Benzylic C–H Oxidation: Recent Advances and Applications in Heterocyclic Synthesis DOI Creative Commons

Nonhlelo Majola,

Vineet Jeena

Molecules, Journal Year: 2024, Volume and Issue: 29(24), P. 6047 - 6047

Published: Dec. 22, 2024

Benzylic C–H oxidation to form carbonyl compounds, such as ketones, is a fundamental transformation in organic synthesis it allows for the preparation of versatile intermediates. In this review, we highlight aromatic ketones via catalytic, electrochemical, and photochemical alkylarenes using different catalysts oxidants past 5 years. Additionally, also discuss heterocyclic molecules benzylic key step. These methods can potentially be used medicinal, synthetic, inorganic chemistry.

Language: Английский

Development and prospects of covalent organic framework-based ratiometric fluorescent sensors DOI
Yinsheng Liu, Rui Xue, Bing Yan

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 523, P. 216280 - 216280

Published: Oct. 19, 2024

Language: Английский

Citations

11
KBr-Mediated Electrochemical Dihydroxylation of Alkenes Using H2O as the Hydroxyl Source DOI

Tao Pan,

Zhichao Shao,

Meng Xue

et al.

Organic Letters, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 4, 2024

Dihydroxylation of alkenes provides direct access to vicinal diols. Herein, a new electrochemical strategy for dihydroxylation in only the presence KBr is disclosed. Water serves as green and sustainable hydroxyl source. Cheap acts both an electrolyte catalyst. Both styrenes unactivated proceed reactions smoothly furnish diols good yields. The successful synthesis Cyclandelate, DTD derivative precursors, key intermediate herbicide Metamitron highlights its synthetic utility.

Language: Английский

Citations

1
Benzylic C–H Oxidation: Recent Advances and Applications in Heterocyclic Synthesis DOI Creative Commons

Nonhlelo Majola,

Vineet Jeena

Molecules, Journal Year: 2024, Volume and Issue: 29(24), P. 6047 - 6047

Published: Dec. 22, 2024

Benzylic C–H oxidation to form carbonyl compounds, such as ketones, is a fundamental transformation in organic synthesis it allows for the preparation of versatile intermediates. In this review, we highlight aromatic ketones via catalytic, electrochemical, and photochemical alkylarenes using different catalysts oxidants past 5 years. Additionally, also discuss heterocyclic molecules benzylic key step. These methods can potentially be used medicinal, synthetic, inorganic chemistry.

Language: Английский

Citations

0