Impacts of Goat Horn/Ammonium Polyphosphate on Mechanical and Thermal Properties of Epoxy Composites DOI Creative Commons

N. Parkunam,

P. Gopal,

G. Navaneethakrishnan

et al.

Engineering Reports, Journal Year: 2025, Volume and Issue: 7(2)

Published: Feb. 1, 2025

ABSTRACT In this paper, the ammonium polyphosphate (APP) is mixed with epoxy to fabricate APP/epoxy goat horn composites. The composites were obtained by casting method different weight ratios of APP 0%, 10%, 15%, and 20% for improving mechanical thermal properties. This first paper discuss about both properties evaluated tensile test wear test. For a content 20 wt% APP, strength was 30 MPa, shows that adding led having better strength. From limiting oxygen index results, it clear composite fire retardant, fire‐retardant value improves addition up ratio 15% APP. thermogravimetric analysis (TGA) reveals degradation in relation temperature. TGA analysis, bio without gives results comparing incorporation 40% loss. At same time, 50% loss occur at temperature around 380°C It stability ignition time from horizontal flammability 0, 10, 15, 20, 22, 24, 25 (in s) respectively. filler material into composites, also increases. water absorption percentage peak lower 10% All samples saturated after 80 h. can be attributed improved interfacial bonding between fibers matrix. scanning electron microscopy (SEM) morphological structure dispersion particles studied.

Language: Английский

Bio-based molecules with ionically bonded phosphorus toward ultra-high flame-retardant efficiency of PLA plastics DOI
Yadong Wang, Jingjing Gao, Guoping Zhu

et al.

International Journal of Biological Macromolecules, Journal Year: 2024, Volume and Issue: unknown, P. 138560 - 138560

Published: Dec. 1, 2024

Language: Английский

Citations

22

Two-dimensional nanomaterials for flame-retardant polymer composites: a mini review DOI Creative Commons
Siqi Huo, Yong Guo, Qingshan Yang

et al.

Advanced Nanocomposites, Journal Year: 2024, Volume and Issue: 1(1), P. 240 - 247

Published: Jan. 1, 2024

The inherent flammability of polymer materials is an issue that cannot be ignored and limits their further application in industry. Therefore, much effort has been devoted to the development flame-retardant polymers. Two-dimensional (2D) nanomaterials have received abundant attention field polymers recently because unique layered structure versatility. 2D with structures, when well dispersed polymers, not only enhance thermal stability significantly, but also strengthen role char layer suppressing heat mass transfer. This review focuses on properties nanocomposites based most common nanomaterials, including graphene, MXene black phosphorus, as efficiency. Moreover, we provide design approaches for future nanocomposites.

Language: Английский

Citations

19

Designing sandwich-structured IBP nanosheets with superior antioxidant property to enhance corrosion resistance, flame retardancy, and wear resistance for polymeric coatings DOI

Qihan Weng,

Li Zhang, Xinxin Sheng

et al.

Journal of Material Science and Technology, Journal Year: 2024, Volume and Issue: 215, P. 22 - 35

Published: July 26, 2024

Language: Английский

Citations

17

An Engineered Heterostructured Trinity Enables Fire-Safe, Thermally Conductive Polymer Nanocomposite Films with Low Dielectric Loss DOI Creative Commons
Qiang Chen,

Jiabing Feng,

Yijiao Xue

et al.

