Development of a Water‐Based Pressure‐Sensitive Adhesive via Emulsion Polymerization for Packaging Tape Applications DOI

Nahide Kiral Çelik,

Tuğba Gürmen

ChemistrySelect, Journal Year: 2024, Volume and Issue: 9(37)

Published: Oct. 2, 2024

Abstract In this study, water‐based pressure‐sensitive adhesives (PSAs) were synthesized through an emulsion polymerization process using n ‐butyl acrylate, methacrylic acid, acrylic and N ‐vinylpyrrolidone monomers, in combination with anionic non‐ionic surfactants. The PSA was coated onto the corona‐treated surface of a BOPP film Mayer bar to prepare packaging tape. effect surfactant concentration on properties resulting copolymer investigated. chemical structure, component distribution, thermal behavior analyzed FTIR, HPLC, DSC. physical copolymer, such as solid content, viscosity, particle size, gel also determined. performance prepared tapes evaluated loop tack, 180° peel, holding shear time tests. results indicated that significantly affected adhesive's performance. Notably, use 2.5 wt% mixture yielded promising results, high monomer conversions excellent adhesion

Language: Английский

Water-based polymer colloids with a branched chain architecture as low-gel pressure-sensitive adhesives DOI Creative Commons
Emily M. Brogden, Stefan A. F. Bon

Polymer Chemistry, Journal Year: 2024, Volume and Issue: 15(28), P. 2849 - 2861

Published: Jan. 1, 2024

The performance of water-based acrylic pressure-sensitive adhesives was investigated. latex particles had minimal gel content, typically below a few percent, and the polymer chains exhibited branched architecture.

Language: Английский

Citations

4
Utilization of Bio-based Monomer Derived from Camelina Oil and Itaconic Acid for the Synthesis of Film-forming Latexes DOI Creative Commons
Martin Kolář, Jan Honzı́ček, Štěpán Podzimek

et al.

Journal of Polymers and the Environment, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 10, 2025

Language: Английский

Citations

0
Correlating Formulation and Performance in All‐Acrylic Waterborne Pressure Sensitive Adhesive Latexes DOI Open Access

Julie Bratasanu,

Victoria Aguilar,

Leila Issoufou Alfari

et al.

Macromolecular Chemistry and Physics, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 20, 2025

Abstract This work investigates the correlation between formulation of waterborne acrylic pressure‐sensitive adhesives (PSAs) and their resulting adhesive performance. A library n ‐butyl acrylate‐based latexes is synthesized via miniemulsion polymerization. Controlled variations in composition these polyacrylates – such as inclusion rigid comonomers, latent crosslinkers chain transfer agents enabled precise control over key network structures particles leading then to a range physical parameters cast PSA films glass transition temperature, entanglement crosslink density. The viscoelastic mechanical behaviors networks are carefully characterized using combination techniques, including linear rheology, dynamic analysis, tensile testing. These properties correlated with performance, measured by probe tack shear holding time tests. comprehensive approach allowed for identification optimal balance that delivers best compromises directly correlating outcomes macromolecular design.

Language: Английский

Citations

0
High Biobased Content Coatings and Pressure Sensitive Adhesives through Blends of Natural Rubber Latex and Tailored Acrylic Dispersions DOI Open Access

Manel Estany,

Romain Bentata,

Cécile Moussard

et al.

Macromolecular Chemistry and Physics, Journal Year: 2025, Volume and Issue: unknown

Published: March 26, 2025

Abstract Natural rubber latex is a widely available, biobased polymer dispersion but the mechanical properties limit its use in number of common applications colloidal polymers, such as coatings and adhesives. In this work, synthesis series acrylic latexes discussed, which are capable manipulating films cast from natural order to expand range potential applications. On one hand, isobornyl acrylate‐rich, hydroplasticizable containing methacrylic acid synthesized. Blends neutralized form these with lead phase‐separated film structure glassy domains poly(isobornyl acrylate)‐rich softer latex. This results an increase Young's modulus several orders magnitude, makes them interest for coatings. other when similar non‐hydroplasticizable acrylate) synthesized much lower molar mass, relatively high T g component low miscible, leading tackified system that displayed reasonable adhesive properties. These demonstrate route adhesives content.

Language: Английский

Citations

0
Recent Advances in Combining Waterborne Acrylic Dispersions with Biopolymers DOI Open Access

Jordi Solera-Sendra,

Nicholas Ballard, Luís J. del Valle

et al.

