Electrolyte design for lithium-sulfur batteries: Progress and challenges DOI

W.Y. Jan,

Adnan Daud Khan, Faiza Jan Iftikhar

et al.

Renewable and Sustainable Energy Reviews, Journal Year: 2025, Volume and Issue: 221, P. 115916 - 115916

Published: June 4, 2025

Language: Английский

Small and low-crystallinity NiO nanoparticles embedded in hollow carbon materials for high performance asymmetric supercapacitors DOI
Xu Zhang, Ying Chen, Zhiqing Liu

et al.

Journal of Energy Storage, Journal Year: 2025, Volume and Issue: 113, P. 115738 - 115738

Published: Feb. 8, 2025

Language: Английский

Citations

3

Enhancing Li-S Battery Performance by Harnessing the Power of Single Atoms on 2D Borophene DOI

Normurоt Fayzullaev,

M. Keshavarz, Mohammad Omidi

et al.

Electrochimica Acta, Journal Year: 2025, Volume and Issue: unknown, P. 145831 - 145831

Published: Feb. 1, 2025

Language: Английский

Citations

3

Pristine MOF Materials for Separator Application in Lithium–Sulfur Battery DOI Creative Commons
Zhibin Cheng, Jie Lian, Jindan Zhang

et al.

Advanced Science, Journal Year: 2024, Volume and Issue: 11(31)

Published: June 18, 2024

Abstract Lithium–sulfur (Li–S) batteries have attracted significant attention in the realm of electronic energy storage and conversion owing to their remarkable theoretical density cost‐effectiveness. However, Li–S continue face challenges, primarily severe polysulfides shuttle effect sluggish sulfur redox kinetics, which are inherent obstacles practical application. Metal‐organic frameworks (MOFs), known for porous structure, high adsorption capacity, structural flexibility, easy synthesis, emerged as ideal materials separator modification. Efficient interception/conversion ability rapid lithium‐ion conduction enabled by MOFs modified layers demonstrated batteries. In this perspective, objective is present an overview recent advancements utilizing pristine MOF modification separators The mechanisms behind enhanced electrochemical performance resulting from each design strategy explained. viewpoints crucial challenges requiring resolution also concluded Moreover, some promising concepts based on proposed enhance investigate adsorption/conversion mechanisms. These efforts expected contribute future advancement advanced

Language: Английский

Citations

17

Beyond lithium-ion: emerging frontiers in next-generation battery technologies DOI Creative Commons
Balaraman Vedhanarayanan,

K. C. Seetha Lakshmi

Frontiers in Batteries and Electrochemistry, Journal Year: 2024, Volume and Issue: 3

Published: April 5, 2024

The rapid advancement of technology and the growing need for energy storage solutions have led to unprecedented research in field metal-ion batteries. This perspective article provides a detailed exploration latest developments future directions storage, particularly focusing on promising alternatives traditional lithium-ion With solid-state batteries, lithium-sulfur systems other (sodium, potassium, magnesium calcium) batteries together with innovative chemistries, it is important investigate these as we approach new era battery technology. examines recent breakthroughs, identifies underlying challenges, discusses significant impact frontiers various applications–from portable electronics electric vehicles grid-scale storage. Against backdrop shifting paradigm where limitations conventional are being addressed by cutting-edge innovations, this offers insights into transformative potential next-generation technologies. further aims contribute ongoing scientific dialogue environmental economic implications

Language: Английский

Citations

15

Spodumene nanosheets@ZrO2-SiO2 heterostructure nanofibers modified separator for long-cycle lithium-sulfur batteries DOI
Lin Li,

Bin Yue,

Yingying Bao

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 495, P. 153619 - 153619

Published: June 29, 2024

Language: Английский

Citations

11

Quasi-solid-state sulfur cathode with ultralean electrolyte via in situ polymerization DOI
Tao Shi, Yaqi Liao,

Jia Kong

et al.

