Current Organic Chemistry,
Journal Year:
2024,
Volume and Issue:
28(4), P. 241 - 285
Published: Feb. 1, 2024
Abstract:
Organic
natural
materials
like
chitosan,
cellulose,
starch,
agarose,
and
alginate
possess
unique
structures
that
are
useful
in
creating
advanced
nanostructured
materials.
These
highly
catalysis
because
of
their
numerous
functional
groups
catalytic
properties.
They
can
also
be
combined
with
inorganic
to
create
"nano-
Biocomposites"
specialized
properties
utilized
as
catalysts
multicomponent
reactions.
This
review
provides
an
overview
the
use
nano-Biocomposites
reactions
(MCRs).
ChemistrySelect,
Journal Year:
2023,
Volume and Issue:
8(35)
Published: Sept. 15, 2023
Abstract
Three
distorted
square
antiprismatic
eight
coordinated
neodymium
acylpyrazolone
complexes
were
synthesized
having
the
compositions
[Nd(L
1
)
3
(H
2
O)(EtOH)]
(
NdL
),
and
).
The
structure
of
all
three
was
examined
using
ESI‐mass,
FT‐IR,
thermogravimetric
methods.
According
to
single
crystal
analysis
,
complex
found
‐
(NdO8)
with
a
geometry.
A
powder
XRD
pattern
confirmed
similar
structural
arrangement
other
two
complexes.
In
electronic
absorption
spectra,
transition
4
G
5/2
←
I
9/2
which
is
close
centre
visible
spectrum
(~17,500
cm
−1
exhibits
hypersensitivity,
stands
out
in
stark
contrast
behaviour
many
typically
weak
reliably
unchanging,
typical
4f–4f
transitions.
Through
comparative
calculated
oscillator
strength,
Judd‐Ofelt
parameters,
root
mean
deviation,
radiative
lifetime
covalency
parameters
various
solvents,
symmetry
characteristics,
have
been
thoroughly
investigated.
promotion
electric‐dipole
intensity
has
be
particularly
successful
ethanol,
pyridine,
DMF,
DMSO.
Utilizing
Ω
values
Hirshfeld
analysis,
long‐range
secondary
π⋅⋅⋅π
stacking
or
H‐bonding
interactions
emission
quantum
yield,
stokes
shift,
antenna
effect
energy
diagram
solid‐state
spectra.
Current Organic Chemistry,
Journal Year:
2024,
Volume and Issue:
28(4), P. 241 - 285
Published: Feb. 1, 2024
Abstract:
Organic
natural
materials
like
chitosan,
cellulose,
starch,
agarose,
and
alginate
possess
unique
structures
that
are
useful
in
creating
advanced
nanostructured
materials.
These
highly
catalysis
because
of
their
numerous
functional
groups
catalytic
properties.
They
can
also
be
combined
with
inorganic
to
create
"nano-
Biocomposites"
specialized
properties
utilized
as
catalysts
multicomponent
reactions.
This
review
provides
an
overview
the
use
nano-Biocomposites
reactions
(MCRs).