Hydrological Processes,
Journal Year:
2021,
Volume and Issue:
35(9)
Published: Aug. 27, 2021
Abstract
Monitoring
the
temporal
variation
of
solute
concentrations
in
streams
at
high
frequency
can
play
an
important
role
understanding
hydrological
and
biogeochemical
behaviour
catchments.
UV–visible
spectrometry
is
a
relatively
inexpensive
easily
used
tool
to
infer
those
resolution.
However,
it
not
yet
clear
which
solutes
be
modelled
with
such
in‐situ
sensor.
Here,
we
installed
spectrometer
probe
(200–750
nm)
high‐altitude
tropical
Páramo
stream
record
wavelength
absorbance
5‐min
For
calibration,
simultaneously
sampled
water
4‐h
from
February
2018
March
2019
for
subsequent
laboratory
analysis.
Absorbance
spectra
laboratory‐determined
were
identify
best
calibration
method
determine
effectively
inferred
using
situ
through
evaluation
six
methods
different
mathematical
complexity.
Based
on
Nash
–
Sutcliffe
efficiency
(NSE)
Akaike
information
criterion
metrics,
our
results
suggest
that
multivariate
always
outperformed
simpler
strategies
concentrations.
Eleven
out
21
studied
(Al,
DOC,
Ca,
Cu,
K,
Mg,
N,
Na,
Rb,
Si
Sr)
successfully
calibrated
(NSE
>0.50)
could
even
reduced
daily
sampling
frequency.
It
worth
noting
most
correlated
wavelengths
(WLs)
low
range
(i.e.,
UV
range)
showed
good
correlation
DOC.
The
latter
suggests
estimation
metal
possible
other
organic
load
(e.g.,
peat
dominated
catchments).
In
operation
spectrometers
monitor
quality
parameters
(sub‐hourly)
enhance
protection
human
supplies
aquatic
ecosystems
as
well
providing
assessing
catchment
functioning.
Water,
Journal Year:
2019,
Volume and Issue:
11(5), P. 910 - 910
Published: April 30, 2019
Random
forests
(RF)
is
a
supervised
machine
learning
algorithm,
which
has
recently
started
to
gain
prominence
in
water
resources
applications.
However,
existing
applications
are
generally
restricted
the
implementation
of
Breiman’s
original
algorithm
for
regression
and
classification
problems,
while
numerous
developments
could
be
also
useful
solving
diverse
practical
problems
sector.
Here
we
popularize
RF
their
variants
practicing
scientist,
discuss
related
concepts
techniques,
have
received
less
attention
from
science
hydrologic
communities.
In
doing
so,
review
resources,
highlight
potential
its
variants,
assess
degree
exploitation
range
Relevant
implementations
random
forests,
as
well
techniques
R
programming
language,
covered.
Global Ecology and Biogeography,
Journal Year:
2020,
Volume and Issue:
29(12), P. 2159 - 2175
Published: Oct. 11, 2020
Abstract
Aims
Soil
dissolved
organic
carbon
(DOC)
is
a
primary
form
of
labile
in
terrestrial
ecosystems,
and
therefore
plays
vital
role
soil
cycling.
This
study
aims
to
quantify
the
budgets
DOC
at
biome
global
levels
examine
variations
their
environmental
controls.
Location
Global.
Time
period
1981–2019.
Methods
We
compiled
dataset
analysed
concentration
distribution
across
10
biomes.
Results
Large
are
found
among
biomes
space
declines
exponentially
along
depths.
Tundra
has
highest
0–30
cm
soils
[453.75
(95%
confidence
interval:
324.95–633.5)
mg/kg],
whereas
tropical
temperate
forests
have
relatively
lower
concentrations,
ranging
from
30.20
(24.78–36.80)
54.54
(49.77–59.77)
mg/kg.
generally
accounts
for
<
1%
total
soils,
contributes
more
than
half
0–100
profile.
Furthermore,
primarily
controlled
by
texture,
moisture,
carbon.
Main
conclusions
A
synthesis
combined
with
an
empirical
model
extrapolate
profiles
globe,
estimated
as
7.20
Pg
C
top
12.97
profile,
respectively,
considerable
variation
The
strong
texture
control
but
weak
(TOC)
on
suggest
that
investigation
physical
protection
might
need
expand
consider
soils.
maps
serve
benchmark
validating
land
surface
models
estimating
storage
Hydrological Processes,
Journal Year:
2019,
Volume and Issue:
33(13), P. 1802 - 1817
Published: March 13, 2019
Abstract
High‐elevation
tropical
grassland
systems,
called
Páramo,
provide
essential
ecosystem
services
such
as
water
storage
and
supply
for
surrounding
lowland
areas.
Páramo
systems
are
threatened
by
climate
land
use
changes.
