Key degradation mechanisms of perovskite solar cells and strategies for enhanced stability: issues and prospects
RSC Advances,
Journal Year:
2025,
Volume and Issue:
15(1), P. 628 - 654
Published: Jan. 1, 2025
Insights
into
the
factors
and
mechanisms
of
degradation,
along
with
potential
solutions.
Language: Английский
Chalcogenide perovskites: enticing prospects across a wide range of compositions and optoelectronic properties for stable photodetector devices
Nano Express,
Journal Year:
2025,
Volume and Issue:
6(1), P. 015002 - 015002
Published: Jan. 13, 2025
Abstract
Photodetectors
are
indispensable
components
of
many
modern
light
sensing
and
imaging
devices,
converting
photon
energy
into
processable
electrical
signal
through
absorption,
carrier
generation
extraction
using
semiconducting
thin
films
with
appropriate
optoelectronic
properties.
Recently,
metal
halide
perovskites
have
demonstrated
groundbreaking
photodetector
performance
due
to
their
exceptional
properties
originating
from
perovskite
structure.
However,
toxicity
stability
remain
challenges
for
large-scale
applications.
Inspired
by
the
structure,
intense
investigation
in
search
highly
stable,
non-toxic
earth
abundant
materials
superior
features
has
led
discovery
chalcogenide
(CPs).
These
unconventional
semiconductors
formula
ABX
3
,
where
A
B
cations
X
is
a
chalcogen,
which
covers
compounds
corner
sharing
structures
type
II-IV-
VI
(II
=
Ba,
Sr,
Ca,
Eu;
IV
Zr,
Hf;
S,
Se)
III
1
-III
2
-VI
(III
Lanthanides,
Y,
Sc;
Se).
The
increased
coordination
ionicity
these
contribute
excellent
charge
transport
exceptionally
high
optical
absorption
coefficient
(>
10
5
cm
−1
).
present
review
encompasses
theoretical
analysis
that
provides
electronic
band
orbital
contributions
support
Furthermore,
challenging
film
deposition,
characterizations,
application
photodetection
focusing
on
BaZrS
-which
most
studied
one,
ascribed.
Additionally,
we
suggest
prospects
can
bring
out
true
potential
photovoltaics.
Language: Английский
Numerical and Experimental Validation of CsPbBr3 Perovskite Solar Cells: Insights on a One-Step Deposition Technique
Soumya Sundar Parui,
No information about this author
K. Vijayan,
No information about this author
Nithin Xavier
No information about this author
et al.
The Journal of Physical Chemistry C,
Journal Year:
2025,
Volume and Issue:
unknown
Published: April 11, 2025
Language: Английский
Exploring the Effect of Nonideal Conditions in Perovskite Solar Cells Performance Using Numerical Simulations
Sutapa Dey,
No information about this author
Mrittika Paul,
No information about this author
Shivam Porwal
No information about this author
et al.
physica status solidi (a),
Journal Year:
2025,
Volume and Issue:
unknown
Published: April 20, 2025
Non‐radiative
recombination
plays
a
crucial
role
in
perovskite
solar
cells,
restricting
their
performance
considerably
lower
than
the
Shockley‐Queisser
limit.
Herein,
at
first,
CsPbI
3
‐based
cell
configuration
is
optimized
by
varying
thickness,
doping,
and
defect
density
of
each
layer.
Then,
device
investigated
under
different
non‐ideal
conditions
Auger
radiative
coefficients
employing
capacitance
simulator‐1D
simulation.
The
observations
suggest
that
notably
deteriorates
when
exceed
10‐24
cm
6
s
−1
.
Further,
variation
acceptor
concentration
significantly
impacts
J
SC
,
changing
0.6
to
24.2%
moderate
(10–24
)
high
(10–20
recombination,
compared
low
(10–30
effect.
