TiF4-mediated, one-pot, reductive amination of carboxylic acids with borane–ammonia DOI Creative Commons

Madison Snyder,

Abdulkhaliq A. Alawaed,

Chunge Li

et al.

RSC Advances, Journal Year: 2024, Volume and Issue: 14(42), P. 31205 - 31209

Published: Jan. 1, 2024

Reductive alkylation of amines with carboxylic acids is achieved using BH 3 –NH and TiF 4 , yielding free or their borane-complexes.

Language: Английский

Nickel-mediated aerobic C(sp2)–nucleophile coupling reactions for late-stage diversification of aryl electrophiles DOI
D. Das, Long P. Dinh,

Ryan E. Smith

et al.

Nature Synthesis, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 16, 2025

Language: Английский

Citations

3

Photocatalytic Applications of Covalent Organic Frameworks: Synthesis, Characterization, and Utility DOI Creative Commons

Jared G. Doremus,

Bertha Lotsi,

Amit Sharma

et al.

Nanoscale, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

This review highlights the recent advances in utilizing covalent organic frameworks (COFs) for photocatalytic applications.

Language: Английский

Citations

5

From Structure to Function: Designing Iridium Catalysts with Spin-Forbidden Excitation for Low-Energy Light-Driven Reactions DOI
Eva Bednářová, Robin Grotjahn,

Chenxi Lin

et al.

Journal of the American Chemical Society, Journal Year: 2025, Volume and Issue: unknown

Published: April 7, 2025

Herein we describe a comprehensive study of ligand effects on optoelectronic properties series Ir(III) catalysts which undergo formally spin-forbidden excitation using low-energy light. We demonstrate that electronic and steric tuning several variables can be explained by their impact the HOMO LUMO energies complex. Density functional theory calculations catalysts' adiabatic triplet agree with experimental results to within 0.05 eV average. As many these subtle are independent each other, merger them in single complex tends have an additive effect thus succeeded developing family highly oxidizing iridium photocatalysts operate excitation.

Language: Английский

Citations

0

Insulated π-conjugated 2,2′-bipyridine transition-metal complexes: enhanced photoproperties in luminescence and catalysis DOI Creative Commons
Tomohiro Iwai, Shinsuke Abe, Shin‐ya Takizawa

et al.

Chemical Science, Journal Year: 2024, Volume and Issue: 15(23), P. 8873 - 8879

Published: Jan. 1, 2024

An insulated π-conjugated 2,2′-bipyridine exhibited enhanced ligand performance in the solid-state emitting biscyclometalated Ir complexes and visible-light-driven Ni catalysts owing to π-extension remote steric effects.

Language: Английский

Citations

1

Air-stable, well-defined palladium–BIAN–NHC chloro dimer: Highly efficient N-Heterocyclic carbene (NHC) catalyst platform for Buchwald–Hartwig C–N cross-coupling reactions DOI
Jin Zhang,

Jianglong Cai,

Xue Li

et al.

Journal of Catalysis, Journal Year: 2024, Volume and Issue: unknown, P. 115783 - 115783

Published: Oct. 1, 2024

Language: Английский

Citations

1

TiF4-mediated, one-pot, reductive amination of carboxylic acids with borane–ammonia DOI Creative Commons

Madison Snyder,

Abdulkhaliq A. Alawaed,

Chunge Li

et al.

RSC Advances, Journal Year: 2024, Volume and Issue: 14(42), P. 31205 - 31209

Published: Jan. 1, 2024

Reductive alkylation of amines with carboxylic acids is achieved using BH 3 –NH and TiF 4 , yielding free or their borane-complexes.

Language: Английский

Citations

0