Synthesis and Characterization of Multilayer 3D Chiral Polymers with Enhanced Optical Properties DOI Creative Commons
Sai Zhang,

Xiaobei Jin,

Daixiang Chen

et al.

Molecules, Journal Year: 2025, Volume and Issue: 30(7), P. 1567 - 1567

Published: March 31, 2025

This study reports the synthesis of novel multilayer 3D chiral polymers using 2,2′-(2,7-Naphthalenediyl)bis[4,4,5,5-tetramethyl-1,3,2-dioxaborolane] and 1,8-dibronaphthalene along with its derivatives as key precursors. Comprehensive characterization was performed nuclear magnetic resonance (NMR), gel permeation chromatography (GPC), photoluminescence, ultraviolet (UV) spectroscopy, scanning electron microscopy (SEM), polarimetry, dynamic light scattering (DLS), thermogravimetric analysis (TGA). Notably, exhibited remarkable aggregation-induced emission (AIE) polarization (AIP) phenomena, revealing enhanced luminescence optical activity in aggregated states. These findings underscore potential these for applications optoelectronics advanced sensing technologies, highlighting intricate relationship between molecular structure behavior.

Language: Английский

Exploring chiral and achiral properties of novel multilayer 3D polymers: synthesis and characterization DOI Creative Commons
Sai Zhang, Qingzheng Xu,

Xiuyuan Qin

et al.

RSC Advances, Journal Year: 2025, Volume and Issue: 15(5), P. 3227 - 3236

Published: Jan. 1, 2025

This study reports the novel synthesis of multilayered 3D polymers via 1,3,5-position coupling 1,3,5-tris(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzene with 1,8-dibronaphthalene, a previously unreported method.

Language: Английский

Citations

0
Characterization of Chiral Thiophene Multilayer 3D Polymers with AIE Properties for Environmental Monitoring of Chromium Ions DOI
Sai Zhang, Qingzheng Xu,

Qingkai Yuan

et al.

Macromolecular Rapid Communications, Journal Year: 2025, Volume and Issue: unknown

Published: April 14, 2025

Abstract This study reports the synthesis and characterization of novel thiophene‐based multilayer 3D chiral polymers incorporating methoxy octyloxy functional groups. These exhibit unique fluorescence properties, including a pronounced aggregation‐induced emission (AIE) phenomenon at lower excitation wavelength than previously reported thiophene systems. Additionally, demonstrate remarkable sensitivity in detecting hexavalent chromium ions (Cr 6+ ), significant environmental pollutant. The interaction between Cr leads to measurable changes fluorescence, highlighting their potential for applications monitoring biosensing. Importantly, these are effective actual water, where they maintain selectivity despite presence competing metal ions. enhanced further underscores suitability real‐world applications. work contributes field emphasizes versatility advanced sensing

Language: Английский

Citations

0
Enantioselective Induction of Helical Chirality in Coil‐Structured Amino Acid‐Based Polymers by Conjugated Molecules DOI Open Access

Guoqiang Ji,

Huimin Duan, Xinlei Wu

et al.

Macromolecular Chemistry and Physics, Journal Year: 2025, Volume and Issue: unknown

Published: March 29, 2025

Abstract Chirality induction in aprotic polar solvents is challenging due to disrupted intermolecular interactions and the high conformational flexibility of random‐coil polymers. Herein, a scalable strategy using chiral BINOL as sole source induce helical chirality polymers presented. Circular dichroism (CD), ultraviolet‐visible (UV– vis), resonance Raman spectroscopy confirm that effectively induces cis‐transoidal conformations through hydrogen bonding π–π stacking interactions. CD circularly polarized luminescence (CPL) measurements reveal efficient transfer amplification, with mirror‐image CPL signals observed at 390 nm. Resonance spectra demonstrate enhanced structural order reduced irregularities, evidenced by blue shift narrowed C═C peak, while achiral exhibits minimal ability. This study highlights mechanisms excitation solvents, providing versatile pathway for designing advanced materials exceptional optical fluorescence properties.

Language: Английский

Citations

0
Synthesis and Characterization of Multilayer 3D Chiral Polymers with Enhanced Optical Properties DOI Creative Commons
Sai Zhang,

Xiaobei Jin,

Daixiang Chen

et al.

Molecules, Journal Year: 2025, Volume and Issue: 30(7), P. 1567 - 1567

Published: March 31, 2025

This study reports the synthesis of novel multilayer 3D chiral polymers using 2,2′-(2,7-Naphthalenediyl)bis[4,4,5,5-tetramethyl-1,3,2-dioxaborolane] and 1,8-dibronaphthalene along with its derivatives as key precursors. Comprehensive characterization was performed nuclear magnetic resonance (NMR), gel permeation chromatography (GPC), photoluminescence, ultraviolet (UV) spectroscopy, scanning electron microscopy (SEM), polarimetry, dynamic light scattering (DLS), thermogravimetric analysis (TGA). Notably, exhibited remarkable aggregation-induced emission (AIE) polarization (AIP) phenomena, revealing enhanced luminescence optical activity in aggregated states. These findings underscore potential these for applications optoelectronics advanced sensing technologies, highlighting intricate relationship between molecular structure behavior.

Language: Английский

Citations

0