In
contrast,
relatively
small
variations
are
observed
V
OC
As
result,
for
an
1016
−3
efficiency
abruptly
changes
from
18.30
17.36%
finally
7.77%,
respectively,
low,
moderate,
effects.
findings
offer
comprehensive
perception
consequences
on
outcomes.
this
detailed
discussion
enhancement
might
also
be
beneficial
addressing
issue
current
mismatch,
which
remains
significant
challenge
Si/perovskite
tandem
cells.
Language: Английский
Dual-functional passivation on highly-efficient air-processed FAPbI₃ perovskite solar cells fabricated under high humidity without auxiliary equipment
Applied Surface Science Advances,
Journal Year:
2024,
Volume and Issue:
25, P. 100683 - 100683
Published: Dec. 24, 2024
Language: Английский
Design of Ternary metal oxides for Photoelectrochemical Water Splitting using Machine Learning Techniques
Journal of environmental chemical engineering,
Journal Year:
2024,
Volume and Issue:
unknown, P. 115260 - 115260
Published: Dec. 1, 2024
Language: Английский
Design of Ternary Metal Oxides for Photoelectrochemical Water Splitting Using Machine Learning Techniques
Published: Jan. 1, 2024
Language: Английский
On the Vegard’s law compliance for CsxFA(1-x)PbI3 perovskite thin films
D. Mateus Torres‐Herrera,
No information about this author
Olaf Ramírez-Iturbe,
No information about this author
Rosa Nava-Sánchez
No information about this author
et al.
Physica Scripta,
Journal Year:
2024,
Volume and Issue:
99(9), P. 095962 - 095962
Published: Aug. 8, 2024
Abstract
Perovskite-based
solar
cells
(PSCs)
have
demonstrated
remarkable
high
power
conversion
efficiency
in
recent
years.
However,
the
use
of
mono-organic
cations
(such
as
Methylammonium
or
Formamidinium)
limits
potential
for
large-scale
development
due
to
degradation
under
environmental
conditions.
The
incorporation
multi-cations
has
emerged
a
strategy
enhance
both
performance
and
stability.
cesium
(Cs)
cation
represents
solid
alternative
partial
substitution
Formamidinium.
initial
concentration
precursors
solution
is
often
reported
without
establishing
final
present
thin
films.
Herein,
Cs
into
FAPbI
3
structure
produce
x
FA
(1-x)
PbI
perovskite
with
different
values
using
one-step
spin
coating
process
demonstrated.
Assessing
structural
optical
properties,
it
that
films
behave
according
Vegard’s
law
between
0
0.66.
In
particular,
,
an
0.33
exhibits
cubic
lattice
parameter
6.28
Å,
lower
than
but
higher
CsPbI
.
This
showed
stability
dark
phase
ambient
conditions
extended
periods.
addition,
this
material
bandgap
1.5
eV,
making
suitable
cells.
Language: Английский
Machine Learning-Assisted Prediction of Ambient-Processed Perovskite Solar Cells’ Performances
Energies,
Journal Year:
2024,
Volume and Issue:
17(23), P. 5998 - 5998
Published: Nov. 28, 2024
As
we
move
towards
the
commercialization
and
upscaling
of
perovskite
solar
cells,
it
is
essential
to
fabricate
them
in
ambient
environment
rather
than
conventional
glove
box
environment.
The
efficiency
ambient-processed
cells
lags
behind
those
fabricated
controlled
environments,
primarily
owing
external
environmental
factors
such
as
humidity
temperature.
In
case
device
fabrication
relying
solely
on
a
single
parameter,
temperature
or
humidity,
insufficient
for
accurately
characterizing
conditions.
Therefore,
dew
point
introduced
parameter
which
accounts
both
humidity.
this
study,
machine
learning
model
was
developed
predict
based
meteorological
data,
particularly
point.
A
total
238
were
fabricated,
their
photovoltaic
parameters
points
collected
from
March
December
2023.
data
used
train
various
tree-based
models,
with
random
forest
achieving
highest
accuracy.
efficiencies
January
February
2024
predicted
MAPE
4.44%.
An
additional
Shapley
Additive
exPlanations
analysis
confirmed
significance
performance
cells.
Language: Английский