquid Catalysis in Cyclic Carbonate Synthesis for the Development of Soybean Oil-Based Non-Isocyanate Polyurethane Foams DOI Creative Commons
Damian Kiełkiewicz, Agnieszka Siewniak, Rafał Gaida

et al.

Molecules, Journal Year: 2024, Volume and Issue: 29(16), P. 3908 - 3908

Published: Aug. 18, 2024

A method for obtaining non-isocyanate polyurethane (NIPU) foams from cyclic carbonate (CC) based on soybean oil was developed. For this purpose, synthesized epoxidized and CO

Language: Английский

Citations

1
Heterogeneous Catalysis for Aerobic Oxidation of 5‐Hydroxymethylfurfural to 2,5‐Furandicarboxylic Acid Under Base‐Free Conditions DOI Open Access
Zheng-Zheng Meng, Shanshan Chen, Hongru Li

et al.

ChemCatChem, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 8, 2024

Abstract 2,5‐Furandicarboxylic acid (FDCA) is a biomass‐derived monomer for the production of poly(ethylene 2,5‐furandicarboxylate) (PEF), which novel polyester that can serve as sustainable alternative to traditional petroleum‐based terephthalate) (PET). Currently, industrial FDCA depends on thermo catalytic aerobic oxidation 5‐hydroxymethylfurfural (HMF) using heterogeneous catalysts in aqueous solution, process equivalent homogeneous bases are usually needed promote hydroxymethyl and aldehyde groups simultaneously improve solubility oxidative products via forming carboxylate. The involvement massive base causes risks equipment corrosion necessitates subsequent product separation purification with large amount acid. In this context, base‐free HMF has attracted much concern. Nowadays, by developing supported multiple sites, diluted substrate finding good solvent FDCA, progress been achieved field. This review provides state art catalysis under conditions, highlighting mechanism shed light catalyst design principles.

Language: Английский

Citations

1
Designing Nickel-based catalysts for the hydrogenation of CO2 under Ambient conditions: A computational study DOI
Anupama Mahato,

Akhilesh Mahato,

Purnima Singh

et al.

Molecular Catalysis, Journal Year: 2024, Volume and Issue: 559, P. 114089 - 114089

Published: April 1, 2024

Language: Английский

Citations

0
Emerging Trends in Nonisocyanate Polyurethane Foams: A Review DOI Creative Commons

Chen Chuan Lim,

Michelle Jui Hsien Ong,

Mingyue Wu

et al.

ACS Engineering Au, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 31, 2024

Polyurethane foams (PUF) are essential materials known for their exceptional chemical and mechanical properties, making them ubiquitous in a wide range of applications. Conventionally, PUF produced through polyaddition reactions between polyols polyisocyanates at room temperature, where water plays critical role this process by hydrolyzing the isocyanates, leading to release carbon dioxide (CO2) as blowing agent. In recent years, isocyanates have raised significant concerns industries consumers due high toxicity. Therefore, driving need explore alternative synthesis routes that do not involve use isocyanates. Nonisocyanate polyurethane (NIPUF) derived from aminolysis cyclic carbonates emerged most promising solution replace conventional method producing PUF. Despite this, challenging aspect lies identifying suitable foaming strategy NIPUF can satisfy both sustainability performance requirements. view first part review focuses on background, chemistry, challenges second part, chemistry various strategies used prepare discussed analyzed. Finally, outlook future research focus areas outlined.

Language: Английский

Citations

0
Novel β-Benzyloxy-Substituted Copolymers of Seven-Membered Cyclic Carbonate: Ring-Opening Polymerization with L-Lactide, ε-Caprolactone and Trimethylenecarbonate DOI Open Access
Valeriia A. Serova, Badma N. Mankaev,

Milana U. Agaeva

et al.

Polymers, Journal Year: 2024, Volume and Issue: 16(23), P. 3364 - 3364

Published: Nov. 29, 2024

To prepare novel biodegradable copolymers with functional substituents that are distributed statistically or randomly over the macromolecule chain and have improved characteristics compared to homopolymers, we conducted a series of synthetic experiments cyclic monomer, 5-(benzyloxy)-1,3-dioxepan-2-one (

Language: Английский

Citations

0