Interface engineering and anion etching facilitating electronic modulation and surface reconstruction of FeSe@NiSe heterostructure catalysts to promote water splitting DOI
Jie Han,

Miaomiao Bai,

Taotao Ai

et al.

Rare Metals, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 11, 2024

Language: Английский

Nanoengineering of P, Se co-doped hollow microspheres induced charge redistribution with P-Se-M bond as multifunctional electrocatalysts DOI
Zhiwei Lu, Zhang Lan,

Qianqian Xiong

et al.

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 686, P. 218 - 231

Published: Jan. 31, 2025

Language: Английский

Citations

1
Revealing the Tandem Behavior of Iron‐Group/Copper Binary Catalysts in the Electroreduction of Nitrate to Ammonia DOI Open Access

Qiuyu Yan,

Rundong Zhao, Chen Huang

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 16, 2025

Abstract As a green strategy for both ammonia (NH 3 ) production and wastewater purification, electrochemical reduction of nitrate (NO RR) faces challenges due to the nitrite 2 − accumulation competitive hydrogen evolution reaction (HER). Tandem catalysis NO NH offers great potential enhancing selectivity. Herein, iron‐group (Fe, Co, or Ni) nanosheets are introduced onto Cu nanowires construct Cu‐Fe, Cu‐Co, Cu‐Ni tandem systems respectively. Specifically, sites facilitate conversion . Fe sites, similar Cu, reduce , exacerbating rather than converting it their inability precisely capture Co exhibiting excellent moderate HER activity, can seamlessly operate with realize well‐ordered relay catalysis, which achieves superior yield rate 48.44 mg h −1 cm −2 Ni demonstrate removal capability at low overpotentials, leading Faraday efficiency 99.47%. However, its remarkable HER‐active property demonstrated via in situ polarization imaging makes challenge ampere‐level current densities. This work identifies behavior coupled providing reference design further optimization system.

Language: Английский

Citations

1
Interface Engineering Induced Multi‐Scale Self‐Assembly NiFe‐LDH Heterostructures for High‐Performance Water Electrolysis DOI
Chun Han, Yuan Yuan, Chen Gong

et al.

ChemSusChem, Journal Year: 2024, Volume and Issue: unknown

Published: June 7, 2024

Confronted with the pressing issue of energy scarcity, development an economical and potent bifunctional catalyst is paramount importance. We adopt interface engineering strategy to modify surface NiFe-LDH nanoplates O

Language: Английский

Citations

7
Facilitating active NiOOH formation via Mo doping towards high-efficiency oxygen evolution DOI
Liuqing Wang, Jinsheng Li, Qinglei Meng

et al.

Catalysis Science & Technology, Journal Year: 2024, Volume and Issue: 14(15), P. 4166 - 4173

Published: Jan. 1, 2024

The promotion effects of Mo doping into NiFe layered double hydroxide were revealed as facilitated NiOOH generation, tailored *OH adsorption, and improved dehydrogenation, which enabled enhanced activity durability towards water oxidation.

Language: Английский

Citations

5
Increased Readiness for Water Splitting: NiO‐Induced Weakening of Bonds in Water Molecules as Possible Cause of Ultra‐Low Oxygen Evolution Potential DOI Creative Commons

Tom Bookholt,

Xian Qin, Bettina Lilli

et al.

Small, Journal Year: 2024, Volume and Issue: 20(30)

Published: Feb. 22, 2024

Abstract The development of non‐precious metal‐based electrodes that actively and stably support the oxygen evolution reaction (OER) in water electrolysis systems remains a challenge, especially at low pH levels. recently published study has conclusively shown addition haematite to H 2 SO 4 is highly effective method significantly reducing overpotential extending anode life. far superior result achieved by concentrating centres on oxide particles rather than electrode. However, unsatisfactory Faradaic efficiencies OER hydrogen (HER) parts as well required high load impede applicability upscaling this process. Here it same performance with three times less metal powder if NiO/H suspensions are used along stainless steel anodes. reason for enormous improvement adding NiO electrolyte weakening intramolecular O─H bond molecules, which under direct influence nickel suspended electrolyte. manipulation bonds molecules increase tendency split ground‐breaking development, first example.

Language: Английский

Citations

4
Short-time potentiostatic assisted borate to induce the generation of ultrathin NiFe LDH active phase for industrial-level water oxidation DOI
Yu Ma, J. Wang, Xiaohan Liu

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 490, P. 151490 - 151490

Published: April 21, 2024

Language: Английский

Citations

4
A Review of Plasma Treatment on Nano-Microstructure of Electrochemical Water Splitting Catalysts DOI
Tianli Hui,

Zheng Tao,

Xiaoluo Cheng

et al.

Chinese Journal of Structural Chemistry, Journal Year: 2025, Volume and Issue: unknown, P. 100520 - 100520

Published: Jan. 1, 2025

Language: Английский

Citations

0
Insight into the Facilitated surface reconstruction of NiFe layered double hydroxide by constructing heterostructures with Prussian blue analogues for enhanced oxygen evolution reaction DOI

Ruiqian Zhang,

Xinyi Sun,

Binbin Qian

et al.

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: unknown, P. 137413 - 137413

Published: March 1, 2025

Language: Английский

Citations

0
Fe/Ce Codoped Ni2P Catalyst to Enhance Alkaline Oxygen Evolution Reaction DOI

Luo Zhao,

Li Wang,

Ruijie Shi

et al.

ACS Applied Energy Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 7, 2025

Language: Английский

Citations

0
Built‐In Electric Field in 2D/2D LDH/Antimonene Heterostructure to Induce Stable β‐NiOOH at Ultralow Potential for Cost‐Effective Water Electrolysis DOI Creative Commons
Jingkun Wang, Xiaoning Li, Haojie Liang

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 15, 2025

Abstract NiFe‐LDH is regarded as one of the most efficient oxygen evolution catalysts, with catalytic activity stems from in‐situ formation NiOOH active phase induced by anodic polarization. In reaction, initially reconstitutes into highly β‐NiOOH phase, which difficult to initiate and stabilize at low potential, will be irreversibly transformed less γ‐NiOOH due over‐oxidation. this work, a novel built‐in electric field (BEF)‐driven surface reconstruction strategy proposed reduce potential required for prevent its This demonstrated in two‐dimensional NiFe‐LDH/Antimonene (2D/2D NiFe‐LDH/AMNSs) heterostructure catalyst, where strong BEF generated through work function engineering. Kelvin probe force microscopy (KPFM) tests, Raman spectra theoretical calculations confirm that enhances electron transfer NiFe‐LDH/AMNSs interface, creating local reduced applied 80 mV NiFe‐LDH. Consequently, record‐low overpotentials 144 209 are achieved 10 300 mA cm −2 reaction (OER), making it best‐performing based catalysts date. It also demonstrates excellent durability hydrogen (HER) activity, ideal overall water splitting.

Language: Английский

Citations

0