Difunctionalization of Alkenes toward 3,3-Disubstituted and Dihydrobenzoindolines by Using an Imidazolylidene Palladacyclic Catalyst DOI

Dong Lin,

Hanxiao Yang,

Yue Chen

et al.

The Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: March 6, 2025

The synthesis of valuable 2a,3-dihydrobenzo[cd]indolines was successfully achieved by combining IPr-Pdcycle-OxaNaphthyl-catalyzed cross-coupling and proton-induced hydroarylation in a one-pot method. In situ-generated alkynyl-functionalized 3,3-disubstituted indolines were proved as the key intermediate, bearing broad scope substrates with diverse functional groups electronic properties.

Language: Английский

Recent advances on electrochemical generation of sulfonyl radical triggered cyclization of alkene/alkynes DOI

Jiaqing Shao,

Jiang Liu, Haibo Mei

et al.

Tetrahedron, Journal Year: 2025, Volume and Issue: 173, P. 134467 - 134467

Published: Jan. 12, 2025

Language: Английский

Citations

1
Difunctionalization of Alkenes toward 3,3-Disubstituted and Dihydrobenzoindolines by Using an Imidazolylidene Palladacyclic Catalyst DOI

Dong Lin,

Hanxiao Yang,

Yue Chen

et al.

The Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: March 6, 2025

The synthesis of valuable 2a,3-dihydrobenzo[cd]indolines was successfully achieved by combining IPr-Pdcycle-OxaNaphthyl-catalyzed cross-coupling and proton-induced hydroarylation in a one-pot method. In situ-generated alkynyl-functionalized 3,3-disubstituted indolines were proved as the key intermediate, bearing broad scope substrates with diverse functional groups electronic properties.

Language: Английский

Citations

0