Fe‐Catalyzed C‐N/C‐S Bonds Formation via Activation of Csp3‐H Bond of Methylarenes: A Straightforward Tandem Oxidative Process to Access Benzazoles DOI Open Access

Fatemeh Bigdelizadeh,

Dariush Khalili, Jasem Aboonajmi

et al.

Applied Organometallic Chemistry, Journal Year: 2025, Volume and Issue: 39(4)

Published: March 25, 2025

ABSTRACT Fe‐catalyzed tandem cross‐dehydrogenative coupling of the methylarenes with o ‐phenylenediamine/2‐aminothiophenol as partners has been developed for synthesis benzimidazoles and benzothiazoles. Various 2‐aryl benzimidazoles/thiazoles were synthesized high efficiency from cost‐effective raw materials using tert ‐butyl hydroperoxide (TBHP) an environmentally benign oxidant without any co‐promoter additional oxidizing reagent.

Language: Английский

Fe‐Catalyzed C‐N/C‐S Bonds Formation via Activation of Csp3‐H Bond of Methylarenes: A Straightforward Tandem Oxidative Process to Access Benzazoles DOI Open Access

Fatemeh Bigdelizadeh,

Dariush Khalili, Jasem Aboonajmi

et al.

Applied Organometallic Chemistry, Journal Year: 2025, Volume and Issue: 39(4)

Published: March 25, 2025

ABSTRACT Fe‐catalyzed tandem cross‐dehydrogenative coupling of the methylarenes with o ‐phenylenediamine/2‐aminothiophenol as partners has been developed for synthesis benzimidazoles and benzothiazoles. Various 2‐aryl benzimidazoles/thiazoles were synthesized high efficiency from cost‐effective raw materials using tert ‐butyl hydroperoxide (TBHP) an environmentally benign oxidant without any co‐promoter additional oxidizing reagent.

Language: Английский

Citations

0