Molecular approach to semiconductors: a shift towards ecofriendly manufacturing and neuroinspired interfaces DOI
Kirill Yu. Monakhov, Christoph Meinecke, Marco Moors

et al.

Pure and Applied Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 13, 2024

Abstract Energy dissipation through physical downscaling towards more complex types of memory and logic devices, loss ultrapure water consumption large amounts (toxic) chemicals for wafer cleaning processes, as well high thermal budget solid-state synthesis thin film growth standard semiconductors including the use rare earth elements – all this poses great challenges semiconductor materials science technology. Therefore, research development alternative methods micro- nanofabrication chemical functionalization a new type resource- energy-efficient core component every computer chip is crucial. One promising opportunities transformation today’s complementary metal-oxide-semiconductor (CMOS) electronics into ecofriendly neuroinspired driven by molecular design multi-level switching mechanisms at room temperature. The sustainable technology electron transport in manufacturing devices with unconventional nanophysics, improved performance, augmented functionalities (beyond-CMOS More-than-Moore) becoming increasingly important context gradual transition to future-oriented concept Internet Everything (IoE). In article, we focus on technological significance preparation from single-source (molecular) precursors prospect functionalizing using DNA origami nanotechnology stimuli-responsive metal–oxygen cluster ions such polyoxometalates (POMs). We also describe advanced characterization these qualified systems soft X-rays. emphasize technical relevance solution-based bottom-up novel hybrid their challenging scalability compatibility lithography-based mass production. Our article aims contribute achievement United Nations’ Sustainable Development Goal 9 (Industry, Innovation Infrastructure).

Language: Английский

Oxovanadium electronics for in-memory, neuromorphic, and quantum computing applications DOI
Kirill Yu. Monakhov

Materials Horizons, Journal Year: 2024, Volume and Issue: 11(8), P. 1838 - 1842

Published: Jan. 1, 2024

Redox- and spin-active macrocyclic vanadyl( iv ) complexes polyoxovanadates( v have promising structural physicochemical characteristics for innovative bottom-up hybrid electronics.

Language: Английский

Citations

6
Electrochemical performance of polyoxometalate-based composite materials fabricated by a localization-coating strategy DOI

Peiqin Tang,

Xuan Li, Rui Liu

et al.

Colloids and Surfaces A Physicochemical and Engineering Aspects, Journal Year: 2025, Volume and Issue: 720, P. 137071 - 137071

Published: April 28, 2025

Language: Английский

Citations

0
POMSimulator: An open‐source tool for predicting the aqueous speciation and self–assembly mechanisms of polyoxometalates DOI Creative Commons
Enric Petrus, Jordi Buils, Diego Garay‐Ruiz

et al.

Journal of Computational Chemistry, Journal Year: 2024, Volume and Issue: 45(26), P. 2242 - 2250

Published: June 3, 2024

Abstract Elucidating the speciation (in terms of concentration versus pH) and understanding formation mechanisms polyoxometalates remains a significant challenge, both in experimental computational domains. POMSimulator is new methodology that tackles this problem from purely perspective. The uses results quantum mechanics based methods to automatically set up chemical reaction network, build models. As result, it becomes possible predict phase diagrams, as well derive insights into large molecular clusters. In work we present main features first open‐source version software. Since report [Chem. Sci. 2020, 11, 8448‐8456], has undergone several improvements keep with growing challenges were tackled. After four years research, recognize source code sufficiently stable share polished user‐friendly version. Python code, manual, examples, install instructions can be found at https://github.com/petrusen/pomsimulator .

Language: Английский

Citations

3
Huge Electron Sponge of Polyoxometalate toward Advanced Lithium-Ion Storage DOI

Peiqin Tang,

Rui Liu, Xuan Li

et al.

Langmuir, Journal Year: 2024, Volume and Issue: 40(27), P. 13860 - 13869

Published: June 26, 2024

The huge polyoxometalate, Na48[HxMo256VIMo112VO1032(H2O)240(SO4)48] ({Mo368}), which can be prepared by a facile solution process and applied in lithium-ion storage applications as the anode. large open hollow nanostructure is promising to store larger number of lithium ions expedite diffusion ions. A single {Mo368} nanocluster transfer 624 electrons, referred "huge electron sponge". Pure without any support materials exhibits very high capacities 964 mA h g–1 with hardly decay for 100 cycles at 0.1 still maintains 761 after 180 0.5 g–1, indicating great cycling stability. anode provides excellent rate performance reversibility during lithiation/delithiation processes, are contributed both diffusion-controlled capacitive process. contribution reach 71.7% scan 2 mV s–1. DLi+ value measured GITT confirms fast reaction kinetics electrode. {Mo368}//NCM111-A full cell practically light LED lamps. These investigations indicate that nanoclusters advanced energy capacities, charge transfer, low-cost mass production storage. Moreover, should considered clean material because there no environmental pollution charge/discharge processes.

Language: Английский

Citations

2
Molecular approach to semiconductors: a shift towards ecofriendly manufacturing and neuroinspired interfaces DOI
Kirill Yu. Monakhov, Christoph Meinecke, Marco Moors

et al.

Pure and Applied Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 13, 2024

Abstract Energy dissipation through physical downscaling towards more complex types of memory and logic devices, loss ultrapure water consumption large amounts (toxic) chemicals for wafer cleaning processes, as well high thermal budget solid-state synthesis thin film growth standard semiconductors including the use rare earth elements – all this poses great challenges semiconductor materials science technology. Therefore, research development alternative methods micro- nanofabrication chemical functionalization a new type resource- energy-efficient core component every computer chip is crucial. One promising opportunities transformation today’s complementary metal-oxide-semiconductor (CMOS) electronics into ecofriendly neuroinspired driven by molecular design multi-level switching mechanisms at room temperature. The sustainable technology electron transport in manufacturing devices with unconventional nanophysics, improved performance, augmented functionalities (beyond-CMOS More-than-Moore) becoming increasingly important context gradual transition to future-oriented concept Internet Everything (IoE). In article, we focus on technological significance preparation from single-source (molecular) precursors prospect functionalizing using DNA origami nanotechnology stimuli-responsive metal–oxygen cluster ions such polyoxometalates (POMs). We also describe advanced characterization these qualified systems soft X-rays. emphasize technical relevance solution-based bottom-up novel hybrid their challenging scalability compatibility lithography-based mass production. Our article aims contribute achievement United Nations’ Sustainable Development Goal 9 (Industry, Innovation Infrastructure).

Language: Английский

Citations

2