Nanoscale,
Journal Year:
2024,
Volume and Issue:
16(8), P. 4047 - 4055
Published: Jan. 1, 2024
A
“top
down”
strategy
for
the
transformation
of
Co
NPs
to
SAs
was
proposed
and
synthesized
SAs/CNF
electrocatalyst
exhibited
excellent
electrocatalytic
NO
3
RR
activity
with
a
FE
91.30%
at
−0.70
V
vs.
RHE.
Advanced Materials,
Journal Year:
2023,
Volume and Issue:
36(17)
Published: June 9, 2023
Natural
nitrogen
cycle
has
been
severely
disrupted
by
anthropogenic
activities.
The
overuse
of
N-containing
fertilizers
induces
the
increase
nitrate
level
in
surface
and
ground
waters,
substantial
emission
oxides
causes
heavy
air
pollution.
Nitrogen
gas,
as
main
component
air,
used
for
mass
ammonia
production
over
a
century,
providing
enough
nutrition
agriculture
to
support
world
population
increase.
In
last
decade,
researchers
have
made
great
efforts
develop
processes
under
ambient
conditions
combat
intensive
energy
consumption
high
carbon
associated
with
Haber-Bosch
process.
Among
different
techniques,
electrochemical
reduction
reaction
(NO
Advanced Functional Materials,
Journal Year:
2023,
Volume and Issue:
33(43)
Published: June 25, 2023
Abstract
Ammonia
as
an
irreplaceable
chemical
has
been
widely
demanded
to
keep
the
sustainable
development
of
modern
society.
However,
its
industrial
production
consumes
huge
energy
and
releases
extraordinary
green‐house
gases,
leading
various
environmental
issues.
To
achieve
green
ammonia
is
a
great
challenge
that
extensively
pursued
recently.
In
review,
most
promising
strategy,
electrochemical
nitrate
reduction
reaction
(e‐NO
3
RR)
for
purpose
comprehensively
investigated
give
full
understanding
mechanism
provide
guidance
future
directions.
Particularly,
electrocatalysts
focused
realize
high
yield
rate
Faraday
efficiency
applications.
The
recent‐developed
catalysts,
including
noble
metallic
materials,
alloys,
metal
compounds,
single‐metal‐atom
metal‐free
are
systematically
discussed
review
effects
factors
on
catalytic
performance
in
e‐NO
RR.
Accordingly,
strategies,
defects
engineering,
coordination
environment
modulating,
surface
controlling,
hybridization,
carefully
improve
performance,
such
intrinsic
activity
selectivity.
Finally,
perspectives
challenges
given
out.
This
shall
insightful
advanced
systems
efficiently
industry.
Energy & Environmental Science,
Journal Year:
2023,
Volume and Issue:
16(7), P. 2991 - 3001
Published: Jan. 1, 2023
Laser-constructed
CuNi
alloy
electrodes
with
tandem
sites
of
Ni
provide
H*
and
Cu
for
NO
3
−
reduction,
achieving
ampere-level
reduction
high-performance
Zn–NO
batteries.
Angewandte Chemie International Edition,
Journal Year:
2023,
Volume and Issue:
62(42)
Published: June 14, 2023
Dual-atom
catalysts
(DACs)
have
been
a
new
frontier
in
heterogeneous
catalysis
due
to
their
unique
intrinsic
properties.
The
synergy
between
dual
atoms
provides
flexible
active
sites,
promising
enhance
performance
and
even
catalyze
more
complex
reactions.
However,
precisely
regulating
site
structure
uncovering
dual-atom
metal
interaction
remain
grand
challenges.
In
this
review,
we
clarify
the
significance
of
inter-metal
DACs
based
on
understanding
center
structures.
Three
diatomic
configurations
are
elaborated,
including
isolated
single-atom,
N/O-bridged
dual-atom,
direct
dual-metal
bonding
interaction.
Subsequently,
up-to-date
progress
oxidation
reactions,
hydrogenation/dehydrogenation
electrocatalytic
photocatalytic
reactions
summarized.
structure-activity
relationship
catalytic
is
then
discussed
at
an
atomic
level.
Finally,
challenges
future
directions
engineer
discussed.
This
review
will
offer
prospects
for
rational
design
efficient
toward
catalysis.
