Nickel-mediated aerobic C(sp2)–nucleophile coupling reactions for late-stage diversification of aryl electrophiles
D. Das,
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Long P. Dinh,
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Ryan E. Smith
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et al.
Nature Synthesis,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 16, 2025
Language: Английский
Photocatalytic Applications of Covalent Organic Frameworks: Synthesis, Characterization, and Utility
Jared G. Doremus,
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Bertha Lotsi,
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Amit Sharma
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et al.
Nanoscale,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Jan. 1, 2024
This
review
highlights
the
recent
advances
in
utilizing
covalent
organic
frameworks
(COFs)
for
photocatalytic
applications.
Language: Английский
From Structure to Function: Designing Iridium Catalysts with Spin-Forbidden Excitation for Low-Energy Light-Driven Reactions
Eva Bednářová,
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Robin Grotjahn,
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Chenxi Lin
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et al.
Journal of the American Chemical Society,
Journal Year:
2025,
Volume and Issue:
unknown
Published: April 7, 2025
Herein
we
describe
a
comprehensive
study
of
ligand
effects
on
optoelectronic
properties
series
Ir(III)
catalysts
which
undergo
formally
spin-forbidden
excitation
using
low-energy
light.
We
demonstrate
that
electronic
and
steric
tuning
several
variables
can
be
explained
by
their
impact
the
HOMO
LUMO
energies
complex.
Density
functional
theory
calculations
catalysts'
adiabatic
triplet
agree
with
experimental
results
to
within
0.05
eV
average.
As
many
these
subtle
are
independent
each
other,
merger
them
in
single
complex
tends
have
an
additive
effect
thus
succeeded
developing
family
highly
oxidizing
iridium
photocatalysts
operate
excitation.
Language: Английский
Insulated π-conjugated 2,2′-bipyridine transition-metal complexes: enhanced photoproperties in luminescence and catalysis
Chemical Science,
Journal Year:
2024,
Volume and Issue:
15(23), P. 8873 - 8879
Published: Jan. 1, 2024
An
insulated
π-conjugated
2,2′-bipyridine
exhibited
enhanced
ligand
performance
in
the
solid-state
emitting
biscyclometalated
Ir
complexes
and
visible-light-driven
Ni
catalysts
owing
to
π-extension
remote
steric
effects.
Language: Английский
Air-stable, well-defined palladium–BIAN–NHC chloro dimer: Highly efficient N-Heterocyclic carbene (NHC) catalyst platform for Buchwald–Hartwig C–N cross-coupling reactions
Jin Zhang,
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Jianglong Cai,
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Xue Li
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et al.
Journal of Catalysis,
Journal Year:
2024,
Volume and Issue:
unknown, P. 115783 - 115783
Published: Oct. 1, 2024
Language: Английский
TiF4-mediated, one-pot, reductive amination of carboxylic acids with borane–ammonia
Madison Snyder,
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Abdulkhaliq A. Alawaed,
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Chunge Li
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et al.
RSC Advances,
Journal Year:
2024,
Volume and Issue:
14(42), P. 31205 - 31209
Published: Jan. 1, 2024
Reductive
alkylation
of
amines
with
carboxylic
acids
is
achieved
using
BH
3
–NH
and
TiF
4
,
yielding
free
or
their
borane-complexes.
Language: Английский