Regulating Ru−O Bonding Interactions by Ir Doping Boosts the Acid Oxygen Evolution Performance DOI

Ji‐Shuang Zeng,

Zhengxin Qian,

Qing‐Na Zheng

et al.

ChemCatChem, Journal Year: 2024, Volume and Issue: 16(5)

Published: Jan. 5, 2024

Abstract Highly active and stable oxygen evolution reaction (OER) catalysts are crucial for the large‐scale application of proton exchange membrane water electrolyzers. However, dynamic reconfiguration catalyst surface structure centers is still undefined, which greatly hinders development efficient OER catalysts. Herein, we report an Ir 0.3 Ru 0.7 O x /C with a facile low‐temperature synthesis route, can reach 10 mA cm −2 at overpotential 217 mV Tafel slope as low 39.4 dec −1 , yields mass activity 61 times that commercial IrO 2 300 mV. The lattice RuO stabilized by introduction species, thus promoting durability. Further in situ Raman reveals emerges species high potentials, Ru−O bonding interactions enhanced regulation, stabilizing solvation potentials accelerating nucleophilic attack molecules, leading to improved performance. This work deepens fundamental understanding offers effective way advance utilization Ru‐based

Language: Английский

Energy storage technologies: An integrated survey of developments, global economical/environmental effects, optimal scheduling model, and sustainable adaption policies DOI Creative Commons
Mohammad Amir,

Radhika G. Deshmukh,

Haris M. Khalid

et al.

Journal of Energy Storage, Journal Year: 2023, Volume and Issue: 72, P. 108694 - 108694

Published: Aug. 19, 2023

Energy Storage Technology is one of the major components renewable energy integration and decarbonization world systems. It significantly benefits addressing ancillary power services, quality stability, supply reliability. However, recent years COVID-19 pandemic have given rise to crisis in various industrial technology sectors. An integrated survey storage development, its classification, performance, safe management made resolve these challenges. The development has been classified into electromechanical, mechanical, electromagnetic, thermodynamics, chemical, hybrid methods. current study identifies potential technologies, operational framework, comparison analysis, practical characteristics. This proposed also provides useful information readers, engineers, practitioners on global economic effects, environmental organization resilience, key challenges, projections technologies. optimal scheduling model proposed. Policies for sustainable adaptation are then described. extensive list publications date open literature canvassed portray developments this area.

Language: Английский

Citations

218
NaSICON: A promising solid electrolyte for solid‐state sodium batteries DOI Creative Commons
Chi Li, Rui Li,

Kaining Liu

et al.

Interdisciplinary materials, Journal Year: 2022, Volume and Issue: 1(3), P. 396 - 416

Published: July 1, 2022

Abstract A surge of interest has been brought to all‐solid‐state batteries (ASSBs) as they show great prospects for enabling higher energy density and improved safety compared conventional liquid batteries. Na Super Ionic CONductors (NaSICONs) proposed by Goodenough Hong in 1976 are the most promising materials class Na‐based ASSBs owing their excellent ion conductivity (>1 mS cm −1 ), high thermal chemical/electrochemical stability, well good compatibility with electrode materials. The major challenge facing NaSICON‐type electrolytes is generally interfacial resistance thus sluggish charge transfer kinetics across NaSICON/cathode interface. Great endeavors past few years have led progress improvement ion‐conducting property, a dramatic decrease NaSICON/electrode interface resistance. Excellent cycling performance rate capability achieved through engineering. In this review article, we summarize state‐of‐the‐art findings various derivatives NaSICON structured solid electrolytes, aim providing deeper understanding underlying mechanism conductivity, intrinsic reasons enhanced kinetics. These strategies can be readily extended other electrolytes. We hope will inspire more work on solid‐state

Language: Английский

Citations

101
Recent advances and perspectives for Zn-based batteries: Zn anode and electrolyte DOI Creative Commons

Huaiyun Ge,

Xilan Feng,

Dapeng Liu

et al.

