SmartMat,
Journal Year:
2022,
Volume and Issue:
4(3)
Published: Dec. 31, 2022
Abstract
The
performance
of
asymmetric
supercapacitors
(ASCs)
is
strongly
restricted
by
the
capacity
gap
between
positive
and
negative
electrodes.
To
address
this
issue,
two
new
electrode
materials
deriving
from
Co‐
Fe‐based
metal–organic
frameworks
(MOFs,
Co‐TAMBA‐d,
Fe‐TAMBA‐d)
through
a
single‐step
sintering
method
have
been
developed
considering
superiorities
derivatives
MOFs
including
large
surface
areas,
sufficient
metal‐atom‐doping
content,
extreme
wettability
to
bath
solution.
as‐prepared
Co‐TAMBA‐d
as
delivers
typical
pseudocapacitive
behavior
with
improvement
capacity,
which
better
than
those
pristine
MOF
materials,
while
Fe‐TAMBA‐d
electrodes
displays
electrochemical
activated
carbon.
ASCs
based
on
these
exhibits
excellent
energy
density
power
47
W
h/kg
1658
W/kg,
respectively,
where
device
can
maintain
prominent
cycling
stability
retention
after
5000
cycles
being
about
75%.
Furthermore,
feed
series
red
light‐emitting
diodes,
gives
solid
evidence
potential
utilization.
These
results
afford
feasibility
isostructural
promising
in
novel
ASCs.
Carbon Energy,
Journal Year:
2022,
Volume and Issue:
4(2), P. 246 - 281
Published: March 1, 2022
Abstract
Because
of
features,
such
as
adjustable
structures,
high
porosity,
and
crystallinity,
metal–organic
frameworks
(MOFs)
deservedly
have
received
considerable
attention.
Nevertheless,
there
is
still
room
for
improvements
in
the
electrical
conductivity
chemical
stability
some
MOFs,
because
which
they
cannot
be
utilized
electrode
materials.
Fortunately,
MOF
derivatives
widespread
attention
recent
years,
especially
phosphide
materials,
are
widely
used
practical
applications
their
outstanding
conductivity,
excellent
specific
surface
area,
standout
charge
mobility.
In
this
review,
latest
developments
MOF‐derived
phosphides
electrocatalysis
related
to
energy,
including
performance
terms
electrochemical
energy
storage
ingenious
strategies,
diversified
synthetic
approaches
been
emphasized
summarized.
Additionally,
arduous
task
feasible
proposals
also
discussed.
Journal of Materials Chemistry A,
Journal Year:
2022,
Volume and Issue:
10(22), P. 12225 - 12234
Published: Jan. 1, 2022
Morphology
and
interfacial
engineering
of
heterogeneous
MOF/MXene
hierarchically-porous
nanorods
on
Ni
foam
deliver
exceptional
robust
stability
energy
density
in
hybrid
supercapacitor
application.
Small,
Journal Year:
2023,
Volume and Issue:
19(23)
Published: March 6, 2023
Nanocomposites
containing
Ni
or
Co
NiCo
alloy
and
nitrogen-doped
carbon
with
diverse
ratios
have
been
prepared
utilized
as
active
elements
in
supercapacitors.
The
atomic
contents
of
nitrogen,
nickel,
cobalt
adjusted
by
the
supplement
amount
salts.
In
virtue
excellent
surface
groups
rich
redox
sites,
NC/NiCo
materials
exhibit
superior
electrochemical
charge-storage
performances.
Among
these
as-prepared
electrode
materials,
NC/NiCo1/1
performs
better
than
other
bimetallic/carbon
electrodes
pristine
metal/carbon
electrodes.
Several
characterization
methods,
kinetic
analyses,
nitrogen-supplement
strategies
determine
specific
reason
for
this
phenomenon.
As
a
result,
performance
can
be
ascribed
to
combination
factors
including
high
area
nitrogen
content,
proper
Co/Ni
ratio,
relatively
low
average
pore
size.
delivers
maximum
capacity
300.5
C
g-1
retention
92.30%
after
3000
unceasing
charge-discharge
cycles.
After
assembling
it
into
battery-supercapacitor
hybrid
device,
energy
density
26.6
Wh
kg-1
(at
412
W
)
is
achieved,
comparable
recent
reports.
Furthermore,
device
also
power
four
light-emitting-diode
(LED)
demos,
suggesting
potential
practicability
N-doped
compositing
bimetallic
materials.
Dalton Transactions,
Journal Year:
2023,
Volume and Issue:
52(7), P. 1962 - 1969
Published: Jan. 1, 2023
A
3D
Mn-based
MOF
[Mn(BGPD)(H
2
O)
]
(Mn-BGPD)
was
synthesized.
The
asymmetrical
supercapacitor
of
Mn-BGPD
exhibits
an
excellent
energy
density
and
better
cycling
stability.
Energy & Fuels,
Journal Year:
2023,
Volume and Issue:
37(5), P. 4000 - 4009
Published: Feb. 20, 2023
The
emerging
supercapattery
imparts
optimum
electrochemical
performance
by
synchronizing
the
admirable
power
density
and
cyclic
stability
of
supercapacitors
with
high
energy
characteristic
batteries.
strong
bonds
a
metal
center
an
organic
linker
give
rise
to
unique
group
porous
materials
known
as
metal–organic
frameworks
(MOFs).
Here,
we
state
synthesis
analyzation
copper-MOF
cobalt-MOF.
initial
specific
capacity
revealed
in
three-electrode
assembly
for
Cu-MOF
Co-MOF
is
451
103
C
g–1
at
3
mV
s–1,
respectively.
Owing
favorable
characteristics
Cu-MOF,
device
fabricated
Cu-MOF//activated
carbon.
exhibits
densities
41
Wh
2400
W
kg–1,
respectively,
reversible
retention
92%
coulombic
efficiency
99%.
Moreover,
elucidate
capacitive
diffusive
contributions
battery–supercapacitor,
Dunn's
model
adapted.
properties
electrode
battery-grade
material
may
be
adapted
future
storage
applications.