Physica Scripta,
Journal Year:
2024,
Volume and Issue:
99(7), P. 075928 - 075928
Published: May 29, 2024
Abstract
The
tunable
optical
characteristics
and
superior
thermal
stability
of
Indium
Thallium-based
quaternary
chalcogenides
are
significant.
We
studied
the
intricate
relationship
between
optoelectronic,
thermoelectric
features
notable
BaXCu
3
Se
4
(X
=
In,
Tl)
chalcogenides.
Both
maximum
valence
band
conduction
coincide
at
Γ-point,
confirming
these
materials
as
direct
gap
materials.
By
substituting
for
thallium,
calculated
decreases
from
0.71
eV
to
0.53
eV.
These
anions
have
a
considerable
impact
contribute
decrease
in
energy
via
electrons.
Partially
filled
d
orbitals
copper
play
an
important
role
electronic
states
Fermi
level.
components
complex
dielectric
function,
well
other
parameters,
examined
analyzed
potential
usage
optoelectronic
devices.
ε
1
(
ω
)
becomes
negative
6.32
eV,
suggesting
that
medium
is
reflecting
all
incident
light.
Thallium
affects
absorption
spectrum
because
it
changes
density
transitions.
spectra
indicated
material
absorbs
visible
near-ultraviolet
parts
spectrum,
which
fascinating
might
applications
optoelectronics.
investigated
appropriate
be
used
devices
confirmed
by
their
significant
properties.
Because
Seebeck
coefficient
negative,
most
charge
carriers,
typically
electrons,
flow
higher
temperature
area
lower
region.
At
both
low
high
temperatures,
thallium
accountable
BaTlCu
’s
conductivity
than
BaInCu
material.
Applied Water Science,
Journal Year:
2024,
Volume and Issue:
14(7)
Published: June 5, 2024
Abstract
MPs
have
raised
significant
public
concern
due
to
their
role
as
carriers
of
organic
contaminants
in
aqueous
solutions.
DZN
is
a
non-systemic
organophosphorus
pesticide
that
poses
risks
human
and
environmental
health.
This
study
aimed
investigate
the
adsorption
onto
PE
by
examining
factors
such
dose,
reaction
time,
concentration,
pH
through
experimental
runs
based
on
Box‒Behnken
model.
According
Langmuir
model,
maximum
capacity
for
was
0.35
mg/g.
The
results
indicated
highest
rate
(92%)
observed
distilled
water,
while
lowest
(57%)
municipal
wastewater.
Δ
H
°
S
values
were
obtained
−
0.16
kJ/mol
54.41
J/(mol
K),
respectively.
Therefore,
regarding
negative
G
values,
it
can
be
concluded
an
exothermic,
highly
disordered,
spontaneous
process.
findings
indicate
reduction
concentrations
interfering
compounds
increase.
These
offer
understanding
interaction
between
contaminants,
emphasizing
need
further
studies
approaches
reduce
harmful
impact
health
environment.
Journal of Separation Science,
Journal Year:
2024,
Volume and Issue:
47(16)
Published: Aug. 1, 2024
Molecularly
imprinted
polymers,
a
type
of
special
polymer
materials,
are
widely
used
in
biosensing
and
other
fields
due
to
their
ability
specifically
recognize
target
molecules,
often
called
"artificial
receptors.".
Nowadays,
researchers
constantly
exploring
new
design
synthesis
methods
for
molecularly
materials
improve
the
selectivity
sensitivity
materials.
Among
them,
selection
functional
monomers
has
attracted
great
attention.
This
review
comprehensively
analyzes
discusses
monomers.
The
most
commonly
among
different
types
templates
screened
based
on
structural
properties
template
including
ion-imprinted
protein-imprinted
bacterial
polymers.
rich
binding
sites
group
multifunctional
also
highlighted
advance
development
molecular
imprinting
technology.
article
further
explores
current
challenges
prospects
emphasizes
multiplex
experiments
computer
simulations
as
important
directions
future
research.
provides
comprehensive
information
constructive
guidelines
selecting
areas
such
analytical
chemistry
biosensors.
Gels,
Journal Year:
2024,
Volume and Issue:
10(7), P. 442 - 442
Published: July 4, 2024
Polymeric
hydrogels
are
soft
materials
with
a
three-dimensional
(3D)
hydrophilic
network
capable
of
retaining
and
absorbing
large
amounts
water
or
biological
fluids.
Due
to
their
customizable
properties,
these
extensively
studied
for
developing
matrices
3D
cell
culture
scaffolds,
drug
delivery
systems,
tissue
engineering.
However,
conventional
still
exhibit
many
drawbacks;
thus,
significant
efforts
have
been
directed
towards
dynamic
that
draw
inspiration
from
organisms’
natural
self-repair
abilities
after
injury.
The
self-healing
properties
closely
associated
ability
form,
break,
heal
bonds
in
response
various
stimuli.
primary
objective
this
review
is
provide
comprehensive
overview
by
examining
the
types
chemical
them
biopolymers
utilized,
elucidate
nature
enable
modulation
hydrogels’
properties.
While
ensure
behavior
hydrogels,
they
do
not
inherently
confer
adhesive
Therefore,
we
also
highlight
emerging
approaches
acquire