Deleted Journal, Journal Year: 2022, Volume and Issue: 2, P. e9120039 - e9120039

Published: Nov. 8, 2022

Zn-based batteries have attracted extensive attention due to their high theoretical energy density, safety, abundant resources, environmental friendliness, and low cost. They are a new storage conversion technology with significant development potential been widely used in renewable portable electronic devices. Considerable attempts devoted improving the performance of batteries. Specifically, battery cycle life efficiency can be improved by electrolyte modification construction highly efficient rechargeable Zn anodes. This review compiles progress research related anodes electrolytes, especially last five years. will introduce fundamental concepts, summarize recent development, inspire further systematic for high-performance future.

Language: Английский

Citations

95
NASICONs‐type solid‐state electrolytes: The history, physicochemical properties, and challenges DOI Creative Commons
Lixiao Zhang, Yimeng Liu, Ya You

et al.

Interdisciplinary materials, Journal Year: 2022, Volume and Issue: 2(1), P. 91 - 110

Published: July 19, 2022

Abstract Solid‐state electrolytes are critical for the development of next‐generation high‐energy and high‐safety rechargeable batteries. Among all candidates, sodium (Na) superionic conductors (NASICONs) highly promising because their evident advantages in high ionic conductivity chemical/electrochemical stability. The concept NASICONs was proposed by Hong Goodenough et al. 1976 reporting synthesis characterization Na 1+ x Zr 2 (Si P 3 − )O 12 (0 ≤ 3), which has attracted tremendous attention on NASICONs‐type solid‐state electrolytes. In this review, we committed to describing history elucidating contribution as a tribute him. We summarize correlations differences between lithium‐based sodium‐based electrolytes, such preparation methods, structures, conductivities, mechanisms ion transportation. Critical challenges NASICONs‐structured discussed, several research directions tackle obstacles toward practical applications.

Language: Английский

Citations

92
Iodine conversion chemistry in aqueous batteries: Challenges, strategies, and perspectives DOI
Lijing Yan, Shaojian Zhang, Qiaoling Kang

et al.

Energy storage materials, Journal Year: 2022, Volume and Issue: 54, P. 339 - 365

Published: Oct. 17, 2022

Language: Английский

Citations

86
Bioinspired cellulose‐integrated MXene‐based hydrogels for multifunctional sensing and electromagnetic interference shielding DOI Creative Commons
Jingjiang Wei,

Chenglong Zhu,

Zhihui Zeng

et al.

Interdisciplinary materials, Journal Year: 2022, Volume and Issue: 1(4), P. 495 - 506

Published: April 28, 2022

Abstract Bioinspired hydrogels are complex materials with distinctive properties comparable to biological tissues. Their exceptional sensitivity various external stimuli leads substantial application potential in wearable smart devices. However, these multifaceted often challenging be combined pattern customization, stimulus responsiveness, self‐healing, and biocompatibility. Herein, inspired by mussel secretions, a printable, biocompatible MXene‐based composite hydrogel was designed prepared incorporating Ti 3 C 2 T x MXene nanosheets into the framework through chelation of calcium ions (Ca 2+ ) polyacrylic acid cellulose nanofibers at alkaline conditions. The conductive exhibited (gauge factor 2.16), self‐healing (within 1 s), recognition, adhesion, distinguishing it as an ideal candidate for multifunctional sensors toward strain sensing, vocal signature detection, Morse code transmission. Additionally, manifested efficient electromagnetic interference shielding (reaching more than 30 dB thickness 2.0 mm), protecting electronics humans from radiation pollution. Therefore, presented work represents versatile strategy developing environmentally friendly hydrogels, demonstrating perspectives intelligent applications.

Language: Английский

Citations

80
Cross-linked polyaniline for production of long lifespan aqueous iron||organic batteries with electrochromic properties DOI Creative Commons
Haiming Lv, Zhiquan Wei, Cuiping Han

et al.

