Enhancement of electrochemical performance of hydrothermally synthesized CoNiO2/PANI for OER efficiency
Chemical Physics,
Journal Year:
2025,
Volume and Issue:
unknown, P. 112728 - 112728
Published: April 1, 2025
Language: Английский
Synergistic Zn-Cd Bimetallic Engineering in ZIFs for High-Chloride 2e− ORR to H2O2 in Simulated Neutral Seawater
Materials,
Journal Year:
2025,
Volume and Issue:
18(8), P. 1786 - 1786
Published: April 14, 2025
Marine
biofouling
causes
significant
economic
losses,
and
conventional
antifouling
methods
are
often
associated
with
environmental
pollution.
Hydrogen
peroxide
(H2O2),
as
a
clean
energy
source,
has
gained
increasing
attention
in
recent
years.
Meanwhile,
electrocatalytic
2e−
oxygen
reduction
reaction
(ORR)
for
H2O2
production
received
growing
interest.
However,
the
majority
of
current
studies
conducted
on
acidic
or
alkaline
electrolytes,
research
ORR
neutral
NaCl
solutions
remains
rare.
Here,
bimetallic
Zn-Cd
zeolitic
imidazolate
framework
(ZnCd-ZIF)
is
rationally
designed
to
achieve
chloride-resistant
catalysis
under
simulated
seawater
conditions
(pH
7.5,
3.5%
Cl−).
Experimental
results
demonstrate
that
ZnCd-ZIF
catalyst
exhibits
an
exceptional
selectivity
70%
at
0.3
VRHE,
surpassing
monometallic
Zn-ZIF
(60%)
Cd-ZIF
(50%).
Notably,
reaches
120
mmol
g−1
Cl−-containing
electrolyte,
exhibiting
strong
resistance
structural
corrosion
Cl−
poisoning.
This
work
not
only
pioneers
effective
strategy
designing
catalysts
adapted
marine
environments
but
also
advances
practical
implementation
seawater-based
electrochemical
synthesis.
Language: Английский
Synthesis of a novel Cu₂O/BiFeO₃@Ti₃C₂ MXene Z-scheme heterojunction for enhanced photocatalytic wastewater treatment and N₂ fixation: Mechanistic insights and optimization
Journal of Water Process Engineering,
Journal Year:
2025,
Volume and Issue:
73, P. 107708 - 107708
Published: April 20, 2025
Language: Английский
Nitrogen, sulphur co-doped carbon quantum dots scaffolded on TiO2 nanoparticles towards efficient photocatalysts for hydrogen evolution
H.J. Yashwanth,
No information about this author
M.Z. Naik,
No information about this author
Udayabhanu Udayabhanu
No information about this author
et al.
Journal of Industrial and Engineering Chemistry,
Journal Year:
2025,
Volume and Issue:
unknown
Published: April 1, 2025
Language: Английский
Naphthalene‐Quinone Electron Donor–Acceptor Covalent Organic Polymers for Hydrogen Peroxide Photosynthesis in Pure Water
Yongxia Li,
No information about this author
Jiafan Chu,
No information about this author
Xingyu Zhang
No information about this author
et al.
Solar RRL,
Journal Year:
2025,
Volume and Issue:
unknown
Published: May 6, 2025
A
2,3‐diaminonaphthalene
(DAN)
1,3,5‐triformylphloroglucinol
(TP)
β‐ketoenamine‐linked
covalent
organic
polymer
with
naphthalene‐quinone
electron
donor
(D)–acceptor
(A)
structure
(DAN‐TP‐CKP)
was
synthesized
using
a
one‐pot
method.
It
exhibited
high
H
2
O
production
rate
of
1120
μmol
g
cat
−1
h
in
‐saturated
water
under
visible
light,
together
better
durability.
The
efficiency
is
attributed
to
its
crystalline
framework,
large
specific
surface
area
(212
m
),
strong
visible‐light
absorption,
and
efficient
charge
separation
properties
arising
from
dense
D–A
structures.
two‐step
single‐electron
oxygen
reduction
reaction
pathway
probable
four‐step
mechanism
further
elucidates
generation
process.
This
work
highlights
D–A‐type
naphthalene–quinone
metal‐free
photocatalysts
durable
photosynthesis
performance.
Language: Английский
A novel chemical-free method for enhancing specific surface area of carbon material derived from pinus bark for CO2 adsorption
Biomass and Bioenergy,
Journal Year:
2025,
Volume and Issue:
200, P. 107974 - 107974
Published: May 14, 2025
Language: Английский
A Novel Electro‐Thermal Coupled State‐of‐Charge Estimation Method for High‐Rate Lithium‐Ion Battery Applications
Advanced Theory and Simulations,
Journal Year:
2025,
Volume and Issue:
unknown
Published: May 19, 2025
Abstract
The
increasing
electrification
of
large‐scale
industrial
equipment,
such
as
heavy‐duty
electric
mining
trucks,
necessitates
precise
state‐of‐charge
(SOC)
estimation
for
lithium‐ion
batteries
under
high‐rate
operations.
This
is
challenging
due
to
the
significant
electro‐thermal
coupling
effect
at
high
discharge
rates.
study
introduces
a
novel
SOC
method
that
incorporates
enhance
accuracy
and
robustness.
An
electrochemical‐thermal
model
developed
capture
interactions
between
electrochemical
reactions
internal
heat
generation.
Subsequently,
reduced‐order
formulated
enable
real‐time
co‐estimation
temperature.
estimator
based
on
Extended
Kalman
Filter
(EKF)
then
designed.
proposed
method's
performance
validated
using
diverse
test
profiles
with
varying
initial
values.
Experimental
results
show
exceptional
robustness,
mean
absolute
error
3.044%
root
square
4.658%
in
15
C
pulse
test,
despite
40%
error.
approach
significantly
outperforms
conventional
EKF‐only
method,
offering
improved
applications.
Language: Английский