Angewandte Chemie International Edition,
Journal Year:
2024,
Volume and Issue:
63(31)
Published: May 21, 2024
Abstract
The
electrochemical
nitrate
reduction
reaction
(NO
3
RR)
is
able
to
convert
−
)
into
reusable
ammonia
(NH
),
offering
a
green
treatment
and
resource
utilization
strategy
of
wastewater
synthesis.
conversion
NO
NH
undergoes
water
dissociation
generate
active
hydrogen
atoms
nitrogen‐containing
intermediates
hydrogenation
tandemly.
two
relay
processes
compete
for
the
same
sites,
especially
under
pH‐neutral
condition,
resulting
in
suboptimal
efficiency
selectivity
electrosynthesis
from
.
Herein,
we
constructed
Cu
1
‐Fe
dual‐site
catalyst
by
anchoring
single
on
amorphous
iron
oxide
shell
nanoscale
zero‐valent
(nZVI)
RR,
achieving
an
impressive
removal
94.8
%
99.2
neutral
pH
concentration
50
mg
L
−1
−N
conditions,
greatly
surpassing
performance
nZVI
counterpart.
This
superior
can
be
attributed
synergistic
effect
enhanced
adsorption
Fe
sites
strengthened
activation
single‐atom
decreasing
energy
barrier
rate‐determining
step
*NO‐to‐*NOH.
work
develops
novel
fabricating
catalysts
enhance
,
presents
environmentally
sustainable
approach
treatment.
Advanced Science,
Journal Year:
2024,
Volume and Issue:
11(33)
Published: July 1, 2024
Abstract
Modifying
the
coordination
or
local
environments
of
single‐,
di‐,
tri‐,
and
multi‐metal
atom
(SMA/DMA/TMA/MMA)‐based
materials
is
one
best
strategies
for
increasing
catalytic
activities,
selectivity,
long‐term
durability
these
materials.
Advanced
sheet
supported
by
metal
atom‐based
have
become
a
critical
topic
in
fields
renewable
energy
conversion
systems,
storage
devices,
sensors,
biomedicine
owing
to
maximum
utilization
efficiency,
precisely
located
centers,
specific
electron
configurations,
unique
reactivity,
precise
chemical
tunability.
Several
offer
excellent
support
are
attractive
applications
energy,
medical
research,
such
as
oxygen
reduction,
production,
hydrogen
generation,
fuel
selective
detection,
enzymatic
reactions.
The
strong
metal–metal
metal–carbon
with
metal–heteroatom
(i.e.,
N,
S,
P,
B,
O)
bonds
stabilize
optimize
electronic
structures
atoms
due
interfacial
interactions,
yielding
activities.
These
provide
models
understanding
fundamental
problems
multistep
This
review
summarizes
substrate
structure‐activity
relationship
different
active
sites
based
on
experimental
theoretical
data.
Additionally,
new
synthesis
procedures,
physicochemical
characterizations,
biomedical
discussed.
Finally,
remaining
challenges
developing
efficient
SMA/DMA/TMA/MMA‐based
presented.
Angewandte Chemie International Edition,
Journal Year:
2024,
Volume and Issue:
63(48)
Published: Sept. 3, 2024
Abstract
Intramolecular
charge
separation
driving
force
and
linkage
chemistry
between
building
blocks
are
critical
factors
for
enhancing
the
photocatalytic
performance
of
metal‐covalent
organic
framework
(MCOF)
based
photocatalyst.
However,
robust
achieving
both
simultaneously
has
yet
to
be
challenging
despite
ongoing
efforts.
Here
we
develop
a
fully
π‐conjugated
vinylene‐linked
multivariate
donor‐π‐acceptor
MCOF
(D‐π‐A,
termed
UJN‐1)
by
integrating
benzyl
cyanides
linker
with
multiple
functional
electron‐rich
triphenylamine
electron‐deficient
copper‐cyclic
trinuclear
units
(Cu‐CTUs)
moieties,
featuring
strong
intramolecular
force,
extended
conjugation
degree
skeleton,
abundant
active
sites.
The
incorporation
Cu‐CTUs
acceptor
electron‐withdrawing
ability
concomitantly
giant
can
efficiently
accelerate
photogenerated
electrons
transfer
from
Cu‐CTUs,
revealing
experiments
theoretical
calculations.
Benefiting
synergistically
effect
D‐π‐A
configuration
vinylene
linkage,
highly‐efficient
spatial
is
achieved.
Consequently,
UJN‐1
exhibits
an
excellent
CO
formation
rate
114.8
μmol
g
−1
in
4
h
without
any
co‐catalysts
or
sacrificial
reagents
under
visible
light,
outperforming
those
analogous
MCOFs
imine‐linked
(UJN‐2,
28.9
)
COF
Cu‐CTU
sites
(UJN‐3,
50.0
),
emphasizing
role
designing
novel
COFs‐based