Polymers, Journal Year: 2025, Volume and Issue: 17(8), P. 1027 - 1027

Published: April 10, 2025

Water-based (meth)acrylic (co)polymer dispersions are produced on a large scale for various applications including coatings, adhesives, paints, and construction materials. A major benefit of waterborne polymer as compared to more traditional solvent-based alternatives is the low volatile organic compound (VOC) content, which results in an improved environmental profile. Following trend sustainability that has driven growth acrylic dispersions, recent research focused further enhancing properties these products by incorporating biobased materials such polysaccharides (e.g., cellulose, starch, chitin, chitosan), proteins casein, soy protein, collagen). Amongst number benefits, incorporation biomaterials can serve decrease amount petroleum-based polymers formulation also contribute enhance physical resulting bio-composites. In this review, beneficial role biopolymers when combined with systems summarized. Recent advances use biodegradable covered, aiming provide guidance development sustainable, high-performance latex-based bio-composites minimal impact.

Language: Английский

Citations

0
Development of Glass Nanofiber and Lanthanide Phosphor–Embedded Natural Polymer Nanocomposite Coating for Ultraviolet Filtering Smart Windows and Optical Data Encryption DOI
Salhah D. Al‐Qahtani, Ghadah M. Al‐Senani,

Maryam Aldoghaim

et al.

Luminescence, Journal Year: 2025, Volume and Issue: 40(5)

Published: April 27, 2025

ABSTRACT Glass nanofibers were prepared by using the electrospinning technology, demonstrating diameters of 50–150 nm. A smart polymer adhesive that has ability to glow in dark and resist water was developed from a hybrid electrospun glass (EGN; reinforcement fibers), rare‐earth aluminate (REA; photochromic agent), gum Arabic (GA; hosting matrix). After an excitation source is turned off, produced luminescent glue can continue produce light for up 100 min. The EGN@GA used immobilize nanoparticles REA ranging size 6 12 adhesives exhibited band at 365 nm emission intensity 518 Both fluorescence afterglow emissions tracked depending on concentration. presence photochromism confirmed when colorless film switched green upon exposure UV yellowish‐green place. scratch resistance hydrophobicity nanocomposites observed improve with increasing content. photostability durability REA/EGN@GA nanocomposite explored. current photoluminescent have several potential applications, including packaging, safety signs, security encoding.

Language: Английский

Citations

0
Novel Porous Composite Polydimethylsiloxane (PDMS) Thin Films with Cellulose Microfibers (CMFs) as Fillers for Adhesive Applications DOI
Swati A. Sonawane,

Kalyani B. Kulkarni,

Mahendra L. Bari

et al.

Silicon, Journal Year: 2024, Volume and Issue: 16(12), P. 5097 - 5108

Published: June 20, 2024

Language: Английский

Citations

1
Flexible metal foil/polymer sandwich composites for electromagnetic interference shielding with anti-wind–sand environment tolerance DOI

Longlong Xue,

Shisheng Xiong

Journal of Materials Science Materials in Electronics, Journal Year: 2024, Volume and Issue: 35(25)

Published: Sept. 1, 2024

Language: Английский

Citations

1
Physical Crosslinking of Aqueous Polymer Dispersions: A Perspective DOI
Nicholas Ballard, Nerea Jiménez,

José M. Asua

et al.

Particle & Particle Systems Characterization, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 10, 2024

Abstract Colloidal polymers, and in particular aqueous polymer dispersions, are widely used commercial applications such as coatings adhesives. Historically, the solvent resistance mechanical properties of these systems have been improved by covalently crosslinking chains after drying. More recently, work has directed toward replacing this covalent crosslinking, which typically involves highly reactive functional groups, physical through use supramolecular interactions. While conceptually similar to a unique influence on rheology polymer, leads substantial differences development strength during drying, well final film. In perspective, advantages challenges approach outlined, an outlook for future research direction is provided.

Language: Английский

Citations

1
Development of a Water‐Based Pressure‐Sensitive Adhesive via Emulsion Polymerization for Packaging Tape Applications DOI

Nahide Kiral Çelik,

Tuğba Gürmen

ChemistrySelect, Journal Year: 2024, Volume and Issue: 9(37)

Published: Oct. 2, 2024

Abstract In this study, water‐based pressure‐sensitive adhesives (PSAs) were synthesized through an emulsion polymerization process using n ‐butyl acrylate, methacrylic acid, acrylic and N ‐vinylpyrrolidone monomers, in combination with anionic non‐ionic surfactants. The PSA was coated onto the corona‐treated surface of a BOPP film Mayer bar to prepare packaging tape. effect surfactant concentration on properties resulting copolymer investigated. chemical structure, component distribution, thermal behavior analyzed FTIR, HPLC, DSC. physical copolymer, such as solid content, viscosity, particle size, gel also determined. performance prepared tapes evaluated loop tack, 180° peel, holding shear time tests. results indicated that significantly affected adhesive's performance. Notably, use 2.5 wt% mixture yielded promising results, high monomer conversions excellent adhesion

Language: Английский

Citations

1