Published: Jan. 1, 2024
Language: Английский
Advanced Energy Materials, Journal Year: 2024, Volume and Issue: 14(17)
Published: Feb. 15, 2024
Abstract As an ideal candidate for the next generation of large‐scale energy storage devices, sodium‐ion batteries (SIBs) have received great attention due to their low cost. However, practical utility SIBs faces constraints imposed by geographical and environmental factors, particularly in high‐altitude cold regions. In these areas, low‐temperature (LT) performance presents a pressing technological challenge that requires significant breakthroughs. LT environments, electrochemical reaction kinetics are sluggish, electrode/electrolyte interface is unstable, diffusion sodium ions electrode materials slow, leading decrease battery performance. Therefore, reasonable design electrolyte significance optimizing SIBs. this review, research progress electrolytes, cathode, anode materials, as well metal solid‐state electrolytes systematically summarized recent years, aiming understand principles SIBs, clarify basic development high‐performance applications, promote technology full temperature range.
Language: Английский
Citations
79
Energy & Environmental Science, Journal Year: 2023, Volume and Issue: 16(11), P. 4759 - 4811
Published: Jan. 1, 2023
This review comprehensively summarizes the operation fundamentals of SMBs in different environments and proposes various targeted optimization strategies.
Language: Английский
Citations
72
Advanced Materials, Journal Year: 2024, Volume and Issue: 36(25)
Published: March 8, 2024
Abstract Room‐temperature sodium‐sulfur (RT‐Na/S) batteries are promising alternatives for next‐generation energy storage systems with high density and power density. However, some notorious issues hampering the practical application of RT‐Na/S batteries. Besides, working mechanism under conditions such as sulfur loading, lean electrolyte, low capacity ratio between negative positive electrode (N/P ratio), is essential importance applications, yet significance these parameters has long been disregarded. Herein, it comprehensively reviewed recent advances on Na metal anode, S cathode, separator engineering The discrepancies laboratory research elaborately discussed, endeavors toward applications highlighted, suggestions values crucial rationally proposed. Furthermore, an empirical equation to estimate actual pouch cells proposed first time, making possible evaluate gravimetric conditions. This review aims reemphasize vital bridge gaps applications.
Language: Английский
Citations
30
Energy & Environmental Science, Journal Year: 2024, Volume and Issue: 17(15), P. 5365 - 5386
Published: Jan. 1, 2024
Various liquid electrolyte designs for low-temperature LMBs/SMBs.
Citations
20
Energy & Environmental Science, Journal Year: 2023, Volume and Issue: 17(2), P. 442 - 496
Published: Nov. 16, 2023
This review provides the understanding and development of Na metal anodes for liquid-based solid-state batteries.
Language: Английский
Citations
35
Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown
Published: Aug. 5, 2024
Abstract Sodium metal is regarded as an optimal anode material for high‐energy‐density sodium‐ion batteries (SIBs). However, during the processes of sodium deposition and stripping, failure solid electrolyte interphase (SEI) film leads to continuous accumulation inactive sodium, thereby compromising cycling reversibility battery. Here, a novel fluoride heterointerface layer generated constructed through in situ manipulation reaction between TiF 4 Na. The reconstructed NaF/TiF 3 interface layer, which tightly anchors metal, effectively suppresses formation dendrites charge‐discharge process. highly sodium‐philic component exhibits strong binding with Na ions, while NaF reduces + diffusion energy barrier, significantly enhancing kinetics. Due successful artificial construction this Na/TiF composite electrode demonstrates exceptional ultra‐long stability 2370 h symmetric cells (0.5 mAh cm −2 ). Density functional theory (DFT) calculations further validate functionality each protective layer. When paired NaNi 1/3 Fe Mn O 2 cathode pouch cell, it up 2000 cycles at current densities C C, maximum density output 483.1 Wh kg −1 (power density: 320.8 W
Language: Английский
Citations
11
Nano Energy, Journal Year: 2023, Volume and Issue: 120, P. 109185 - 109185
Published: Dec. 12, 2023
Language: Английский
Citations
14
Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(28), P. 17222 - 17228
Published: Jan. 1, 2024
A multiphase artificial interphase layer can induce homogeneous deposition of Na + and promote rapid transport . Therefore, the BiCl 3 -Na anode achieves uniform dendrite-free improves electrochemical performance.
Language: Английский
Citations
5
Batteries, Journal Year: 2023, Volume and Issue: 9(7), P. 345 - 345
Published: June 27, 2023
Nature-abundant sodium metal is regarded as ideal anode material for advanced batteries due to its high specific capacity of 1166 mAh g−1 and low redox potential −2.71 V. However, the uncontrollable dendritic Na formation coulombic efficiency remain major obstacles application. Notably, unstable inhomogeneous solid electrolyte interphase (SEI) recognized be root cause. As SEI layer plays a critical role in regulating uniform deposition improving cycling stability, modification, especially artificial has been extensively investigated recently. In this regard, we discuss advances interface engineering from aspects inorganic, organic hybrid inorganic/organic protective layers. We also highlight key prospects further investigations.
Language: Английский
Citations
11
Nano Energy, Journal Year: 2024, Volume and Issue: 132, P. 110348 - 110348
Published: Oct. 9, 2024
Citations
4