Nature Communications, Journal Year: 2023, Volume and Issue: 14(1)

Published: May 30, 2023

Aqueous iron batteries are appealing candidates for large-scale energy storage due to their safety and low-cost aspects. However, the development of aqueous Fe is hindered by inadequate long-term cycling stability. Here, we propose synthesis application as positive electrode active material cross-linked polyaniline (C-PANI). We use melamine crosslinker improve electronical conductivity electrochemical stability C-PANI. Indeed, when C-PANI tested in combination with a metal negative 1 M trifluoromethanesulfonate (Fe(TOF)2) electrolyte solution, coin cell can deliver specific capacity about 110 mAh g-1 an average discharge voltage 0.55 V after 39,000 cycles at 25 A test temperature 28 °C ± °C. Furthermore, mechanistic studies suggest that Fe2+ ions bonded TOF- anions form positively charged complexes Fe(TOF)+, which stored protons structures. Finally, also demonstrate polymeric hydrogel produce flexible reflective electrochromic lab-scale battery prototype.

Language: Английский

Citations

73
Electrolyte engineering strategies for regulation of the Zn metal anode in aqueous Zn‐ion batteries DOI Creative Commons
Zixuan Li, Alex W. Robertson

Battery energy, Journal Year: 2022, Volume and Issue: 2(1)

Published: Dec. 29, 2022

Abstract Rechargeable aqueous zinc‐ion batteries (AZBs), with their high theoretical capacity, low cost, safety, and environmental friendliness, have risen as a promising candidate for next‐generation energy storage. Despite the fruitful progress in cathode material research, electrochemical performance of AZB remains hindered by physical chemical instability Zn anode. The anode suffers from dendrite growth reactions electrolyte, leading to efficiency decay capacity loss. Recently, significant effort has been dedicated regulating Electrolyte manipulation, including tailoring salt, additives, or concentration, is useful strategy electrolyte strongly influences anode's failure processes. It thus worthwhile gain an in‐depth understanding these electrolyte‐dependent regulation mechanisms. With this mind, review first outlines two main issues behind failure, growth, side reactions. Subsequently, strategy, namely, influence additive, concentration on anode, provided. We conclude summarizing future prospects metal potential electrolyte‐based solutions.

Language: Английский

Citations

70
Unleashing recent electrolyte materials for next-generation supercapacitor applications: A comprehensive review DOI

Somya Samantaray,

Debabrata Mohanty, I‐Ming Hung

et al.

Journal of Energy Storage, Journal Year: 2023, Volume and Issue: 72, P. 108352 - 108352

Published: July 20, 2023

Language: Английский

Citations

60
Progress on Transition Metal Ions Dissolution Suppression Strategies in Prussian Blue Analogs for Aqueous Sodium-/Potassium-Ion Batteries DOI Creative Commons

Wenli Shu,

Junxian Li,

Guangwan Zhang

et al.

Nano-Micro Letters, Journal Year: 2024, Volume and Issue: 16(1)

Published: Feb. 21, 2024

Aqueous sodium-ion batteries (ASIBs) and aqueous potassium-ion (APIBs) present significant potential for large-scale energy storage due to their cost-effectiveness, safety, environmental compatibility. Nonetheless, the intricate mechanisms in electrolytes place stringent requirements on host materials. Prussian blue analogs (PBAs), with open three-dimensional framework facile synthesis, stand out as leading candidates storage. However, PBAs possess a swift capacity fade limited cycle longevity, structural integrity is compromised by pronounced dissolution of transition metal (TM) ions milieu. This manuscript provides an exhaustive review recent advancements concerning ASIBs APIBs. The TM PBAs, informed attributes redox processes, are thoroughly examined. Moreover, this study delves into innovative design tactics alleviate issue ions. In conclusion, paper consolidates various strategies suppressing posits avenues prospective exploration high-safety sodium-/potassium-ion batteries.

Language: Английский

Citations

55