Rejuvenating manganese-based rechargeable batteries: fundamentals, status and promise DOI
Weizhai Bao, Hao Shen, Yangyang Zhang

et al.

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(15), P. 8617 - 8639

Published: Jan. 1, 2024

Energy storage devices with advanced rechargeable batteries are highly demanded by our modern society.

Language: Английский

Filling carbon: a microstructure-engineered hard carbon for efficient alkali metal ion storage DOI
Xiaoyang Chen,

Nurbiye Sawut,

Kean Chen

et al.

Energy & Environmental Science, Journal Year: 2023, Volume and Issue: 16(9), P. 4041 - 4053

Published: Jan. 1, 2023

Carbonaceous materials are the most promising anodes for alkali metal-ion batteries (AMIBs); however, it is still a great challenge to construct carbonaceous with elaborate microstructures achieve superior electrochemical performance.

Language: Английский

Citations

149

Recent advances in rational design for high-performance potassium-ion batteries DOI
Yifan Xu, Yichen Du,

Han Chen

et al.

Chemical Society Reviews, Journal Year: 2024, Volume and Issue: 53(13), P. 7202 - 7298

Published: Jan. 1, 2024

The growing global energy demand necessitates the development of renewable solutions to mitigate greenhouse gas emissions and air pollution. To efficiently utilize yet intermittent sources such as solar wind power, there is a critical need for large-scale storage systems (EES) with high electrochemical performance. While lithium-ion batteries (LIBs) have been successfully used EES, surging price, coupled limited supply crucial metals like lithium cobalt, raised concerns about future sustainability. In this context, potassium-ion (PIBs) emerged promising alternatives commercial LIBs. Leveraging low cost potassium resources, abundant natural reserves, similar chemical properties potassium, PIBs exhibit excellent ion transport kinetics in electrolytes. This review starts from fundamental principles structural regulation PIBs, offering comprehensive overview their current research status. It covers cathode materials, anode electrolytes, binders, separators, combining insights full battery performance, degradation mechanisms,

Language: Английский

Citations

146

Routes to high-performance layered oxide cathodes for sodium-ion batteries DOI
Jingqiang Wang,

Yan‐Fang Zhu,

Yu Su

et al.

Chemical Society Reviews, Journal Year: 2024, Volume and Issue: 53(8), P. 4230 - 4301

Published: Jan. 1, 2024

Various optimization strategies are reviewed and summarized to formulate design principles for layered oxide cathodes sodium-ion batteries.

Language: Английский

Citations

140

The Distance Between Phosphate‐Based Polyanionic Compounds and Their Practical Application For Sodium‐Ion Batteries DOI Open Access
Zhiqiang Hao, Xiaoyan Shi, Zhuo Yang

et al.

Advanced Materials, Journal Year: 2023, Volume and Issue: 36(7)

Published: Aug. 18, 2023

Abstract Sodium‐ion batteries (SIBs) are a viable alternative to meet the requirements of future large‐scale energy storage systems due uniform distribution and abundant sodium resources. Among various cathode materials for SIBs, phosphate‐based polyanionic compounds exhibit excellent sodium‐storage properties, such as high operation voltage, remarkable structural stability, superior safety. However, their undesirable electronic conductivities specific capacities limit application in systems. Herein, development history recent progress cathodes first overviewed. Subsequently, effective modification strategies summarized toward high‐performance including surface coating, morphological control, ion doping, electrolyte optimization. Besides, electrochemical performance, cost, industrialization analysis SIBs discussed accelerating commercialization development. Finally, directions comprehensively concluded. It is believed that this review can provide instructive insight into developing practical SIBs.

Language: Английский

Citations

113

Vacancy designed 2D materials for electrodes in energy storage devices DOI
Rajesh Kumar, Sumanta Sahoo, Ednan Joanni

et al.

Chemical Communications, Journal Year: 2023, Volume and Issue: 59(41), P. 6109 - 6127

Published: Jan. 1, 2023

Vacancies are ubiquitous in nature, usually playing an important role determining how a material behaves, both physically and chemically.

