Synthesis and antioxidant activities of N-thiophenyl ebselenamines: a 77Se{1H} NMR mechanistic study DOI
Manish Kumar, Vijay P. Singh

New Journal of Chemistry, Journal Year: 2022, Volume and Issue: 46(25), P. 12010 - 12022

Published: Jan. 1, 2022

Synthesis of N -thiophenyl ebselenamines and selenenyl sulphides as efficient radical-trapping hydroperoxide-decomposing antioxidants, respectively has been described.

Language: Английский

Solvent effect on the 77Se NMR chemical shifts of diphenyl diselenides DOI
Ricardo H. Bartz,

Paola dos Santos Hellwig,

Gelson Perin

et al.

New Journal of Chemistry, Journal Year: 2024, Volume and Issue: 48(7), P. 2971 - 2978

Published: Jan. 1, 2024

Herein, we evaluated the solvent effect on 77 Se NMR chemical shifts of diphenyl diselenides. To gain a deeper insight into shift behavior, DFT calculations have been performed.

Language: Английский

Citations

6
New Fluorescent Chemodosimetric Mechanism for Selective Recognition of Selenocysteine by Dansyl-Appended Ruthenium Nitrosyl Complexes DOI Creative Commons
Iván J. Bazany‐Rodríguez, Pandiyan Thangarasu, M. Leticia Almada‐Leyva

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 20, 2025

Selenocysteine (Sec) is a biologically essential amino acid that serves as crucial component in selenoproteins play key role various cellular functions. Thus, developing reliable and rapid method for detecting Sec physiological media of paramount importance. This report introduces the first time novel fluorescent chemodosimetric mechanism selective recognition using dansyl-appended ruthenium nitrosyl complexes. These complexes consist tetradentate ligand featuring π-extended system (L = N,N′-bis(2-hydroxy-1-naphthylidene)-1,2-phenylenediamine) monodentate derived from conjugated dansyl group, which acts strong signaling unit (ID dansyl-imidazole, BD dansyl-benzimidazole). The reaction between {RuNO}6 [RuL(NO)(ID)]Cl or [RuL(NO)(BD)]Cl an aqueous phase enhances fluorescence; result, it releases NO• has been demonstrated through fluorimetric titrations, UV–vis 77Se NMR, EPR, IR, MS, electronic density calculations. quantitatively detect within micromolar concentration range, achieving limit detection low 0.31 0.12 μM, respectively, just 5 min. Remarkably, these chemodosimeters can also be conveniently employed to living Saccharomyces cerevisiae cells.

Language: Английский

Citations

0
77Se NMR spectroscopy of selenium adducts of N-heterocyclic carbenes DOI

Sean Ray Kahnert,

Lucas Pruschinski,

Andreas Schmidt

et al.

Advances in heterocyclic chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

Language: Английский

Citations

2
Synthesis and antioxidant activities of N-thiophenyl ebselenamines: a 77Se{1H} NMR mechanistic study DOI
Manish Kumar, Vijay P. Singh

New Journal of Chemistry, Journal Year: 2022, Volume and Issue: 46(25), P. 12010 - 12022

Published: Jan. 1, 2022

Synthesis of N -thiophenyl ebselenamines and selenenyl sulphides as efficient radical-trapping hydroperoxide-decomposing antioxidants, respectively has been described.

Language: Английский

Citations

9