A Rare Case of Magnesium Alkyl Mediated CO‐to‐Alkoxide Conversion DOI Creative Commons
Oliver P. E. Townrow,

Tim Richter,

Jens Langer

et al.

Chemistry - A European Journal, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 7, 2024

Alcohols can be produced by nucleophilic addition at the C=O functional group of ketones or aldehydes. Such C-C bond formations generally proceed smoothly and selective. In contrast, carbon monoxide is considerably more complex unselective due to instability polar metal acyl intermediates. Herein, we report a magnesium alkyl complex, stabilised with dipyrromethenide ligand, its reactivity CO

Language: Английский

A Rare Case of Magnesium Alkyl Mediated CO‐to‐Alkoxide Conversion DOI Creative Commons
Oliver P. E. Townrow,

Tim Richter,

Jens Langer

et al.

Chemistry - A European Journal, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 7, 2024

Alcohols can be produced by nucleophilic addition at the C=O functional group of ketones or aldehydes. Such C-C bond formations generally proceed smoothly and selective. In contrast, carbon monoxide is considerably more complex unselective due to instability polar metal acyl intermediates. Herein, we report a magnesium alkyl complex, stabilised with dipyrromethenide ligand, its reactivity CO

Language: Английский

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