Energy storage materials, Journal Year: 2024, Volume and Issue: 72, P. 103744 - 103744

Published: Aug. 24, 2024

Language: Английский

Citations

7

Revitalizing Li–S batteries: the power of electrolyte additives DOI Creative Commons

Derek Ovc-Okene,

Lakshmi Shiva Shankar, Alen Vižintin

et al.

RSC Advances, Journal Year: 2025, Volume and Issue: 15(7), P. 5381 - 5404

Published: Jan. 1, 2025

Lithium-sulfur (Li-S) batteries have garnered significant attention as promising next-generation energy storage solutions due to their high density and cost efficiency. However, the broad adoption of Li-S is impeded by several critical issues. These include intrinsically low conductivities sulfur (S) lithium sulfide (Li2S), polysulfide shuttle effect, dendrite formation on (Li) electrode, among other challenges. Overcoming these obstacles crucial realizing full potential batteries. A key step towards improving battery performance optimization electrolytes, with a particular focus enhancing cell cyclability, rate capability, safety, lifespan. This review examines current advancements in various electrolyte additive options, including concepts, designs, materials, how electrolyte's final chemical physical properties influence overall The aim provide comprehensive framework for rational selection future additives batteries, based available evaluate existing additives.

Language: Английский

Citations

1

Tailoring Cathode–Electrolyte Interface for High-Power and Stable Lithium–Sulfur Batteries DOI Creative Commons
Mengting Liu, Lingling Hu, Zong‐Jie Guan

et al.

Nano-Micro Letters, Journal Year: 2024, Volume and Issue: 17(1)

Published: Dec. 4, 2024

Abstract Global interest in lithium–sulfur batteries as one of the most promising energy storage technologies has been sparked by their low sulfur cathode cost, high gravimetric, volumetric densities, abundant resources, and environmental friendliness. However, practical application is significantly impeded several serious issues that arise at cathode–electrolyte interface, such interface structure degradation including uneven deposition Li 2 S, unstable interphase (CEI) layer intermediate polysulfide shuttle effect. Thus, an optimized along with electrodes required for overall improvement. Herein, we comprehensively outline challenges corresponding strategies, electrolyte optimization to create a dense CEI layer, regulating S pattern, inhibiting effect regard solid–liquid–solid pathway, transformation from solid–solid pathway interface. In order spur more perceptive research hasten widespread use batteries, viewpoints on designing stable deep comprehension are also put forth.

Language: Английский

Citations

6

Mofs hybridized carbon matrix as multi-functional cathodic interlayer for lithium-sulfur batteries DOI

Xiangjie Gong,

Yan Song,

Ning Zhao

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 512, P. 215877 - 215877

Published: April 26, 2024

Language: Английский

Citations

4

Covalent Organic Frameworks and Their Derivatives for Applications in High‐Performance Lithium–Sulfur Batteries DOI
Xiudong Chen,

Huixiong Jiang,

Jin‐Hang Liu

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 30, 2024

Abstract Lithium–Sulfur batteries (LSBs) are widely regarded as one of the most promising energy storage systems due to their ultra‐high theoretical density and environmental friendliness. However, practical applications LSBs face significant challenges, including shuttle effect soluble polysulfides formation lithium dendrites. Covalent organic frameworks (COFs) have emerged potential materials for inhibiting polysulfide buffering This review provides an overview latest advancements in use COF its derivative sulfur host materials, modified commercial separators, electrolytes LBSs, makes some brief conclusions predictions. Pure COFs, derivatives, composites discussed hosts, along with novel strategies intended enhance LSB cycling stability reversibility. Strategies enhancing performance summarized through modification separators using ultimate goal achieving high density. It also discusses designing COF‐based electrolytes, which include structural design, ionic introduction salt molecules or flexible oligo(ethylene oxide) chains into skeletons. Additionally, future prospects COFs derivatives LSBs.

Language: Английский

Citations

3