Nano-Micro Letters, Journal Year: 2025, Volume and Issue: 17(1)

Published: Feb. 26, 2025

Abstract To adapt to the trend of increasing miniaturization and high integration microelectronic equipments, there is a demand for multifunctional thermally conductive (TC) polymeric films combining excellent flame retardancy low dielectric constant ( ε ). date, have been few successes that achieve such performance portfolio in polymer due their different even mutually exclusive governing mechanisms. Herein, we propose trinity strategy creating rationally engineered heterostructure nanoadditive (FG@CuP@ZTC) by situ self-assembly immobilization copper-phenyl phosphonate (CuP) zinc-3, 5-diamino-1,2,4-triazole complex (ZTC) onto fluorinated graphene (FG) surface. Benefiting from synergistic effects FG, CuP, ZTC bionic lay-by-lay (LBL) strategy, as-fabricated waterborne polyurethane (WPU) nanocomposite film with 30 wt% FG@CuP@ZTC exhibits 55.6% improvement limiting oxygen index (LOI), 66.0% 40.5% reductions peak heat release rate total release, respectively, 93.3% increase tensile strength relative pure WPU between ZTC. Moreover, presents thermal conductivity λ ) 12.7 W m −1 K 2.92 at 10 6 Hz. This work provides commercially viable rational design develop high-performance films, which hold great potential as advanced dissipators high-power-density microelectronics.

Language: Английский

Citations

3

Recyclable fire-retardant bio-based thermosets: From molecular engineering to performances and applications DOI Creative Commons
Yong Guo, Qingshan Yang, Siqi Huo

et al.

Progress in Polymer Science, Journal Year: 2025, Volume and Issue: unknown, P. 101935 - 101935

Published: March 1, 2025

Language: Английский

Citations

3

Mxene nanohybrids assembled with phytic acid-modified UiO-66 toward mechanically reinforced, fire-resistant and Smoke-suppressed epoxy composites DOI
Kaili Gong,

Lian Yin,

Zilong Wu

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 159605 - 159605

Published: Jan. 1, 2025

Language: Английский

Citations

2

Functionalized MXenes nanosheets inspired flame retardant epoxy composites: Mechanisms investigation and safety evaluation DOI
Junling Wang, Liang Li,

Konghao Yu

et al.

Construction and Building Materials, Journal Year: 2025, Volume and Issue: 464, P. 140124 - 140124

Published: Jan. 27, 2025

Language: Английский

Citations

2

Intrinsically reactive hyperbranched interface governs graphene oxide dispersion and crosslinking in epoxy for enhanced flame retardancy DOI
Hefeng Li, Cong Liu,

Jiabao Zhu

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 672, P. 465 - 476

Published: June 6, 2024

Language: Английский

Citations

13

Nanostructured flame retardants: An overview DOI
Jolina Rodrigues, Navinchandra G. Shimpi

Nano-Structures & Nano-Objects, Journal Year: 2024, Volume and Issue: 39, P. 101253 - 101253

Published: July 6, 2024

Language: Английский

Citations

9

Vertically aligned cellulose nanofiber/carbon nanotube aerogel-infused epoxy nanocomposites for highly efficient solar-thermal-electric conversion DOI Creative Commons
Jiali Yan, Yu Sun, Tao Jia

et al.

Journal of Material Science and Technology, Journal Year: 2024, Volume and Issue: 214, P. 313 - 321

Published: July 20, 2024

Solar-driven thermo-electric generation (STEG) emerges as a promising solution to mitigate the global energy shortage. However, practical application of conventional photothermal materials equipped with STEG is limited due low solar thermal conversion efficiency. Herein, we fabricated an epoxy resin (EP) nanocomposite, EP/CCA80, excellent photo-thermal-electric properties by embedding vertically aligned aerogel consisting cellulose nanofibers (CNF) and carboxylated multi-walled carbon nanotubes (CMWCNTs) into transparent EP matrix. EP/CCA80 composites possessed broad light absorption range from 200 nm 2500 properties. Under illumination 1.0 kW m–2, achieved notable stable temperature 93.2°C efficiency up 54.35% only 0.65 wt% CMWCNTs inclusion. Additionally, coupled thermoelectric (TE) devices, composite facilitated significant difference voltage output 25.3°C 160.29 mV (1.0 m–2), respectively, which could power small fan rotate at speed 193 min–1. Such are poised offer viable solutions for enhancing accessibility in remote regions, thereby contributing reduction shortages environmental degradation.

Language: Английский

Citations

9