Rainfall
generation
processes
moisture
transport
pathways
influencing
precipitation
in
the
poorly
understood
but
needed
to
estimate
impact
of
these
changes,
particularly
during
El
Niño
conditions,
which
largely
affect
hydrometeorological
conditions
regions.
To
fill
this
knowledge
gap,
we
present
a
stable
isotope
analysis
rainfall
samples
collected
on
daily
weekly
basis
between
January
2015
May
2016
strongest
event
recorded
history
(2014–2016)
two
regions
Central
America
(Chirripó,
Costa
Rica)
northern
Andes
(Cajas,
south
Ecuador).
Isotopic
compositions
were
used
identify
how
(convective
orographic)
change
seasonally
at
each
study
site.
Hybrid
Single
Particle
Lagrangian
Integrated
Trajectory
model
(HYSPLIT)
air
mass
back
trajectory
was
preferential
Our
results
show
strong
influence
north‐east
trade
winds
from
Caribbean
Sea
Chirripó
South
American
low‐level
jet
Amazon
forest
Cajas.
These
contributions
also
related
formation
convective
associated
with
passage
Intertropical
Convergence
Zone
over
Rica
Ecuador
wetter
seasons
orographic
transition
drier
seasons.
findings
baseline
information
further
research
applications
isotopes
tracers
other
montane
ecosystems
tropics.
Water Resources Research,
Journal Year:
2020,
Volume and Issue:
56(4)
Published: March 17, 2020
Abstract
Our
understanding
of
how
wet‐dry
tropical
catchments
process
water
and
solutes
remains
limited.
In
this
study,
we
attempt
to
gain
dissolved
organic
carbon
(DOC)
transport,
storage,
mixing
in
a
126
km
2
catchment
northern
Australia.
We
developed
coupled,
tracer‐aided,
conceptual
rainfall‐runoff
model
(SAVTAM)
that
simultaneously
calculates
water,
isotope,
DOC‐based
processes
at
daily
time
step.
The
semidistributed
can
account
for
the
marked
hydrological
distinction
between
savanna
woodlands
adjacent
seasonal
wetlands.
Using
calibrated
model,
tracked
fluxes
derived
age
storages.
Model
output
matched
variability,
controlled
by
rainfall,
which
switched
on
off
flow
pathways
from
wetlands
ultimately
perennial
river.
Such
connectivity
is
modulated
karst
aquifer
system
continuously
contributes
older
waters
(decades
century
old)
maintain
relatively
stable
streamflow
during
dry
season
(average
stream
=
9.7
16.2
years).
occur
despite
rapid,
monsoon‐driven
response.
DOC
were
largely
sourced
wetland
riparian
forest
transported
order
1.9
t
C
−2
year
−1
stream,
was
average
90%
total
simulated
exports
C·km
·year
.
conclude
coupled
simulation
biogeochemistry
necessary
generate
more
complete
picture
functioning,
particularly
tropics.
Hydrological Processes,
Journal Year:
2020,
Volume and Issue:
34(9), P. 2032 - 2047
Published: March 9, 2020
Abstract
Andosol
soils
formed
in
volcanic
ash
provide
key
hydrological
services
montane
environments.
To
unravel
the
subsurface
water
transport
and
tracer
mixing
these
we
conducted
a
detailed
characterization
of
soil
properties
analyzed
3‐year
data
set
sub‐hourly
hydrometric
weekly
stable
isotope
collected
at
three
locations
along
steep
hillslope.
A
weakly
developed
(52–61
cm
depth),
highly
organic
andic
(Ah)
horizon
overlaying
mineral
(C)
was
identified,
both
showing
relatively
similar
flow
dynamics
Soil
moisture
observations
Ah
showed
fast
responding
(few
hours)
“rooted”
layer
to
depth
15
cm,
overlying
“perched”
that
remained
near
saturated
year‐round.
The
formation
latter
results
from
high
matter
(33–42%)
clay
(29–31%)
content
an
abrupt
hydraulic
conductivity
reduction
this
with
respect
rooted
above.
Isotopic
signatures
revealed
resides
within
for
short
periods,
(2
weeks)
perched
(4
layer.
reaction
during
rainfall
events
also
observed
C
horizon,
response
times
those
These
indicate
despite
layer,
which
helps
sustain
storage
soil,
vertical
mobilization
through
entire
profile
occurs
events.
being
result
transmissivity
potentials
porous
matrix
Andosols,
as
evidenced
by
exponential
shape
retention
curves
subsequent
horizons.
findings
demonstrate
behavior
resembles
“layered
sponge,”
paths
dominate.
