Synergistic Integration of Proton-Coupled Electron Transfer and Heterogeneous Photocatalysis for Promoting the Synthesis of Unsymmetrical Imidazolidines DOI
Jian Tian, Chuan Yang, Pengwei Hu

et al.

Organic Letters, Journal Year: 2025, Volume and Issue: unknown

Published: April 8, 2025

The proton-coupled electron transfer (PCET) process has garnered significant attention in photocatalysis due to its ability facilitate challenging transformations under mild conditions. By integrating PCET into heterogeneous photocatalysts, substrates can be precisely activated through the concurrent of both electrons and protons between catalyst reaction medium. Herein, we synthesized a novel type carbon-nitride-based photocatalyst, which effectively drive via mechanism, enabling three-component synthesis unsymmetrical imidazolidines with ease.

Language: Английский

gem-Difluoroalkenylation of Aldehydes and Ketones with Bis(difluoromethyl)triphenylphosphorane under Operationally Simple Conditions DOI

Jiaxi Cai,

Huanhuan Song, Xin Liu

et al.

Tetrahedron, Journal Year: 2025, Volume and Issue: unknown, P. 134461 - 134461

Published: Jan. 1, 2025

Language: Английский

Citations

0
Synergistic Integration of Proton-Coupled Electron Transfer and Heterogeneous Photocatalysis for Promoting the Synthesis of Unsymmetrical Imidazolidines DOI
Jian Tian, Chuan Yang, Pengwei Hu

et al.

Organic Letters, Journal Year: 2025, Volume and Issue: unknown

Published: April 8, 2025

The proton-coupled electron transfer (PCET) process has garnered significant attention in photocatalysis due to its ability facilitate challenging transformations under mild conditions. By integrating PCET into heterogeneous photocatalysts, substrates can be precisely activated through the concurrent of both electrons and protons between catalyst reaction medium. Herein, we synthesized a novel type carbon-nitride-based photocatalyst, which effectively drive via mechanism, enabling three-component synthesis unsymmetrical imidazolidines with ease.

Language: Английский

Citations

0