Langmuir,
Journal Year:
2024,
Volume and Issue:
40(24), P. 12697 - 12708
Published: June 6, 2024
Polysulfides
are
easily
dissolved
in
the
electrolyte
of
Li–S
batteries
after
long
cycles.
Sn
atom
modification
electrodes
beneficial
for
improving
cycling
stabilities
batteries.
However,
influence
atoms
on
structure
and
electrochemical
performance
SnO2/C
composite
materials
is
not
explored.
Sn/SnO2/C
developed
as
sulfur
carriers
our
work.
In
addition,
stability
mechanism
Sn/SnO2/C/S
also
elucidated.
Results
show
that
introduced
display
good
(420.1
mAh·g–1
at
1C
1000
cycles)
The
load
80
wt
%
(2
mg–1·cm–2).
introduction
into
plays
three
roles.
first
role
to
enhance
structural
SnO2.
second
help
adsorb
active
ions.
last
promote
electron
transportation
ability
during
initial
discharging/charging
process.
inhibiting
dissolution
polysulfides
electrolytes
Chemical Reviews,
Journal Year:
2024,
Volume and Issue:
124(20), P. 11348 - 11434
Published: Oct. 9, 2024
Environmental
catalysis
has
emerged
as
a
scientific
frontier
in
mitigating
water
pollution
and
advancing
circular
chemistry
reaction
microenvironment
significantly
influences
the
catalytic
performance
efficiency.
This
review
delves
into
engineering
within
liquid-phase
environmental
catalysis,
categorizing
microenvironments
four
scales:
atom/molecule-level
modulation,
nano/microscale-confined
structures,
interface
surface
regulation,
external
field
effects.
Each
category
is
analyzed
for
its
unique
characteristics
merits,
emphasizing
potential
to
enhance
efficiency
selectivity.
Following
this
overview,
we
introduced
recent
advancements
advanced
material
system
design
promote
(e.g.,
purification,
transformation
value-added
products,
green
synthesis),
leveraging
state-of-the-art
technologies.
These
discussions
showcase
was
applied
different
reactions
fine-tune
regimes
improve
from
both
thermodynamics
kinetics
perspectives.
Lastly,
discussed
challenges
future
directions
engineering.
underscores
of
intelligent
materials
drive
development
more
effective
sustainable
solutions
decontamination.
Carbon Neutralization,
Journal Year:
2025,
Volume and Issue:
4(2)
Published: Feb. 19, 2025
ABSTRACT
The
development
of
high‐performance
energy
storage
systems
requires
several
key
attributes,
including
high
and
power
density,
cost‐effectiveness,
safety,
environmental
sustainability.
Among
the
various
potential
technologies,
lithium–sulfur
batteries
stand
out
as
a
promising
contender
for
future
solutions
due
to
their
exceptional
theoretical
specific
density
(2600
Wh
kg⁻¹)
relatively
capacity
(1675
mAh
g⁻¹).
However,
commercialization
faces
significant
challenges,
such
low
sulfur
loading,
rapid
degradation,
poor
cycling
stability.
At
heart
these
issues
lies
limited
understanding
complex
conversion
chemistry
involved
in
batteries.
In
recent
years,
progress
has
been
made
elucidating
reaction
mechanisms,
thanks
use
both
ex
situ
characterization
techniques.
Methods
optical
spectroscopy,
time‐of‐flight
secondary
ion
mass
spectrometry,
synchrotron
X‐ray,
neural
network
analysis
have
demonstrated
great
uncovering
redox
processes
lithium
polysulfides
underlying
significantly
advancing
research
battery
systems.
This
review
focuses
on
major
advancements
research,
particularly
study
electrocatalytic
mechanisms
using
emerging
We
discuss
aspects
accurately
revealing
through
advanced
diagnostic
methods,
well
main
challenges
techniques
face.
Finally,
we
explore
prospects
commercialization.
Advanced Functional Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 3, 2025
Abstract
Oxygen
electrocatalysis
is
a
core
reaction
in
renewable
energy
devices,
greatly
promoting
the
transformation
and
upgrading
of
structure.
Nonetheless,
performance
conversion
devices
hindered
by
large
overpotential
slow
kinetics
oxygen
electrocatalytic
reactions.
Recently,
single‐atom
catalysts
(SACs)
have
emerged
as
promising
contenders
field
because
their
exceptional
metal
atom
utilization,
distinctive
coordination
environment,
adjustable
electronic
properties.
This
review
presents
latest
advancements
design
Co‐based
SACs
for
electrocatalysis.
First,
OER
ORR
mechanisms
are
introduced.
Subsequently,
strategies
regulating
structure
summarized
three
aspects,
including
centers,
support
carriers.
A
particular
emphasis
given
to
relationship
between
properties
catalysts.
Afterward,
applications
explored.
Ultimately,
challenges
prospects
prospected.
Angewandte Chemie International Edition,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Oct. 17, 2024
The
pursuit
of
sustainable
practices
through
the
chemical
recycling
polyamide
wastes
holds
significant
potential,
particularly
in
enabling
recovery
a
range
nitrogen-containing
compounds.
Herein,
we
report
novel
strategy
to
upcycle
tertiary
amines
with
assistance
H
Small,
Journal Year:
2024,
Volume and Issue:
20(46)
Published: Aug. 7, 2024
Abstract
The
kinetically
retarded
sulfur
evolution
reactions
and
notorious
lithium
dendrites
as
the
major
obstacles
hamper
practical
implementation
of
lithium–sulfur
batteries
(LSBs).
Dual
metal
atom
catalysts
a
new
model
are
expected
to
show
higher
activity
by
their
rational
coupling.
Herein,
dual‐atom
catalyst
with
coupled
Ni─Co
pairs
(Ni/Co‐DAC)
is
designed
successfully
programmed
approaches.
alter
local
electron
structure
optimize
coordination
configuration
Ni/Co‐DAC,
leading
coupling
effect
for
promoting
interconversion
guiding
plating/striping.
LSB
delivers
remarkable
capacity
818
mA
h
g
−1
at
3.0
C
low
degeneration
rate
0.053%
per
cycle
over
500
cycles.
Moreover,
high
mass
loading
6.1
mg
cm
−2
lean
electrolyte
dosage
6.0
µL
S
shows
areal
5.7
.
