Tailoring of single copper atoms anchored on N, P co-doped carbon for electrochemical CO2 reduction

Catalysis Today, Journal Year: 2025, Volume and Issue: unknown, P. 115284 - 115284

Published: March 1, 2025

Language: Английский

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On the Hunt for Chiral Single-Atom Catalysts

ACS Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 6852 - 6873

Published: April 12, 2025

Enantioselective transformations are crucial in various fields, including chemistry, biology, and materials science. Today, the selective production of enantiopure compounds is achieved through asymmetric homogeneous catalysis. Single-atom catalysts (SACs) emerging as a transformative approach enabling heterogenization organometallic complexes effectively bridging gap between heterogeneous Despite their potential, integration SACs into enantioselective processes remains an underexplored area. This perspective offers comprehensive analysis possible strategies for design catalysts, examining how chiral surfaces, modifiers, grafted complexes, spatial confinement techniques can be employed to enhance enantioselectivity. Each these methods presents distinct advantages challenges; example, surfaces modifiers offer potential tailored reactivity but suffer from limited stability selectivity, while provide robust platforms may face issues related scalability synthesis complexity. Spatial show promise enhancing catalyst efficiency constrained by accessibility reproducibility concerns. These lay groundwork adaptation SACs, providing innovative approaches replicate well-defined environments preserving stability, reusability, unique single-atom systems.

Language: Английский

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Modification of single atomic Fe-N4 catalytic site with sulfur to promote CO2 electroreduction

Carbon, Journal Year: 2025, Volume and Issue: unknown, P. 120388 - 120388

Published: May 1, 2025

Language: Английский

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Design of reaction-driven active configuration for enhanced CO2 electroreduction

Nano Energy, Journal Year: 2024, Volume and Issue: 128, P. 109873 - 109873

Published: June 12, 2024

Language: Английский

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Spontaneous Metal‐Chelation Strategy for Highly Dense Ni Single‐Atom Catalysts with Asymmetric Coordination in CO₂ Electroreduction

Small, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 12, 2024

Developing metal-nitrogen-doped carbon single-atom catalysts (M-NC SACs) with high loadings for the electrochemical CO

Language: Английский

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Designing cobalt–nickel dual-atoms on boron, nitrogen-codoped carbon nanotubes for carbon dioxide electroreduction to syngas

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 683, P. 446 - 456

Published: Dec. 16, 2024

Language: Английский

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Blending of Nitrogen-Doped Carbon Nanotubes with Transition Metal: Effect of Type and Amount of Metal Seed on CO2 Electroreduction to CO

Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: unknown, P. 115159 - 115159

Published: Dec. 1, 2024

Language: Английский

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N, S-coordinated Ni single-atom catalysts for efficient CO2 reduction in a zero-gap membrane electrode assembly electrolyzer

Materials Today Energy, Journal Year: 2024, Volume and Issue: 46, P. 101706 - 101706

Published: Oct. 11, 2024

Language: Английский

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Oxygen functionalized diamond nanocone arrays coupling cobalt phthalocyanine for enhanced electrochemical CO2 reduction

Materials Today Energy, Journal Year: 2024, Volume and Issue: 44, P. 101634 - 101634

Published: June 25, 2024

Language: Английский

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A universal route to graft highly dispersed Cobalt Phthalocyanine on porous carbon for efficient CO2 Electroreduction

New Journal of Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

A promising catalyst for dispersing CoPc on three-dimensional porous carbon was prepared and showed impressive performance CO 2 electroreduction to CO.

Language: Английский

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