Understanding and Tuning the Effects of H2O on Catalytic CO and CO2 Hydrogenation DOI
Mingrui Wang, Guanghui Zhang, Hao Wang

et al.

Chemical Reviews, Journal Year: 2024, Volume and Issue: 124(21), P. 12006 - 12085

Published: Oct. 31, 2024

Catalytic COx (CO and CO2) hydrogenation to valued chemicals is one of the promising approaches address challenges in energy, environment, climate change. H2O an inevitable side product these reactions, where its existence effect are often ignored. In fact, significantly influences catalytic active centers, reaction mechanism, performance, preventing us from a definitive deep understanding on structure-performance relationship authentic catalysts. It necessary, although challenging, clarify provide practical strategies tune concentration distribution optimize influence. this review, we focus how induces structural evolution catalysts assists processes, as well efforts understand underlying mechanism. We summarize discuss some representative tuning for realizing rapid removal or local enrichment around catalysts, along with brief techno-economic analysis life cycle assessment. These fundamental understandings further extended reactions CO CO2 reduction under external field (light, electricity, plasma). also present suggestions prospects deciphering controlling applications.

Language: Английский

Construction of a hierarchical BiOBr/C3N4 S-scheme heterojunction for selective photocatalytic CO2 reduction towards CO DOI
Wei Tao,

Qiaoya Tang,

Jianqiang Hu

et al.

Journal of Materials Chemistry A, Journal Year: 2023, Volume and Issue: 11(45), P. 24999 - 25007

Published: Jan. 1, 2023

A hierarchical S-scheme heterojunction photocatalyst was fabricated through the in situ growth of BiOBr nanosheets on microtubular C 3 N 4 , which demonstrates excellent photocatalytic activity for converting CO 2 into under visible light irradiation.

Language: Английский

Citations

23
Single-site cobalt catalyst embedded in a covalent triazine-based framework (CTF) for photocatalytic CO2 reduction DOI
Anupam Jana,

Arijit Maity,

Abhimanyu Sarkar

et al.

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(9), P. 5244 - 5253

Published: Jan. 1, 2024

Single-site Co-embedded CTF-TPE exhibits high photocatalytic CO 2 conversion to with a production rate of 945 μmol g −1 h .

Language: Английский

Citations

14
A molecular view of single-atom catalysis toward carbon dioxide conversion DOI Creative Commons
Xin Shang,

Xiaofeng Yang,

Ye Liu

et al.

Chemical Science, Journal Year: 2024, Volume and Issue: 15(13), P. 4631 - 4708

Published: Jan. 1, 2024

We present critical advances in single-atom catalysis toward CO 2 transformation and address crucial issues about SACs from a molecular point of view.

Language: Английский

Citations

13
Graphitic carbon nitride/La, Rh co-doped SrTiO3 S-scheme heterojunction for photocatalytic CO2 reduction DOI

Sijie Wan,

Yan-Ting Hou,

Wang Wang

et al.

Rare Metals, Journal Year: 2024, Volume and Issue: 43(11), P. 5880 - 5890

Published: July 6, 2024

Language: Английский

Citations

13
Understanding and Tuning the Effects of H2O on Catalytic CO and CO2 Hydrogenation DOI
Mingrui Wang, Guanghui Zhang, Hao Wang

et al.

Chemical Reviews, Journal Year: 2024, Volume and Issue: 124(21), P. 12006 - 12085

Published: Oct. 31, 2024

Catalytic COx (CO and CO2) hydrogenation to valued chemicals is one of the promising approaches address challenges in energy, environment, climate change. H2O an inevitable side product these reactions, where its existence effect are often ignored. In fact, significantly influences catalytic active centers, reaction mechanism, performance, preventing us from a definitive deep understanding on structure-performance relationship authentic catalysts. It necessary, although challenging, clarify provide practical strategies tune concentration distribution optimize influence. this review, we focus how induces structural evolution catalysts assists processes, as well efforts understand underlying mechanism. We summarize discuss some representative tuning for realizing rapid removal or local enrichment around catalysts, along with brief techno-economic analysis life cycle assessment. These fundamental understandings further extended reactions CO CO2 reduction under external field (light, electricity, plasma). also present suggestions prospects deciphering controlling applications.

Language: Английский

Citations

11