ChemistrySelect,
Journal Year:
2025,
Volume and Issue:
10(3)
Published: Jan. 1, 2025
Abstract
This
work
presents
the
facile
synthesis
of
Ag
nanoparticles‐decorated
porous
crystalline
covalent
organic
frameworks
(namely,
Ag@TPT‐TP
COF)
having
exceptional
surface
area
and
CO
2
uptake
capacity
to
facilitate
‐cyclization
reactions
produce
highly
value‐added
compounds.
Several
characterization
techniques
have
been
used
thoroughly
analyze
as‐synthesized
nanomaterial,
COF.
The
synthesized
NPs‐embedded
2D
COF
serves
as
a
stable
active
catalyst
for
cyclic
carbonates
from
variety
epoxides
derivatives
2‐oxazolidinone
propargyl
alcohols
amines
with
high
yield
selectivity
corresponding
products
via
fixation
(1
atm)
under
sustainable
reaction
conditions.
functionalized
(Ag@TPT‐TP
exhibited
recyclability
both
up
six
consecutive
runs
without
any
visible
deterioration
in
catalytic
activity.
Consequently,
formation
wide
range
compounds
are
dramatically
expanded
by
these
transformations
provide
possible
pathway
functionalization
get
beyond
energy
barrier
this
area.
Chemical Society Reviews,
Journal Year:
2023,
Volume and Issue:
52(5), P. 1773 - 1946
Published: Jan. 1, 2023
This
review
summarizes
the
use
of
zeolites
and
ordered
mesoporous
silica-based
catalysts,
development
new
processes
technologies
to
boost
conversion
CO
2
into
chemicals
fuels.
Angewandte Chemie International Edition,
Journal Year:
2022,
Volume and Issue:
61(22)
Published: March 10, 2022
Abstract
Carbon
dioxide
is
a
renewable,
inexhaustible,
and
cheap
alternative
to
fossil
resources
for
the
production
of
fine
chemicals
plastics.
It
can
notably
be
converted
into
exovinylene
cyclic
carbonates,
unique
synthons
gaining
momentum
preparation
an
impressive
range
important
organic
molecules
functional
polymers,
in
reactions
proceeding
with
100
%
atom
economy
under
mild
operating
conditions
most
cases.
This
Review
summarizes
recent
advances
their
synthesis
particular
attention
on
describing
catalysts
needed
discussing
reactivity
these
CO
2
‐based
heterocycles
construction
diverse
building
blocks
(functional)
polymers.
We
also
discuss
challenges
future
perspectives
field.
ACS Applied Nano Materials,
Journal Year:
2021,
Volume and Issue:
4(8), P. 7663 - 7674
Published: July 28, 2021
Covalent
organic
frameworks
(COFs)
have
been
gaining
substantial
attention
over
the
past
decade
due
to
their
developing
crystalline
porous
polymeric
nature
linked
by
strong
covalent
bonds
and
widespread
applications
in
various
fields.
Currently,
three-dimensional
COFs
(3D
COFs)
are
engaging
spotlight
distinctive
features,
greater
surface
area,
exceptional
performances
comparison
with
formerly
published
two-dimensional
(2D)
AA-stacking
layered
mode.
In
this
paper,
we
present,
for
first
time,
a
nanoporous
3D-COF-based
zinc(II)
catalyst
(Zn@RIO-1),
which
shows
an
efficient
pathway
chemical
conversion
of
carbon
dioxide
produce
α-alkylidene
cyclic
carbonates
oxazolidinones
from
propargylic
alcohols.
The
microporous
material
high
area
(312.61
m2/g)
facilitates
both
types
catalytic
reactions
under
atmospheric
CO2
pressure.
More
importantly,
easily
recyclable
reusable
catalysts
produced
moderate
yields
desired
as
well
oxazolidinone
products
solvent-free
conditions.
This
study
emphasizes
capability
catalysis
field,
more
specifically
field
capture
fixation
fine
chemicals.
These
results
pave
spectacular
into
alcohols
using
3D-COF
potential
heterogeneous
ligand
sustainable
conditions
(i.e.,
solvent-free).
Materials Advances,
Journal Year:
2022,
Volume and Issue:
3(22), P. 8063 - 8080
Published: Jan. 1, 2022
The
review
provides
a
concise
report
on
various
types
of
COFs,
current
trends,
their
application
in
CO
2
reduction
via
photochemical,
electrochemical
and
photo
coupled
pathways.
Organic & Biomolecular Chemistry,
Journal Year:
2022,
Volume and Issue:
20(8), P. 1707 - 1722
Published: Jan. 1, 2022
This
study
emphasizes
the
utility
of
a
Zn(
ii
)-functionalized
COF
in
developing
heterogeneous
recyclable
catalytic
system
for
generation
cyclic
carbonates
(up
to
99%
yield)
and
carbamates
94%
under
sustainable
conditions.
Angewandte Chemie International Edition,
Journal Year:
2023,
Volume and Issue:
63(5)
Published: Dec. 13, 2023
Covalent
organic
frameworks
(COFs)
have
been
utilized
for
catalyzing
the
reduction
of
carbon
dioxide
(CO2RR)
due
to
their
atomic
metal
centers
and
controllable
pore
channels,
which
are
facilitated
by
different
covalent
bonds.
However,
exploration
boron-based
linkages
in
these
catalytic
COFs
has
limited
owing
potential
instability.
Herein,
we
present
construction
boronic
ester-linked
through
nucleophilic
substitution
reactions
order
catalyze
CO
