Crystalline–Amorphous Interface Coupling of Ni3S2/NiPx/NF with Enhanced Activity and Stability for Electrocatalytic Oxygen Evolution DOI
Xinyu Wang, Xu Yu, Shuang Wu

et al.

ACS Applied Materials & Interfaces, Journal Year: 2023, Volume and Issue: 15(12), P. 15533 - 15544

Published: March 15, 2023

The rational design of highly efficient and stable electrocatalysts for the oxygen evolution reaction (OER) is an urgent need but remains challenging various sustainable energy systems. How to adjust atomic structure electronic active center a key bottleneck problem. Accelerating electron transfer process deep self-reconstruction sites could be cost-effective strategy toward electrocatalytic OER catalyst development. Here, crystalline-amorphous (c-a) coupled Ni3S2/NiPx electrocatalyst self-supported on nickel foam with intimate interface was developed via feasible solvothermal-electrochemistry method. coupling crystalline high conductivity amorphous numerous potential regulate optimize adsorption/desorption O-containing species, ultimately resulting in catalytic performance. obtained Ni3S2/NiPx/NF presents low overpotential 265 mV obtain 10 mA·cm-2 small Tafel slope 51.6 mV·dec-1. Also, exhibited significantly enhanced long-term stability compared other two catalysts, <5% decay activity over 20 h continuous operation, while that Ni3S2/NF NiPx/NF decreased by about 30 50%, respectively. This study provides inspiration conversion reactions optimizing performance catalysts structures.

Language: Английский

A review of modulation strategies for improving catalytic performance of transition metal phosphides for oxygen evolution reaction DOI

Chen‐Jin Huang,

Huimin Xu,

Ting‐Yu Shuai

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2022, Volume and Issue: 325, P. 122313 - 122313

Published: Dec. 21, 2022

Language: Английский

Citations

150
Design of modified MOFs electrocatalysts for water splitting: High current density operation and long-term stability DOI
Yangping Zhang, Xiangjun Zheng, Xingmei Guo

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2023, Volume and Issue: 336, P. 122891 - 122891

Published: May 18, 2023

Language: Английский

Citations

112
High-performance seawater oxidation by a homogeneous multimetallic layered double hydroxide electrocatalyst DOI Creative Commons
Luo Yu, Jiayong Xiao, Chuqiang Huang

et al.

Proceedings of the National Academy of Sciences, Journal Year: 2022, Volume and Issue: 119(18)

Published: April 27, 2022

SignificanceSeawater is one of the most abundant resources on Earth. Direct electrolysis seawater a transformative technology for sustainable hydrogen production without causing freshwater scarcity. However, this severely impeded by lack robust and active oxygen evolution reaction (OER) electrocatalysts. Here, we report highly efficient OER electrocatalyst composed multimetallic layered double hydroxides, which affords superior catalytic performance long-term durability high-performance electrolysis. To best our knowledge, catalyst among it advances development technology.

Language: Английский

Citations

104
Noble Metal Phosphides Supported on CoNi Metaphosphate for Efficient Overall Water Splitting DOI

Bingrong Guo,

Jianying Zhao, Yao Xü

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(7), P. 8939 - 8948

Published: Feb. 9, 2024

Transition metal metaphosphates and noble phosphides prepared under similar conditions are potential hybrid catalysts for electrocatalytic water splitting, which is of great significance H2 production. Herein, the structure activity different species (i.e., Rh, Pd, Ir) on CoNiP4O12 nanoarrays have been systematically studied. Due to formation energies phosphides, Rh (RhPx) Pd (PdPx) as well Ir obtained same phosphorylation perspectively. RhPx/CoNiP4O12 PdPx/CoNiP4O12 exhibit much better HER than Ir/CoNiP4O12 due advantages phosphides. Density functional theory (DFT) calculations reveal that extraordinary originated from strong affinity H2O optimal adsorption H*. The best only requires a low overpotential 30 234 mV deliver 10 mA cm–2 OER, respectively, therefore effective overall splitting (requiring 1.57 V achieve current density cm–2). This work not develops novel electrocatalyst but also provides deep insight into mechanism

Language: Английский

Citations

94
Strategies for enhancing the catalytic activity and electronic conductivity of MOFs-based electrocatalysts DOI

Peiyun Zhou,

Junjun Lv, Xiubing Huang

et al.

