Accounts of Chemical Research,
Journal Year:
2023,
Volume and Issue:
56(20), P. 2763 - 2775
Published: Sept. 26, 2023
ConspectusCarbon
capture
is
an
indispensable
step
toward
closing
the
anthropogenic
carbon
cycle.
However,
large-scale
implementation
of
conventional
thermochemical
technologies
hindered
by
their
low
energy
efficiency,
limited
sorbent
stability,
and
complexity
in
infrastructure
integration.
A
mechanistically
different
alternative,
commonly
known
as
electrochemically
mediated
(EMCC),
has
garnered
increasing
research
traction
over
past
few
years
relies
on
electrochemical
stimuli
instead
thermal
or
pressure
swings
for
release
dioxide
(CO2).
Compared
to
methods,
EMCC
can
be
operated
under
mild
conditions
driven
intermittent
renewable
sources
a
flexible
design
meet
multiscale
demands
capture,
offering
potentially
sustainable,
energy-efficient,
cost-effective
solution
CO2
concentration
from
dilute
mixtures
ambient
environment.Nanomaterials
have
played
crucial
role
research.
For
instance,
nanoporous
materials
provide
increased
free
volumes,
surface
areas,
active
sites
through
physical
chemical
adsorption
gaseous
phase.
In
contrast,
absorption
via
acid–base
interactions
using
solubilized
electrolytes.
Therefore,
most
sorbents
mediators
explored
so
far
been
developed
molecules
rather
than
nanomaterials.
recent
years,
our
team
focusing
electrifying
processes
at
molecular,
materials,
process
levels.
We
seek
address
pressing
issues
associated
with
EMCC,
either
fixed-bed
flow
systems,
that
prevent
practical
use.
These
include
parasitic
reactions
molecular
oxygen,
insufficient
electrode
capacity
utilization,
crossover,
etc.
To
these
problems,
there
urgent
need
develop
rationally
designed
nanomaterials
interface
electrochemistry
device
engineering.
This
Account
provides
overview
progress
developing
new
chemistries
engineering
batch/continuous
EMCC.
discuss
limitations
current
technology
emphasize
why
are
critical
capture.
First,
we
introduce
principles
based
redox-active
organic
carriers
metrics
performance
evaluation.
Second,
showcase
how
tackle
problems
solubility,
oxygen
electrolyte
compatibility
Third,
early
results
solid
nonswelling
membranes
high-surface-area
gas–liquid
contactors.
Finally,
building
foundation
established
prior
work,
offer
perspectives
future
directions
help
challenges
Sustainability,
Journal Year:
2023,
Volume and Issue:
15(14), P. 10891 - 10891
Published: July 11, 2023
Nanomaterials
have
gained
significant
attention
as
a
remarkable
class
of
materials
due
to
their
unique
properties
and
the
fact
that
they
encompass
wide
range
samples
with
at
least
one
dimension
ranging
from
1
100
nm.
The
deliberate
design
nanoparticles
enables
achievement
extremely
large
surface
areas.
In
field
cost-effective
electrochemical
devices
for
energy
storage
conversion
applications,
nanomaterials
emerged
key
area
research.
Their
exceptional
physical
chemical
led
extensive
investigations
aimed
improving
performance
cost-effectiveness
devices,
including
batteries,
supercapacitors,
fuel
cells.
continuous
development
enhancement
these
high-performance
are
driven
by
demand
enhanced
productivity,
connectivity,
sustainability
reduced
cost.
This
review
focuses
on
electrodes,
storage,
sensors
(ES)
based
nanotechnology.
It
discusses
application
nanotechnology
in
electrochemistry
water
purification
fate
substances
water,
while
also
introducing
green
cost-effective,
high-fidelity
product
creation
through
methods.
study
emphasizes
synthesis
novel
nanomaterials,
such
metal–organic
frameworks
(MOFs),
covalent
organic
(COFs),
MXenes,
applications
devices.
Furthermore,
it
explores
integration
nanostructures
systems
economically
future
along
challenges
faced
nanotechnology-based
industries.
paper
interplay
between
biosensors,
which
play
vital
role
Overall,
this
provides
comprehensive
overview
significance
conversion.
highlights
need
further
research
rapidly
evolving
serves
valuable
resource
researchers
engineers
interested
latest
advancements
Journal of Polymer Science,
Journal Year:
2023,
Volume and Issue:
62(8), P. 1517 - 1535
Published: Aug. 2, 2023
Abstract
Hyper‐crosslinked
polymers
(HCPs)
are
a
family
of
that
possess
several
desirable
characteristics,
including
high
specific
surface
area,
excellent
stability,
tunable
porous
structures,
and
low‐cost
reagents.
