Journal of Energy Chemistry, Journal Year: 2024, Volume and Issue: 98, P. 562 - 587
Published: July 19, 2024
Language: Английский
Journal of Energy Chemistry, Journal Year: 2024, Volume and Issue: 98, P. 562 - 587
Published: July 19, 2024
Language: Английский
Advanced Materials, Journal Year: 2024, Volume and Issue: 36(25)
Published: March 16, 2024
Tunnel-type vanadium oxides are promising cathodes for aqueous zinc ion batteries. However, unlike layer-type with adjustable layer distances, enhancing ion-transport kinetics in tunnels characterized by fixed sizes poses a considerable challenge. This study highlights that the macroscopic arrangement of electrode crucially determines tunnel orientation, thereby influencing transport. By changing material morphology, orientation can be optimized to facilitate rapid diffusion. In proof-of-concept demonstration, it is revealed (00l) facets-dominated VO
Language: Английский
Citations
48Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 485, P. 150077 - 150077
Published: Feb. 29, 2024
Language: Английский
Citations
37Energy storage materials, Journal Year: 2024, Volume and Issue: 67, P. 103300 - 103300
Published: March 1, 2024
Language: Английский
Citations
36Journal of Power Sources, Journal Year: 2024, Volume and Issue: 599, P. 234215 - 234215
Published: Feb. 20, 2024
Language: Английский
Citations
25Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(20), P. 11867 - 11874
Published: Jan. 1, 2024
An organic indanthrone molecule realizes alternate Zn 2+ /CF 3 SO − ion storage involving multi-electron transfer at bipolar-type redox-active centers, providing high capacity, high-voltage durability and energy density for dual-ion batteries.
Language: Английский
Citations
25Advanced Materials, Journal Year: 2024, Volume and Issue: 36(18)
Published: Feb. 2, 2024
Abstract Layered materials are characterized by strong in‐plane covalent chemical bonds within each atomic layer and weak out‐of‐plane van der Waals (vdW) interactions between adjacent layers. The non‐bonding nature neighboring layers naturally results in a vdW gap, which enables the insertion of guest species into interlayer gap. Rational design regulation nanochannels crucial for converting these layered their 2D derivatives ion separation membranes or battery electrodes. Herein, based on latest progress derivative nanosheets, various engineering methods briefly introduced, along with effects intercalated crystal structure coupling host materials. Their applications energy storage fields then summarized, focus to improve selective transport performance. Finally, future research opportunities challenges this emerging field comprehensively discussed.
Language: Английский
Citations
24Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 671, P. 601 - 610
Published: May 28, 2024
Language: Английский
Citations
18Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(11)
Published: Jan. 17, 2024
Abstract The utilization rate of active sites in cathode materials for Zn‐based batteries is a key factor determining the reversible capacities. However, long‐neglected issue strong electrostatic repulsions among divalent Zn 2+ hosts inevitably causes squander some (i.e., gap sites). Herein, we address this conundrum by unraveling “gap‐filling” mechanism multiple charge carriers aqueous Zn‐MoS 2 batteries. tailored MoS /(reduced graphene quantum dots) hybrid features an ultra‐large interlayer spacing (2.34 nm), superior electrical conductivity/hydrophilicity, and robust layered structure, demonstrating highly NH 4 + /Zn /H co‐insertion/extraction chemistry 1 M ZnSO +0.5 (NH ) SO electrolyte. H ions can act as fillers to fully utilize screen interactions accelerate diffusion. Thus, unprecedentedly high capability (439.5 104.3 mAh g −1 at 0.1 30 A , respectively) ultra‐long cycling life (8000 cycles) are achieved.
Language: Английский
Citations
17ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 12, 2025
Improving electrical conductivity and increasing the active site are important directions for improving technology of manganese-based cathode materials zinc ion batteries (ZIBs). In this paper, cobalt-doped oxygen-vacancy coupled MnO2 nanorods (Vo-CMO) were prepared by defect engineering an doping strategy as rechargeable ZIBs. Oxygen vacancies can increase density material provide more migration paths ions, thereby electrochemical activity specific capacity. The introduction cobalt adjust electronic structure manganese oxide, change Fermi level material, promote generation transmission charge carriers, transfer rate material. synergistic effect among them improve diffusion kinetics capacity cycle stability Vo-CMO has better Zn2+ storage 295.6 mAh·g–1 at 0.1 A·g–1. reaction mechanism was H+/Zn2+ coinsertion through galvanostatic current intermittent titration (GITT) ex situ experiments. addition, assembled flexible quasi-solid ZIB. oxygen vacancy a new way to develop water-based
Language: Английский
Citations
2Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 16, 2025
Abstract The wide band gap of δ‐MnO 2 and the restricted regulation p‐band center ( p ) active oxygen atoms hinder electron conduction ion diffusion during zinc storage. Heteroatom doping has proven effective in improving However, solely through cation is comparatively constrained. Herein, a cation/anion co‐doping strategy proposed to simultaneously adjust d‐band d Mn by establishing Mn–O–Ca Mn─N bonds Ca/N co‐doped (Ca/N‐MnO ). This effect induces shift predominant stretching vibration mode Mn─O [MnO 6 ] octahedra, resulting decreased d/p‐band proximity (Δ d‐p 1.688 eV (1.750 for Consequently, both adsorption capacity adsorption/desorption rates Zn 2+ /H + ions are enhanced. Theoretical calculations further reveal that significantly triggers optimization gap, migration energy barrier, energy. As result, Ca/N‐MnO achieves remarkable reversible 192.7 mAh g −1 at 1.0 A after 200 cycles exceptional rate performance. Furthermore, enhancement mechanisms thoroughly elucidated. synergistic offers significant potential efficient storage applications.
Language: Английский
Citations
2