Hydrological Processes,
Journal Year:
2020,
Volume and Issue:
34(24), P. 4609 - 4627
Published: Sept. 14, 2020
Abstract
Páramos,
a
neotropical
alpine
grassland‐peatland
biome
of
the
northern
Andes
and
Central
America,
play
an
essential
role
in
regional
global
cycles
water,
carbon,
nutrients.
They
act
as
water
towers,
delivering
ecosystem
services
from
high
mountains
down
to
Pacific,
Caribbean,
Amazon
regions.
Páramos
are
also
widely
recognized
biodiversity
climate
change
hot
spots,
yet
they
threatened
by
anthropogenic
activities
environmental
changes.
Despite
their
importance
for
security
carbon
storage,
vulnerability
human
activities,
only
three
decades
ago,
páramos
were
severely
understudied.
Increasing
awareness
need
hydrological
evidence
guide
sustainable
management
prompted
action
generating
data
filling
long‐standing
knowledge
gaps.
This
has
led
remarkably
successful
increase
scientific
knowledge,
induced
strong
interaction
between
scientific,
policy,
(local)
communities.
A
combination
well‐established
innovative
approaches
been
applied
collection,
processing,
analysis.
In
this
review,
we
provide
short
overview
historical
development
research
state
hydrometeorology,
flux
dynamics,
impacts,
influence
extreme
events
páramos.
We
then
present
emerging
technologies
hydrology
resources
discuss
how
converging
science
policy
efforts
have
leveraged
traditional
new
observational
techniques
generate
base
that
can
support
conclude
co‐evolution
was
able
successfully
cover
different
spatial
temporal
scales.
Lastly,
outline
future
directions
showcase
long‐term
collection
foster
responsible
conservation
towers.
Journal of Plant Nutrition and Soil Science,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 26, 2025
ABSTRACT
Background
Both
organic
carbon
(OC)
stocks
and
labile
OC
(LOC)
fractions
are
important
indicators
of
soil
health
sensitive
to
land
use
change.
Aims
To
study
the
effects
change
on
these
in
montane
volcanic
ash
soils,
a
transect
was
surveyed
northern
Ecuador.
Methods
Samples
were
collected
from
0–30,
30–60,
60–90
cm
depth
at
two
agricultural
sites
with
different
time
cultivation
three
natural
vegetation
(tropical
alpine
grassland,
páramo).
LOC
determined
as
cold
hot
water
extractable
(CWEOC
HWEOC).
Molar
absorptivity
254
nm
extracts
qualitative
measure.
Results
Total
high
páramo
(51.3–60.2
kg
C
m
−3
)
younger
site
(50.8
;
20
years
cultivation),
but
significantly
lower
(30.1
older
(at
least
100
cultivation);
CWEOC
(0.1%–0.7%)
HWEOC
(0.6%–4.1%)
represented
only
small
part
OC.
pools
decreased
increasing
time,
reflecting
short‐term
long‐term
effects.
In
contrast,
molar
highest
oldest
(198–307
L
mol
−1
vs.
36–64
other
sites),
indicating
that
easily
degradable
depleted
leaving
compounds
higher
aromaticity.
Conclusions
The
conversion
into
negatively
affects
health,
indicated
by
reduced
storage
capacities
contents.
Hydrological Processes,
Journal Year:
2020,
Volume and Issue:
35(1)
Published: Dec. 16, 2020
Abstract
Accurate
determination
of
the
water
retention
curve
(WRC)
a
soil
is
essential
for
understanding
and
modelling
subsurface
hydrological,
ecological,
biogeochemical
processes.
Volcanic
ash
soils
with
andic
properties
(Andosols)
are
recognized
as
important
providers
ecological
hydrological
services
in
mountainous
regions
worldwide
due
to
their
large
fraction
small
size
particles
(clay,
silt,
organic
matter)
that
gives
them
an
outstanding
holding
capacity.
Previous
comparative
analyses
situ
(field)
standard
laboratory
methods
WRC
Andosols
showed
contrasting
results.
Based
on
extensive
analysis
laboratory,
experimental,
field
measured
WRCs
combination
data
extracted
from
published
literature
we
show
using
sample
volumes
(≤300
cm
3
)
mimic
these
only
partially.
The
results
obtained
by
latter
resemble
portion
wet
range
Andosols'
(from
saturation
up
−5
kPa,
or
pF
1.7),
but
overestimate
substantially
content
higher
matric
potentials.
This
discrepancy
occurs
irrespective
site‐specific
land
use
cover,
properties,
applied
method.
disagreement
limits
our
capacity
infer
correctly
behaviour,
illustrated
through
long‐term
moisture
potential
experimental
site
tropical
Andes.
These
findings
imply
reported
past
research
should
be
used
caution
future
focus
determining
allow
obtaining
correct
characterization
Andosols.
For
latter,
set
recommendations
directions
solve
identified
methodological
issues
proposed.