
Materials Science and Engineering R Reports, Journal Year: 2025, Volume and Issue: 165, P. 100993 - 100993
Published: April 22, 2025
Language: Английский
Materials Science and Engineering R Reports, Journal Year: 2025, Volume and Issue: 165, P. 100993 - 100993
Published: April 22, 2025
Language: Английский
Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 159635 - 159635
Published: Jan. 1, 2025
Language: Английский
Citations
0Journal of Material Science and Technology, Journal Year: 2025, Volume and Issue: unknown
Published: March 1, 2025
Language: Английский
Citations
0Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: April 8, 2025
Photocatalytic cycloaddition of carbon dioxide and epoxides under mild conditions is important for green chemistry, while metal clusters loaded on a variety carriers are widely used in energy biology. However, long-term illumination, the light stability at carrier interface poor, which usually leads to loss catalytic performance. Covalent organic polymers (COPs) with periodic ultrasmall pore structures ideal dispersing stabilizing clusters. Through simple nitrogen purge process, embedding Mn2Dy2 hydroxy-containing COP was successfully achieved, makes it an effective photocatalyst CO2 cycloaddition. By introducing adjacent hydroxyl imine bonds unit, dispersed adsorption sites were constructed, generating large number active photogenerated electrons. The photoelectric measurement results indicate that catalyst excellent, good charge separation efficiency. presented expose surfaces, greatly promoting electron transfer. highest conversion rate room temperature normal pressure 99%, TON value 2352. This great significance study novel photocatalytic dioxide.
Language: Английский
Citations
0Materials Science and Engineering R Reports, Journal Year: 2025, Volume and Issue: 165, P. 100993 - 100993
Published: April 22, 2025
Language: Английский
Citations
0