Sulfur (S)‐Directed CH Functionalization DOI

Rui‐Peng Bao,

Nanqi Shao,

Fan Wang

et al.

Handbook of CH‐Functionalization, Journal Year: 2022, Volume and Issue: unknown, P. 1 - 32

Published: Nov. 29, 2022

Abstract The uses of sulfur (S) atoms as the directing groups for CH bond functionalization are summarized.

Language: Английский

Synthesis of 1,4-oxathiins via [3+3] annulation of pyridinium 1,4-zwitterionic thiolates with iodonium ylides DOI Creative Commons

Zhibin Niu,

Chao Pi, Yangjie Wu

et al.

Green Synthesis and Catalysis, Journal Year: 2024, Volume and Issue: unknown

Published: July 1, 2024

A straightforward and valuable approach for the synthesis of 1,4-oxathiins has been developed via [3 ​+ ​3] annulation pyridinium 1,4-zwitterionic thiolates with iodonium ylides. C–S C–O bonds were formed in one pot manner this transformation, which features readily available substrates, excellent tolerance functional groups mild reaction conditions. It would be great value construction biological pharmacological activity.

Language: Английский

Citations

0
Improve the Conductivity of CuBTC by in‐situ Reduction to Core‐Shell CuTCNQ@CuBTC DOI
Chunfeng Meng,

Hantao Chen,

Pinfei Hu

et al.

ChemistrySelect, Journal Year: 2020, Volume and Issue: 5(47), P. 15049 - 15054

Published: Dec. 17, 2020

Abstract In recent years, metal‐organic frameworks (MOFs) have been widely used in the fields of hydrogen storage, gas separation, catalysts, and so on. It is inspiring to apply MOFs field electrochemistry, whereas intrinsic low electric conductivity limits their promising future. Herein, a new approach improve electronic Cu‐MOF (CuBTC) developed, by adopting LiTCNQ solution as reductant generate CuTCNQ@CuBTC (BTC=1,3,5‐benzenetricarboxylic acid; TCNQ=7,7,8,8‐tetracyanoquinodimethane) core‐shell nanoparticles with conductive CuTCNQ shell non‐conductive CuBTC core, reaction conditions are optimized. Mutually validated data indicate that grows thicker higher temperature (60 °C) prolonged time (24 h). With this method, material effectively improved from 3.84×10 −9 2.94×10 −7 S cm −1 .

Language: Английский

Citations

3
Synthesis of diaryl sulfides based on copper-doped OMS-2 DOI Creative Commons

Shao-Qiang Yu,

Na Liu, Ming‐Guo Liu

et al.

Journal of Chemical Research, Journal Year: 2020, Volume and Issue: 45(3-4), P. 237 - 241

Published: Nov. 24, 2020

We describe a practical protocol for efficiently preparing diaryl sulfide compounds using Cu–OMS-2 as the catalyst. originates from manganese oxide octahedral molecular sieves modified with copper ions and catalyzes C–S coupling reaction of substituted thiophenols aryl halides. This has advantages environmental friendliness, simple operation, high yields, good tolerance functional groups, catalytic material can be recycled several times.

Language: Английский

Citations

2
Synthesis of 2,3-dihydro-1,4-benzoxathiine derivatives DOI

Jun Dong,

Jiaxi Xu

Chemistry of Heterocyclic Compounds, Journal Year: 2022, Volume and Issue: 58(6-7), P. 271 - 278

Published: July 1, 2022

Language: Английский

Citations

1
Sulfur (S)‐Directed CH Functionalization DOI

Rui‐Peng Bao,

Nanqi Shao,

Fan Wang

et al.

Handbook of CH‐Functionalization, Journal Year: 2022, Volume and Issue: unknown, P. 1 - 32

Published: Nov. 29, 2022

Abstract The uses of sulfur (S) atoms as the directing groups for CH bond functionalization are summarized.

Language: Английский

Citations

0