Bifunctionalization of α-Bromophenone: An Access to Functionalized β-Keto Thiosulfones DOI

Xiaoqing Wen,

Mengxin Li, Xiaoyan Peng

et al.

The Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 12, 2024

A simple and high-yielding strategy to produce a variety of β-keto sulfides using asymmetrical symmetrical thiosulfonates with ketones under mild conditions is reported. It was found that the various substituted compounds, both electron-withdrawing electron-donating substituents, afforded wide range thiosulfones (α-thioaryl-β-keto sulfones) in moderate high yields. The transformations were reliable at gram-scale, thus illustrating their efficiency practicality. plausible mechanism for protocol also proposed.

Language: Английский

Synthetic application of oxalate salts for visible-light-induced radical transformations DOI

Hui-Xian Jiang,

Zhitao Liu, Pei Xu

et al.

Chinese Chemical Letters, Journal Year: 2025, Volume and Issue: unknown, P. 111224 - 111224

Published: April 1, 2025

Language: Английский

Citations

0
Bifunctionalization of α-Bromophenone: An Access to Functionalized β-Keto Thiosulfones DOI

Xiaoqing Wen,

Mengxin Li, Xiaoyan Peng

et al.

The Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 12, 2024

A simple and high-yielding strategy to produce a variety of β-keto sulfides using asymmetrical symmetrical thiosulfonates with ketones under mild conditions is reported. It was found that the various substituted compounds, both electron-withdrawing electron-donating substituents, afforded wide range thiosulfones (α-thioaryl-β-keto sulfones) in moderate high yields. The transformations were reliable at gram-scale, thus illustrating their efficiency practicality. plausible mechanism for protocol also proposed.

Language: Английский

Citations

0