A Dinuclear Ir(III) Bis(thiophosphinite) Complex Formed by Unusual meta-C–H Activation at a Pincer Ligand DOI Creative Commons
Alexander Linke, Hans‐Joachim Drexler, Torsten Beweries

et al.

Organometallics, Journal Year: 2024, Volume and Issue: 43(11), P. 1205 - 1207

Published: May 29, 2024

Oxidative addition of PC(H)P pincer ligands at late transition metals typically occurs via C–H activation in the 2-position ligand, yielding [(PCP)MHX] type complexes (X = monoanionic ligand). We present formation dinuclear Ir(III) complex [(iPrPSCSPiPr)Ir(H)(MeCN)2]2[OTf]2 as a rare example meta-C–H ligand.

Language: Английский

The crystal structure of (μ4-oxo)-tri(μ4-2,2′-bipyridine-6,6′-bis(olato)-κ5 O,O′:N:N′:O″)tetrazinc(II) – methylformamide (1/1), C33H25N7O8Zn4 DOI Creative Commons

Zhen-Zhen Shi,

Shu-Yang Chen,

J. Chen

et al.

Zeitschrift für Kristallographie - New Crystal Structures, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 6, 2024

Abstract C 33 H 25 N 7 O 8 Zn 4 , triclinic, P 1̄ (no. 2), a = 12.1524(7) Å, b 12.2035(7) c 14.2730(7) α 78.669(4)°, β 66.615(5)°, γ 62.482(6)°, V 1722.83(19) Å 3 Z 2, R gt ( F ) 0.0405, wR ref 2 0.1128, T 293(2) K.

Language: Английский

Citations

0
A Dinuclear Ir(III) Bis(thiophosphinite) Complex Formed by Unusual meta-C–H Activation at a Pincer Ligand DOI Creative Commons
Alexander Linke, Hans‐Joachim Drexler, Torsten Beweries

et al.

Organometallics, Journal Year: 2024, Volume and Issue: 43(11), P. 1205 - 1207

Published: May 29, 2024

Oxidative addition of PC(H)P pincer ligands at late transition metals typically occurs via C–H activation in the 2-position ligand, yielding [(PCP)MHX] type complexes (X = monoanionic ligand). We present formation dinuclear Ir(III) complex [(iPrPSCSPiPr)Ir(H)(MeCN)2]2[OTf]2 as a rare example meta-C–H ligand.

Language: Английский

Citations

0