Recent Progress in Synthetic and Biological Application of Diorganyl Diselenides DOI
Roberto do Carmo Pinheiro, Luiza Souza Marques, Juliano Ten Kathen Jung

et al.

The Chemical Record, Journal Year: 2024, Volume and Issue: 24(7)

Published: July 1, 2024

Abstract Diorganyl diselenides have emerged as privileged structures because they are easy to prepare, distinct reactivity, and broad biological activity. They also been used in the synthesis of natural products an electrophile organoselenylation aromatic systems peptides, reductions alkenes, nucleophilic substitution. This review summarizes advancements methods for transformations promoted by diorganyl main functions organic chemistry. Parallel, it will describe findings on pharmacology toxicology diselenides, emphasizing anti‐inflammatory, hypoglycemic, chemotherapeutic, antimicrobial activities. Therefore, examination detailing reactivity characteristics provides valuable insights academic researchers industrial professionals.

Language: Английский

Blue Light/NIS-Promoted Amino-Selenylation of Alkenes with Amides and Diselenides DOI

Yixin Luo,

Linsheng Zhong,

Meng Ding

et al.

Journal of Organometallic Chemistry, Journal Year: 2025, Volume and Issue: unknown, P. 123716 - 123716

Published: May 1, 2025

Language: Английский

Citations

0
Synthesis of organoselenium compounds using electrochemical and photochemical methods as novel approaches in organic chemistry DOI
Adrián A. Heredia, Lydia M. Bouchet, Willber D. Castro‐Godoy

et al.

Tetrahedron, Journal Year: 2023, Volume and Issue: 148, P. 133667 - 133667

Published: Sept. 26, 2023

Language: Английский

Citations

5
Recent Progress in Synthesis and Application of Chiral Organoselenium Compounds DOI

Shuyan Lai,

Xiayu Liang, Qingle Zeng

et al.

Chemistry - A European Journal, Journal Year: 2023, Volume and Issue: 30(16)

Published: Dec. 11, 2023

Abstract Chiral organoselenium compounds have shown an important role as intermediates in many areas, such drug discovery, organic catalysis, and nanomaterials. A lot of different methods been developed to synthesize chiral which contain selenium, because they interesting properties can be used real life. Over the last few decades, a progress has made synthesizing compounds. This work gives overview creating new ways by categorizing them into groups based on reactions undergo. In addition, use is also discussed.

Language: Английский

Citations

5
Blue LED light‐promoted CuCl2‐catalyzed three component reaction of styrenes, indoles, and diselenides DOI

Xianjie Yin,

Helin Wang, Lei Shen

et al.

Applied Organometallic Chemistry, Journal Year: 2023, Volume and Issue: 37(10)

Published: Aug. 19, 2023

A three‐component reaction of olefins, indoles, and diaryl diselenides catalyzed by copper chloride under irradiation blue LED light is disclosed. Various including diheteroaryl are suitable for this bifunctionalization olefins. This protocol provides 26 examples β‐(hetero)arylselenyl indoles in 60%–87% yields. The proposed mechanism involves activation coordination with chloride, generation arylselenium cations heterolysis activated diselenides, electrophilic addition to styrenes, then Friedel–Crafts‐type alkylation at the 3‐position NH‐indoles.

Language: Английский

Citations

3
Advances in Difunctionalization of Olefins with Diorganyl Dichalcogenides DOI
Helin Wang,

Alex Adonis Nking’wa,

Fawad Islam

et al.

Chemistry - An Asian Journal, Journal Year: 2023, Volume and Issue: 19(1)

Published: Nov. 11, 2023

Organochalcogen molecules have extensive applications in various fields. They serve as pharmaceuticals, ligands, organocatalysts, agrochemicals, and other functional materials. Difunctionalization of olefins, which belong to a class multicomponent reactions, is successful technique for introducing two moieties single-step reaction, both terms atom economy step economy. The difunctionalization olefins with diorganyl dichalcogenides may effectively increase the molecular complexity, has achieved significant advancements recent decades. This article describes diselenides disulfides.

Language: Английский

Citations

2
Indium(III)‐Catalyzed Three Component Reaction of N‐Bromosuccinimide, Alkenes and N‐Tosylhydrazones DOI

Yixin Luo,

Sihan Zhou,

Alex Adonis Nking’wa

et al.

European Journal of Organic Chemistry, Journal Year: 2023, Volume and Issue: 27(5)

Published: Dec. 13, 2023

Abstract A three‐component reaction involving alkenes, N ‐sulfonylhydrazones, and ‐bromosuccinimide (NBS) is described that uses Indium(III) triflate for the synthesis of bromoethyl sulfonyl hydrazones. Using ‐tosylhydrazones as a nitrogen source NBS bromine source, this intermolecular aminobromination alkenes carried out under air in mild conditions. mechanism electrophilic addition proposed based on GC‐MS analytical result.

Language: Английский

Citations

2
Recent Progress in Synthetic and Biological Application of Diorganyl Diselenides DOI
Roberto do Carmo Pinheiro, Luiza Souza Marques, Juliano Ten Kathen Jung

et al.

The Chemical Record, Journal Year: 2024, Volume and Issue: 24(7)

Published: July 1, 2024

Abstract Diorganyl diselenides have emerged as privileged structures because they are easy to prepare, distinct reactivity, and broad biological activity. They also been used in the synthesis of natural products an electrophile organoselenylation aromatic systems peptides, reductions alkenes, nucleophilic substitution. This review summarizes advancements methods for transformations promoted by diorganyl main functions organic chemistry. Parallel, it will describe findings on pharmacology toxicology diselenides, emphasizing anti‐inflammatory, hypoglycemic, chemotherapeutic, antimicrobial activities. Therefore, examination detailing reactivity characteristics provides valuable insights academic researchers industrial professionals.

Language: Английский

Citations

0