Advanced Composites and Hybrid Materials, Journal Year: 2024, Volume and Issue: 7(1)
Published: Feb. 1, 2024
Language: Английский
Advanced Composites and Hybrid Materials, Journal Year: 2024, Volume and Issue: 7(1)
Published: Feb. 1, 2024
Language: Английский
Catalysis Today, Journal Year: 2024, Volume and Issue: 429, P. 114505 - 114505
Published: Jan. 2, 2024
The photoelectrochemical reduction of CO2 to value-added products represents a promising strategy for mitigating emissions. However, further research efforts need be undertaken enable the technology scale-up, including design and fabrication efficient photoelectrodes capable yielding substantial photogenerated current densities. In this work, photoanode combining commercial calcium titanate perovskite (CaTiO3) BiVO4 layers coated onto transparent FTO substrate by automated spray pyrolysis is proposed. Different configurations are tested, with most favourable results achieved when positioned as top layer back illumination. optimization catalytic loading also assessed, finding an optimal at 1 mg cm-2 CaTiO3 3 BiVO4, resulting in impressive density –71 mA –1.8 V vs. Ag/AgCl. This then integrated into electrolyzer continuous visible light-driven gas phase formate, obtaining concentration 63.8 g L-1, Faradaic Efficiency 79.1%, solar-to-fuel conversion efficiency 7.6%. These represent significant advancement development photoanodes, offering promise future scalability processes.
Language: Английский
Citations
11Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 349, P. 123895 - 123895
Published: April 24, 2024
Language: Английский
Citations
11Materials Today Chemistry, Journal Year: 2024, Volume and Issue: 36, P. 101924 - 101924
Published: Jan. 24, 2024
Language: Английский
Citations
10Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 352, P. 124023 - 124023
Published: April 21, 2024
Language: Английский
Citations
10Advanced Composites and Hybrid Materials, Journal Year: 2024, Volume and Issue: 7(1)
Published: Feb. 1, 2024
Language: Английский
Citations
9