Language: Английский

Citations

69

A novel Na8Fe5(SO4)9@rGO cathode material with high rate capability and ultra-long lifespan for low-cost sodium-ion batteries DOI Creative Commons
Changyu Liu,

Kean Chen,

Huiqian Xiong

et al.

eScience, Journal Year: 2023, Volume and Issue: 4(1), P. 100186 - 100186

Published: Sept. 13, 2023

Sodium-ion batteries (SIBs) are regarded as the most promising technology for large-scale energy storage systems. However, practical application of SIBs is still hindered by lack applicable cathode materials. Herein, novel phase-pure polyanionic Na8Fe5(SO4)9 designed and employed a material first time. The has an alluaudite-type sulfate framework small Na+ ion diffusion barriers. As expected, as-synthesized Na8Fe5(SO4)9@rGO exhibits high working voltage 3.8 V (versus Na/Na+), superior reversible capacity 100.2 mAh g–1 at 0.2 C, excellent rate performance (∼80 10 ∼63 50 C), ultra-long cycling life (91.9% retention after 10,000 cycles 81% 20,000 C). We use various techniques computational methods to comprehensively investigate material's electrochemical reaction mechanisms.

Language: Английский

Citations

66

Facilitating Layered Oxide Cathodes Based on Orbital Hybridization for Sodium‐Ion Batteries: Marvelous Air Stability, Controllable High Voltage, and Anion Redox Chemistry DOI

Xin‐Bei Jia,

Jingqiang Wang, Yi‐Feng Liu

et al.

Advanced Materials, Journal Year: 2023, Volume and Issue: 36(15)

Published: Nov. 1, 2023

Layered oxides have become the research focus of cathode materials for sodium-ion batteries (SIBs) due to low cost, simple synthesis process, and high specific capacity. However, poor air stability, unstable phase structure under voltage, slow anionic redox kinetics hinder their commercial application. In recent years, concept manipulating orbital hybridization has been proposed simultaneously regulate microelectronic modify surface chemistry environment intrinsically. this review, modes between atoms in 3d/4d transition metal (TM) orbitals O 2p near region Fermi energy level (E

Language: Английский

Citations

64

Recent Progress of Promising Cathode Candidates for Sodium‐Ion Batteries: Current Issues, Strategy, Challenge, and Prospects DOI Creative Commons
Chenxi Peng, Xijun Xu,

Fangkun Li

et al.

Small Structures, Journal Year: 2023, Volume and Issue: 4(10)

Published: June 22, 2023

Lithium‐ion batteries (LIBs) have dominated the secondary market in past few decades. However, their widespread application is seriously hampered by limited lithium resource and high cost. Recently, sodium‐ion (SIBs) generated significant attention because of characteristics abundant raw sources, low cost, similar “rocking chair” mechanism with LIBs, which hold great potential large‐scale energy storage. Cathode materials excellent electrochemical performance are urgent demand for next‐generation SIBs. Herein, this review provides a comprehensive overview recent advances most promising SIBs cathode candidates, including layered oxides, polyanionic materials, Prussian blue analogues. The currently existing issues that need to be addressed these cathodes pointed out, such as insufficient density, electron conductivity, air sensitivity, so on. This also details structural three candidates. Moreover, optimization strategies improving summarized, element doping, morphology modification, structure architecture, Finally, current research status proposed future developmental directions concluded. aims provide practical guidance development

Language: Английский

Citations

58

Boosting Multielectron Reaction Stability of Sodium Vanadium Phosphate by High-Entropy Substitution DOI
Zhiqiang Hao, Xiaoyan Shi, Wenqing Zhu

et al.

ACS Nano, Journal Year: 2024, Volume and Issue: 18(13), P. 9354 - 9364

Published: March 22, 2024

Na3V2(PO4)3 (NVP) based on the multielectron reactions between V2+ and V5+ has been considered a promising cathode for sodium-ion batteries (SIBs). However, it still suffers from unsatisfactory stability, caused by poor reversibility of V5+/V4+ redox couple structure evolution. Herein, we propos strategy that combines high-entropy substitution electrolyte optimization to boost reversible NVP. The high crystalline evolution are disclosed in situ X-ray absorption near-edge spectra diffraction. Meanwhile, electrochemical reaction kinetics NVP (HE-NVP) can be further improved diglyme-based electrolyte. These enable HE-NVP deliver superior performance (capacity retention 93.1% after 2000 cycles; large capacity 120 mAh g–1 even at 5.0 A g–1). Besides, long cycle life power density HE-NVP∥natural graphite full-cell configuration demonstrated superiority SIBs. This work highlights synergism is powerful enhance sodium-storage polyanionic cathodes

Language: Английский

Citations

53

Magnesium ion-doped layered oxide cathodes for alkali-metal ion batteries: Recent research progress and outlook DOI

Haowei Tang,

Liping Duan, Jiaying Liao

et al.

Energy storage materials, Journal Year: 2023, Volume and Issue: 62, P. 102935 - 102935

Published: Aug. 19, 2023

Language: Английский

Citations

51