Photoinduced PhI(OAc)2-Mediated Cross-Dehydrogenative Heteroarylation of Aldehydes DOI
Lusina Mantry, Parthasarathy Gandeepan

The Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: May 14, 2025

Direct acylation of heteroarenes with aldehydes has been established through a photoinduced hypervalent iodine-mediated cross-dehydrogenative coupling reaction. The reaction proceeds the in situ generation nucleophilic acyl radicals from via C-H hydrogen atom transfer (HAT), followed by Minisci-type heteroarenes. developed system proved to be suitable for cross-coupling diverse range heterocycles and aldehydes.

Language: Английский

Combination of photocatalytic proton-coupled electron transfer and spin-center shift: direct C-H benzylation of N-heteroarenes with benzaldehydes in continuous-flow DOI

Jia-Cheng Hou,

Jun Jiang,

Hui Dai

et al.

Science China Chemistry, Journal Year: 2025, Volume and Issue: 68(5), P. 1945 - 1951

Published: Feb. 24, 2025

Language: Английский

Citations

2
Photoinduced PhI(OAc)2-Mediated Cross-Dehydrogenative Heteroarylation of Aldehydes DOI
Lusina Mantry, Parthasarathy Gandeepan

The Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: May 14, 2025

Direct acylation of heteroarenes with aldehydes has been established through a photoinduced hypervalent iodine-mediated cross-dehydrogenative coupling reaction. The reaction proceeds the in situ generation nucleophilic acyl radicals from via C-H hydrogen atom transfer (HAT), followed by Minisci-type heteroarenes. developed system proved to be suitable for cross-coupling diverse range heterocycles and aldehydes.

Language: Английский

Citations

0