Boronyl-Group-Assisted Decatungstate-Catalyzed Benzylic C(sp3)–H Alkylation DOI

Hui Jiang,

Takeru Torigoe, Yoichiro Kuninobu

et al.

Organic Letters, Journal Year: 2024, Volume and Issue: 26(23), P. 4853 - 4856

Published: June 5, 2024

Boronic acid synthesis primarily involves the introduction of boronyl groups. However, an alternative route that functionalization boronic acids has not received much attention. This study describes catalytic C(sp3)–H alkylation ortho-tolylboronic utilizing interaction between a free group [−B(OH)2] and decatungstate photocatalyst [W10O32]4–. The groups alkylated products could be converted without isolation product.

Language: Английский

Boronyl-Group-Assisted Decatungstate-Catalyzed Benzylic C(sp3)–H Alkylation DOI

Hui Jiang,

Takeru Torigoe, Yoichiro Kuninobu

et al.

Organic Letters, Journal Year: 2024, Volume and Issue: 26(23), P. 4853 - 4856

Published: June 5, 2024

Boronic acid synthesis primarily involves the introduction of boronyl groups. However, an alternative route that functionalization boronic acids has not received much attention. This study describes catalytic C(sp3)–H alkylation ortho-tolylboronic utilizing interaction between a free group [−B(OH)2] and decatungstate photocatalyst [W10O32]4–. The groups alkylated products could be converted without isolation product.

Language: Английский

Citations

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