Coordination Chemistry Reviews, Journal Year: 2022, Volume and Issue: 478, P. 214969 - 214969

Published: Dec. 14, 2022

Language: Английский

Citations

90
Constructing oxygen vacancy-rich MXene @Ce-MOF composites for enhanced energy storage and conversion DOI
Shuke Li,

Hanrui Chai,

Ling Zhang

et al.

Journal of Colloid and Interface Science, Journal Year: 2023, Volume and Issue: 642, P. 235 - 245

Published: March 21, 2023

Language: Английский

Citations

84
Surface reconstruction of Se-doped NiS2 enables high-efficiency oxygen evolution reaction DOI
Mengxin Chen, Yuanyuan Zhang, Ran Wang

et al.

Journal of Energy Chemistry, Journal Year: 2023, Volume and Issue: 84, P. 173 - 180

Published: May 22, 2023

Language: Английский

Citations

72
Unveiling the Adsorption Behavior and Redox Properties of PtNi Nanowire for Biomass-Derived Molecules Electrooxidation DOI
Jingcheng Wu, Zhijie Kong, Yingying Li

et al.

ACS Nano, Journal Year: 2022, Volume and Issue: 16(12), P. 21518 - 21526

Published: Dec. 7, 2022

Ni-based materials are auspicious electrocatalysts for 5-hydroxymethylfurfural oxidation reaction (HMFOR), including the adsorption and conversion of HMF OHad on electrocatalyst surface. However, intrinsic HMFOR activity catalysts is far from satisfactory due to weak species. Herein, a set PtxNi100-x bundle nanowires (NWs) were prepared HMFOR, which enables low onset-potential large current density. Operando methods reveal that Pt modulates redox property Ni in PtNi NWs accelerates Ni2+-OH Ni3+-O species during HMFOR. Moreover, studies demonstrate synergetic roles enhancing by forming Pt-O-Ni bonds. In detail, atoms modulate d band alter behavior HMF. promote sites. This work provides design principles modulating behaviors organic molecules OHad.

Language: Английский

Citations

71
Strong phosphide-metaphosphate interaction in RuP/CoNiP4O12 for enhanced electrocatalytic water splitting DOI
Jianying Zhao, Yuanyuan Zhang, Yu Xia

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2023, Volume and Issue: 328, P. 122447 - 122447

Published: Feb. 10, 2023

Language: Английский

Citations

65
Iron Oxyhydroxide: Structure and Applications in Electrocatalytic Oxygen Evolution Reaction DOI

Bingrong Guo,

Haohao Huo,

Qixuan Zhuang

et al.

Advanced Functional Materials, Journal Year: 2023, Volume and Issue: 33(25)

Published: March 10, 2023

Abstract Oxygen evolution reaction (OER) is the anodic half‐reaction for crucial energy devices, such as water electrolysis, metal–air battery, and electrochemical CO 2 reduction. Fe‐based materials are recognized one of most promising electrocatalysts OER because its extremely low price high activity. In particular, iron oxyhydroxide (FeOOH) not only highly active toward OER, but also widely accepted true species plenty converted into FeOOH during test. Herein, recent advances FeOOH‐based nano‐structure application in reviewed. The relationship between structure catalytic performance, followed by introduction current strategies enhancing activity (i.e., crystalline phase engineering, element doping, construction hybrid materials) mainly focused. Finally, a summary perspective about remaining challenges future opportunities this area further design provided.

Language: Английский

Citations

61