Wearable flexible zinc-ion batteries based on electrospinning technology DOI
Tiantian Zhang, Jingge Ju, Zehao Zhang

et al.

Journal of Energy Chemistry, Journal Year: 2024, Volume and Issue: 98, P. 562 - 587

Published: July 19, 2024

Language: Английский

Tunnel‐Oriented VO2 (B) Cathode for High‐Rate Aqueous Zinc‐Ion Batteries DOI
Qian He, Tao Hu, Qiang Wu

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: 36(25)

Published: March 16, 2024

Tunnel-type vanadium oxides are promising cathodes for aqueous zinc ion batteries. However, unlike layer-type with adjustable layer distances, enhancing ion-transport kinetics in tunnels characterized by fixed sizes poses a considerable challenge. This study highlights that the macroscopic arrangement of electrode crucially determines tunnel orientation, thereby influencing transport. By changing material morphology, orientation can be optimized to facilitate rapid diffusion. In proof-of-concept demonstration, it is revealed (00l) facets-dominated VO

Language: Английский

Citations

48

Unlocking the critical role of Mg doping in α-MnO2 cathode for aqueous zinc ion batteries DOI

Qiongguang Li,

Cun Wang,

Yue Zhu

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 485, P. 150077 - 150077

Published: Feb. 29, 2024

Language: Английский

Citations

37

Carbon-based nanomaterials for stabilizing zinc metal anodes towards high-performance aqueous zinc-ion batteries DOI
Ying Li, Yafei Guo, Zhengxiao Li

et al.

Energy storage materials, Journal Year: 2024, Volume and Issue: 67, P. 103300 - 103300

Published: March 1, 2024

Language: Английский

Citations

36

Achieving high-capacity aqueous calcium-ion storage in amorphous manganese oxide nanospheres for calcium-ion asymmetric supercapacitors DOI
Dewei Wang,

Xinliang Han,

Xinyang Zhang

et al.

Journal of Power Sources, Journal Year: 2024, Volume and Issue: 599, P. 234215 - 234215

Published: Feb. 20, 2024

Language: Английский

Citations

25

Multi-electron bipolar-type organic molecules for high-capacity dual-ion zinc batteries DOI

Chengmin Hu,

Xiaozhe Yang,

Pingxuan Liu

et al.

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(20), P. 11867 - 11874

Published: Jan. 1, 2024

An organic indanthrone molecule realizes alternate Zn 2+ /CF 3 SO − ion storage involving multi-electron transfer at bipolar-type redox-active centers, providing high capacity, high-voltage durability and energy density for dual-ion batteries.

Language: Английский

Citations

25

Interlayer Engineering of Layered Materials for Efficient Ion Separation and Storage DOI
Jinlin Yang, Yu Zhang,

Yanzeng Ge

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: 36(18)

Published: Feb. 2, 2024

Abstract Layered materials are characterized by strong in‐plane covalent chemical bonds within each atomic layer and weak out‐of‐plane van der Waals (vdW) interactions between adjacent layers. The non‐bonding nature neighboring layers naturally results in a vdW gap, which enables the insertion of guest species into interlayer gap. Rational design regulation nanochannels crucial for converting these layered their 2D derivatives ion separation membranes or battery electrodes. Herein, based on latest progress derivative nanosheets, various engineering methods briefly introduced, along with effects intercalated crystal structure coupling host materials. Their applications energy storage fields then summarized, focus to improve selective transport performance. Finally, future research opportunities challenges this emerging field comprehensively discussed.

Language: Английский

Citations

24

Constructing hierarchical CuS hollow spheres as efficient anode for aqueous zinc-ion batteries DOI

Rongrong Mu,

Guoquan Suo,

Chuanjin Lin

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 671, P. 601 - 610

Published: May 28, 2024

Language: Английский

Citations

18

Unraveling the “Gap‐Filling” Mechanism of Multiple Charge Carriers in Aqueous Zn‐MoS2 Batteries DOI
Shengwei Li, Xudong Zhao, Tianhao Wang

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(11)

Published: Jan. 17, 2024

Abstract The utilization rate of active sites in cathode materials for Zn‐based batteries is a key factor determining the reversible capacities. However, long‐neglected issue strong electrostatic repulsions among divalent Zn 2+ hosts inevitably causes squander some (i.e., gap sites). Herein, we address this conundrum by unraveling “gap‐filling” mechanism multiple charge carriers aqueous Zn‐MoS 2 batteries. tailored MoS /(reduced graphene quantum dots) hybrid features an ultra‐large interlayer spacing (2.34 nm), superior electrical conductivity/hydrophilicity, and robust layered structure, demonstrating highly NH 4 + /Zn /H co‐insertion/extraction chemistry 1 M ZnSO +0.5 (NH ) SO electrolyte. H ions can act as fillers to fully utilize screen interactions accelerate diffusion. Thus, unprecedentedly high capability (439.5 104.3 mAh g −1 at 0.1 30 A , respectively) ultra‐long cycling life (8000 cycles) are achieved.

Language: Английский

Citations

17

Oxygen Vacancy-Rich Cobalt-Doped MnO2 Nanorods for Zn Ion Batteries DOI
Xiaowen Chen, Zihan Xu, Sai Guo

et al.

ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 12, 2025

Improving electrical conductivity and increasing the active site are important directions for improving technology of manganese-based cathode materials zinc ion batteries (ZIBs). In this paper, cobalt-doped oxygen-vacancy coupled MnO2 nanorods (Vo-CMO) were prepared by defect engineering an doping strategy as rechargeable ZIBs. Oxygen vacancies can increase density material provide more migration paths ions, thereby electrochemical activity specific capacity. The introduction cobalt adjust electronic structure manganese oxide, change Fermi level material, promote generation transmission charge carriers, transfer rate material. synergistic effect among them improve diffusion kinetics capacity cycle stability Vo-CMO has better Zn2+ storage 295.6 mAh·g–1 at 0.1 A·g–1. reaction mechanism was H+/Zn2+ coinsertion through galvanostatic current intermittent titration (GITT) ex situ experiments. addition, assembled flexible quasi-solid ZIB. oxygen vacancy a new way to develop water-based

Language: Английский

Citations

2

Efficient Modulation d/p‐Band Center Proximity in Birnessite‐Type MnO2 by Cation/Anion Co‐Doping for Enhanced Dual‐Ion Storage DOI Open Access

Yuhui Xu,

Gaini Zhang, Xiaoxue Wang

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 16, 2025

Abstract The wide band gap of δ‐MnO 2 and the restricted regulation p‐band center ( p ) active oxygen atoms hinder electron conduction ion diffusion during zinc storage. Heteroatom doping has proven effective in improving However, solely through cation is comparatively constrained. Herein, a cation/anion co‐doping strategy proposed to simultaneously adjust d‐band d Mn by establishing Mn–O–Ca Mn─N bonds Ca/N co‐doped (Ca/N‐MnO ). This effect induces shift predominant stretching vibration mode Mn─O [MnO 6 ] octahedra, resulting decreased d/p‐band proximity (Δ d‐p 1.688 eV (1.750 for Consequently, both adsorption capacity adsorption/desorption rates Zn 2+ /H + ions are enhanced. Theoretical calculations further reveal that significantly triggers optimization gap, migration energy barrier, energy. As result, Ca/N‐MnO achieves remarkable reversible 192.7 mAh g −1 at 1.0 A after 200 cycles exceptional rate performance. Furthermore, enhancement mechanisms thoroughly elucidated. synergistic offers significant potential efficient storage applications.

Language: Английский

Citations

2