Conceptual Process Design, Techno-Economics, and Greenhouse Gas Analysis of Furfuryl Alcohol Production via Transfer Hydrogenation DOI
Gabriel Fraga, Jerome Ramirez, Marguerite Renouf

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2024, Volume and Issue: 12(28), P. 10604 - 10614

Published: June 28, 2024

Catalytic transfer hydrogenation (CTH) has gained attention as a potentially more sustainable process than conventional with H 2 gas.In this process, hydrogen is supplied in situ from donor molecule without the need for high-pressure .We developed conceptual commercial of furfural into furfuryl alcohol and performed techno-economic greenhouse gas analyses aiming to identify bottlenecks guide future research field.Two compounds were considered: isopropanol ethanol.Total capital investment varies between US$24.8-33.3 million these processes, minimum selling price (MSP) below market US$1.52/kgonly ethanol donor.The main impact on profitability dehydrogenated co-product.Thus, low-cost donors that generate high-value dehydrogenation products are required be competitive hydrogenation.In addition, utilizing comes free embodied and/or avoids GHG release CTH have lower emissions intensity hydrogenation.

Language: Английский

Morphology-Engineered Porous Flower-Like Coni-Ldo with Oxygen Vacancies for the Production of Aromatic Amines Through Waste H2s DOI
Weiping Jiang, Rui Huang, Xiaohai Zheng

et al.

Published: Jan. 1, 2025

Language: Английский

Citations

0
Continuous flow synthesis of aldol condensation products from furfural using ternary hydrotalcites: Catalytic efficiency and selectivity DOI

Eliana Nope,

Ángel G. Sathicq, José J. Martínez

et al.

Materials Today Chemistry, Journal Year: 2025, Volume and Issue: 44, P. 102598 - 102598

Published: Feb. 20, 2025

Language: Английский

Citations

0
Morphology-engineered porous flower-like CoNi-LDO with oxygen vacancies for the production of aromatic amines through waste H2S DOI

Weiping Jiang,

Rui Huang, Xiaohai Zheng

et al.

Journal of Hazardous Materials, Journal Year: 2025, Volume and Issue: unknown, P. 138120 - 138120

Published: April 1, 2025

Language: Английский

Citations

0
In situ hydroprocessing of lignocellulosic biomass-derived molecules into fuels and chemicals using heterogeneous catalysts DOI

Palanivel Subha,

Kumar Krishan,

Putla Sudarsanam

et al.

Sustainable Energy & Fuels, Journal Year: 2024, Volume and Issue: 8(17), P. 3775 - 3800

Published: Jan. 1, 2024

The in situ hydrogenation of lignocellulosic biomass and its derivatives using liquid hydrogen carriers heterogeneous catalysts provides greener sustainable methodologies for producing biofuels chemicals.

Language: Английский

Citations

1
Conceptual Process Design, Techno-Economics, and Greenhouse Gas Analysis of Furfuryl Alcohol Production via Transfer Hydrogenation DOI
Gabriel Fraga, Jerome Ramirez, Marguerite Renouf

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2024, Volume and Issue: 12(28), P. 10604 - 10614

Published: June 28, 2024

Catalytic transfer hydrogenation (CTH) has gained attention as a potentially more sustainable process than conventional with H 2 gas.In this process, hydrogen is supplied in situ from donor molecule without the need for high-pressure .We developed conceptual commercial of furfural into furfuryl alcohol and performed techno-economic greenhouse gas analyses aiming to identify bottlenecks guide future research field.Two compounds were considered: isopropanol ethanol.Total capital investment varies between US$24.8-33.3 million these processes, minimum selling price (MSP) below market US$1.52/kgonly ethanol donor.The main impact on profitability dehydrogenated co-product.Thus, low-cost donors that generate high-value dehydrogenation products are required be competitive hydrogenation.In addition, utilizing comes free embodied and/or avoids GHG release CTH have lower emissions intensity hydrogenation.

Language: Английский

Citations

0