eScience,
Journal Year:
2024,
Volume and Issue:
4(3), P. 100231 - 100231
Published: Jan. 21, 2024
Stimuli-responsive
coordination
polymers
(CPs)
are
among
one
of
the
most
prolific
research
areas
in
developing
next-generation
functional
materials.
Their
capability
being
accurately
excited
by
particular
external
changes
with
pre-determined
and
observable/characterizable
behaviours
correspond,
so
called
"stimuli"
"responsive".
Abundant
types
CP
compounds,
especially
metal-organic
frameworks
(MOFs),
rocketing
interest
owing
to
their
compositional
diversity,
structural
tunability,
essence
highly
engineerable
functionality.
This
present
review
is
aimed
sketch
several
common
stimulation
corresponding
responses
for
CPs,
accompanied
broad
logic
mechanisms
underneath.
And
further
from
aspect
material
revolution,
some
representative
progresses
together
latest
advances
CP-based
materials
various
fields
covered
attempt
display
a
broader
picture
towards
possible
prospects
this
topic.
Sensors International,
Journal Year:
2021,
Volume and Issue:
2, P. 100121 - 100121
Published: Jan. 1, 2021
Sensor
technologies
have
improved
the
everyday
life
of
human
beings
through
their
applications
in
almost
all
fields.
Sensors
are
devices
that
detect
changes
source/environment
and
collect
signals,
accordingly,
reaction
is
designed.
There
a
range
sources,
including
light,
temperature,
movements,
pressure
etc.,
which
may
be
used.
A
wide
utilised
using
innovative
sensor
lifestyle,
healthcare,
fitness,
manufacturing,
daily
life.
In
medical
field,
difficulty
to
take
medicine
eased
by
drug
donors
fitted
with
sensors.
It
reminds
them
via
signal
also
supply
necessary
at
specified
moment.
health
care,
older
individuals,
athletes,
risk
patients
benefit
from
modern
technology.
The
current
industrial
trends
driving
innovation
include
ultrasound,
radar,
non-contact
optoelectronic
solutions
laser
paper
gives
brief
overview
numerous
types
sensors
Various
capabilities
for
day-to-day
healthcare
discussed.
features,
associated
nomenclature,
measures
routine
discussed
diagrammatically
finally,
identifies
discusses
twenty-two
significant
produce
vital
information
exchange
data
other
connected
administration
systems
when
linked
network.
Thus,
effective
running
many
companies,
critical.
used
our
life,
more
accurate
makes
quicker
analysis.
Chemical Science,
Journal Year:
2022,
Volume and Issue:
13(47), P. 13978 - 14007
Published: Jan. 1, 2022
MOF-based
optical
sensors
can
achieve
volatile
organic
compound
sensing
via
different
mechanisms:
colorimetric
sensing,
luminescent
and
optical-index
modulation
sensing.
Nanoscale Advances,
Journal Year:
2022,
Volume and Issue:
4(9), P. 2077 - 2089
Published: Jan. 1, 2022
This
review
summarizes
the
representative
works
of
MOFs
for
gas
adsorption/separation
in
recent
years,
analyses
host–guest
interaction,
structure–performance
relations,
and
mechanism.
Angewandte Chemie International Edition,
Journal Year:
2023,
Volume and Issue:
62(35)
Published: July 7, 2023
Solvothermal
reaction
of
5,5'-(pyridine-2,6-diylbis(oxy))diisophthalic
acid
(H4
L)
with
europium(III)
or
terbium(III)
nitrates
in
acetonitrile-water
(1
:
1)
at
120
°C
gave
rise
to
isostructural
2D
coordination
polymers,
[Ln(HL)(H2
O)3
]∞
(NIIC-1-Eu
and
NIIC-1-Tb),
the
layers
which
are
composed
by
eight-coordinated
lanthanide(III)
ions
interconnected
triply
deprotonated
ligands
HL3-
.
The
packed
crystal
without
any
specific
intermolecular
interactions
between
them,
allowing
facile
preparation
stable
water
suspensions,
NIIC-1-Tb
exhibited
top-performing
sensing
properties
through
luminescence
quenching
effect
exceptionally
low
detection
limits
towards
Fe3+
(LOD
8.62
nM),
ofloxacin
(OFX)
antibiotic
3.91
nM)
cotton
phytotoxicant
gossypol
2.27
nM).
In
addition
limit
high
selectivity,
features
fast
response
(within
60-90
seconds),
making
it
superior
other
MOF-based
sensors
for
metal
cations
organic
toxicants.
photoluminescence
quantum
yield
was
93
%,
one
highest
among
lanthanide
MOFs.