As
result,
HCPs
have
gained
significant
attention
in
the
areas
gas
storage,
adsorption,
catalysis,
separation,
carbon
precursors,
exhibiting
advanced
performances
catalytic
energy‐related
applications.
Recently,
researchers
explored
potential
biomedical
engineering.
In
this
review,
we
discuss
classical
synthesis
strategies
morphological
assembly
methods
used
to
create
with
unique
biological
properties.
We
also
highlight
latest
advances
emerging
HCPs,
such
as
drug
delivery,
antimicrobial,
bioimaging,
biosensing.
By
providing
various
examples,
further
correlations
between
morphologies,
enhanced
properties
HCPs.
Finally,
summarize
key
applications
provide
an
outlook
on
research
direction
encourage
development
biomedically
available
Overall,
offer
promising
new
class
materials
for
use
applications,
continued
field
will
lead
exciting
discoveries
breakthroughs.
Chemical Society Reviews,
Journal Year:
2024,
Volume and Issue:
53(4), P. 2056 - 2098
Published: Jan. 1, 2024
Non-CO
2
greenhouse
gas
mitigation
and
recovery
with
advanced
porous
materials
(MOFs,
COFs,
HOFs,
POPs,
etc.
)
would
significantly
contribute
to
achieving
carbon
neutrality
gain
economic
benefits
concurrently.
Industrial & Engineering Chemistry Research,
Journal Year:
2024,
Volume and Issue:
63(8), P. 3443 - 3464
Published: Feb. 14, 2024
CO2
capture
and
conversion
have
garnered
worldwide
attention
in
view
of
the
objective
sustainable
development
carbon
neutrality.
Recently,
ionic
liquid-functionalized
metal–organic
frameworks
(MOFs)
or
covalent–organic
(COFs)
(MOFs/COFs)
offer
a
rising
platform
for
effective
separation
from
specific
gas
mixture
into
value-added
chemicals.
Benefiting
synergistic
effect
offered
by
ILs
MOFs/COFs,
IL-MOFs/COFs
exhibit
better
exceptional
adsorption/catalytic
performance
than
pristine
MOFs/COFs
ILs.
Herein,
review
intends
to
establish
primary
database
recently
emerging
conversion,
covering
functionalization
strategies,
interaction
between
representative
applications,
aiding
rational
design
optimization
novel
with
properties
real-world
application.
Along
this
line,
different
systems
(CO2/N2,
CO2/CH4,
CO2/C2H2)
further
multiproducts
(cyclic
carbonate,
hydrocarbon,
alcohol,
others),
along
mechanism
insight
such
processes
are
summarized
discussed.
Furthermore,
challenges
prospects
topical
fields
been
elaborated.
Macromolecular Symposia,
Journal Year:
2024,
Volume and Issue:
413(1)
Published: Feb. 1, 2024
Abstract
Membrane–based
gas
separation
has
become
an
important
research
field
for
sustainable
energy
and
environmental
applications.
Gas
is
one
of
the
key
steps
in
refineries
other
gas‐related
industries.
Over
last
two
decades,
on
extended
porous
organic
inorganic
materials
such
as
zeolites,
metal–organic
frameworks
(MOFs),
covalent–organic
(COFs),
their
hybrids
increased
continuously.
These
have
garnered
significant
interest
due
to
structural
flexibility
pronounced
porosity,
which
offer
excellent
potential
adsorption
processes
industrial
settings.
As
such,
this
review
aimed
provide
in‐depth
analysis
recent
developments
MOFs,
COFs,
MOF–COF
hybrid‐based
membranes
separation,
highlighting
practical
It
also
offers
a
comprehensive
understanding
some
most
critical
advanced
used
compared
common
polymers.
In
addition,
membranes'
concepts,
efficiency,
cost‐effectiveness
are
discussed
detail.
Advanced Materials,
Journal Year:
2024,
Volume and Issue:
36(19)
Published: Jan. 30, 2024
Abstract
3D
covalent
organic
frameworks
(3D
COFs)
constitute
a
new
type
of
crystalline
materials
that
consist
range
porous
structures
with
numerous
applications
in
the
fields
adsorption,
separation,
and
catalysis.
However,
because
complexity
three‐periodic
net
structure,
it
is
desirable
to
develop
thorough
structural
comprehension,
along
means
precisely
determine
actual
structure.
Indeed,
such
advancements
would
considerably
contribute
rational
design
application
COFs.
In
this
review,
reported
topologies
COFs
are
introduced
categorized
according
configurations
their
building
blocks,
comprehensive
overview
diffraction‐based
determination
methods
provided.
The
current
challenges
future
prospects
for
these
will
also
be
discussed.
