Stable RuIr Nanoalloy Catalyst for Levulinic Acid Hydrogenation Reaction DOI Creative Commons
Jingru Wang, Xianshu Dong,

Yuping Fan

et al.

Molecules, Journal Year: 2024, Volume and Issue: 30(1), P. 93 - 93

Published: Dec. 29, 2024

Hydrogenation of levulinic acid (LA) represents a significant approach for producing the high-value biomass-based platform compound γ-valerolactone (GVL). In this study, an efficient RuIr alloy bimetallic catalyst supported on SiC was synthesized and applied aqueous hydrogenation LA into GVL under mild conditions. The RuIr/SiC exhibited high conversion selectivity (both > 99%) in water at 0.2 MPa H2 pressure 25 °C. excellent performance is attributed to synergistic interaction between Ru Ir nanoparticles semiconducting support. Furthermore, catalytic activity remained basically unchanged after five cycles, confirming stability catalyst.

Language: Английский

A Comprehensive Review of the Impact of Nano-Catalysts on Biodiesel Production DOI
Christopher Selvam Damian,

Yuvarajan Devarajan

Journal of Biosystems Engineering, Journal Year: 2024, Volume and Issue: 49(3), P. 277 - 290

Published: Sept. 1, 2024

Language: Английский

Citations

4
Efficient and Stable Synthesis of Butyrolactone from Biomass Derived 1,4‐ButaneDiol Dehydrogenation over Cu Supported on MgAl2O4 with Textural Properties DOI

Manne Parusha Ramudu,

T. Jagadish,

K. Eshwari

et al.

ChemistrySelect, Journal Year: 2025, Volume and Issue: 10(7)

Published: Feb. 1, 2025

Abstract Copper based catalysts have gained significant attention due to the exceptional reactivity of Cu species in breaking OH and C─H bonds through oxidation, as well their cost‐effectiveness. Herein, a series Cu‐based MgAl 2 O 4 with high dispersed spinel oxide particles were synthesized by impregnation method tested for catalytic dehydrogenation 1,4‐Butanediol gamma butyrolactone. The 15 confirmed highest activity maximum stability among all catalysts. Under moderate reaction conditions, conversion 98% butyrolactone selectivity 99% achieved on XRD, H ‐TPR, TPD, BET, FT‐IR, N pulse characterization exposed that catalyst prepared could be ascribed smallest particle size, dispersion, proper surface acid‐base sites weak metal‐support interaction, leading performance.

Language: Английский

Citations

0
NiO‐CuO Nanoplates as Recyclable and Effective Catalyst for Simple One‐Pot Synthesis of Spiro Dibenzo[1,4]Diazepine/Oxazepine Scaffolds via Multicomponent Strategy DOI
Soumitra Rana, Aswini Bera, Uday Shee

et al.

ChemistrySelect, Journal Year: 2025, Volume and Issue: 10(16)

Published: April 1, 2025

Abstract We developed an eco‐friendly one‐pot method using synthesized NiO‐CuO nanoplates to generate seven‐membered Spiro dibenzo[1,4]diazepine and oxazepine moieties. This three‐component reaction (isatin, 1,2‐phenylenediamine, cyclohexane‐1,3‐dione) proceeds via enamine–imine formation intramolecular Mannich with water elimination. enabled the of C─O C─N bonds, yielding highly substituted Dibenzodiazepine Dibenzoxazepine derivatives, along spiro benzodiazepine/oxazepine‐oxindoles containing a quaternary stereogenic center. The use recyclable nanocatalyst in ethanol‐based system ensures protocol that is both sustainable environmentally friendly. were extensively characterized powder XRD, HRTEM, EDX, BET, TGA ICPMS. approach benefits from easily accessible starting materials cooperative synergistic interaction bimetallic oxide nanocatalyst, operating under mild conditions. Leaching tests confirmed its heterogeneous nature catalyst was reused for eight cycles. accommodates broad range substrates, demonstrating versatility supported catalyst.

Language: Английский

Citations

0
Construction of bimetallic CuMn catalysts supported on ordered mesoporous Al2O3-CeO2 for high-efficient synthesis of furfuryl alcohol from furfural DOI
Qian Meng,

Cong Liu,

Xueting Yu

et al.

Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: 1008, P. 176499 - 176499

Published: Sept. 17, 2024

Language: Английский

Citations

3
Optimization, dielectric properties, and antibacterial efficacy of copper-grafted MgO nanoparticles synthesized via sol-gel method DOI

Habiba Kadhim Aity,

E. Dhahri, Mohammed Rasheed

et al.

Ceramics International, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 1, 2024

Language: Английский

Citations

1
Stable RuIr Nanoalloy Catalyst for Levulinic Acid Hydrogenation Reaction DOI Creative Commons
Jingru Wang, Xianshu Dong,

Yuping Fan

et al.

Molecules, Journal Year: 2024, Volume and Issue: 30(1), P. 93 - 93

Published: Dec. 29, 2024

Hydrogenation of levulinic acid (LA) represents a significant approach for producing the high-value biomass-based platform compound γ-valerolactone (GVL). In this study, an efficient RuIr alloy bimetallic catalyst supported on SiC was synthesized and applied aqueous hydrogenation LA into GVL under mild conditions. The RuIr/SiC exhibited high conversion selectivity (both > 99%) in water at 0.2 MPa H2 pressure 25 °C. excellent performance is attributed to synergistic interaction between Ru Ir nanoparticles semiconducting support. Furthermore, catalytic activity remained basically unchanged after five cycles, confirming stability catalyst.

Language: Английский

Citations

0