Mixed-metal
polymers
NIIC-1-Eux
Tb1-x
demonstrated
efficient
photoluminescence,
color
could
be
modulated
excitation
wavelength
time
delay
emission
monitoring
1
millisecond).
Furthermore,
an
original
QR-coding
scheme
designed
anti-counterfeiting
labeling
goods
based
on
unique
tunable
spectra
NIIC-1-Ln
polymers.
ACS Omega,
Journal Year:
2023,
Volume and Issue:
8(10), P. 9004 - 9030
Published: Feb. 28, 2023
In
previous
years,
different
pollutants,
for
example,
organic
dyes,
antibiotics,
heavy
metals,
pharmaceuticals,
and
agricultural
have
been
of
note
to
the
water
enterprise
due
their
insufficient
reduction
during
standard
wastewater
processing
methods.
MOFs
found
potential
toward
management.
This
Review
focused
on
synthesis
process
(such
as
traditional,
electrochemical,
microwave,
sonochemical,
mechanochemical,
continuous-flow
spray-drying
method)
MOF
materials.
Moreover,
properties
materials
discussed
in
detail.
Further,
materials'
applications
treatment
removal
metal
ions,
waste)
discussed.
Additionally,
we
compared
performances
some
typical
MOFs-based
with
those
other
commonly
used
Finally,
study's
current
challenges,
future
prospects,
outlook
highlighted.
Global Challenges,
Journal Year:
2023,
Volume and Issue:
8(2)
Published: Dec. 30, 2023
Abstract
Metal‐organic
frameworks
(MOFs)
that
are
the
wonder
material
of
21st
century
consist
metal
ions/clusters
coordinated
to
organic
ligands
form
one‐
or
more‐dimensional
porous
structures
with
unprecedented
chemical
and
structural
tunability,
exceptional
thermal
stability,
ultrahigh
porosity,
a
large
surface
area,
making
them
an
ideal
candidate
for
numerous
potential
applications.
In
this
work,
recent
progress
in
design
synthetic
approaches
MOFs
explore
their
applications
fields
gas
storage
separation,
catalysis,
magnetism,
drug
delivery,
chemical/biosensing,
supercapacitors,
rechargeable
batteries
self‐powered
wearable
sensors
based
on
piezoelectric
triboelectric
nanogenerators
summarized.
Lastly,
work
identifies
present
challenges
outlines
future
opportunities
field,
which
can
provide
valuable
references.
Molecules,
Journal Year:
2022,
Volume and Issue:
27(14), P. 4529 - 4529
Published: July 15, 2022
Enzymatic
biocatalysis
is
a
sustainable
technology.
Enzymes
are
versatile
and
highly
efficient
biocatalysts,
have
been
widely
employed
due
to
their
biodegradable
nature.
However,
because
the
three-dimensional
structure
of
these
enzymes
predominantly
maintained
by
weaker
non-covalent
interactions,
external
conditions,
such
as
temperature
pH
variations,
well
presence
chemical
compounds,
can
modify
or
even
neutralize
biological
activity.
The
enablement
this
category
processes
result
several
advances
in
areas
molecular
biology
biotechnology
achieved
over
past
two
decades.
In
scenario,
metal–organic
frameworks
(MOFs)
highlighted
supports
for
enzyme
immobilization.
They
be
used
‘house’
specific
enzyme,
providing
it
with
protection
from
environmental
influences.
This
review
discusses
MOFs
structures;
emphasizes
synthesis
strategies,
properties,
applications;
explores
existing
methods
using
immobilization
various
enzymes;
lists
possible
modifications
combinations
other
compounds
formulate
ideal
given
application.
Advanced Functional Materials,
Journal Year:
2022,
Volume and Issue:
32(41)
Published: Sept. 13, 2022
Abstract
Hydrogen‐bonded
organic
frameworks
(HOFs)
have
aroused
interest
due
to
their
applications
in
gas
storage
and
separation
proton
conduction.
Much
effort
has
been
focused
on
developing
stable
HOFs
with
permanent
porosity.
Recently,
more
attention
paid
the
development
of
luminescent
HOFs.
At
present,
a
systematic
study
is
lacking.
Here,
recent
advances
are
highlighted.
The
construction
HOFs,
properties
corresponding
discussed
detail.
According
properties,
can
be
divided
into
fluorescent
room‐temperature
phosphorescent
In
addition,
color‐tunable
luminescence,
stimuli‐responsive
or
mechanoluminescence
also
introduced
at
great
length.
These
distinctive
features
endow
wide
chemical
sensing,
microlasers,
oxygen
data
encryption,
so
on.
This
review
not
only
provides
basic
principle
designing
but
points
out
research
perspectives
future.
lays
foundation
for
thus
broadening
enriching
porous
materials.