The competitive influence of the intramolecular electric field and hydrophilic active sites of D–A conjugated porous polymers on photocatalytic hydrogen evolution performance DOI
Yongzhen Yang, Fei Zhao, Xinyi Feng

et al.

Journal of Materials Chemistry A, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Conjugated porous polymers (CPPs) with a donor–acceptor (D–A) molecular structure usually exhibit good photocatalytic hydrogen evolution (PHE).

Language: Английский

A S-scheme 0D/2D heterojunction formed by decorating Cd0.5Zn0.5S nanoparticles on Cu2MoS4 plates for efficient photocatalytic hydrogen generation DOI
Jiahui Yu, Ping Su, Dong Zhang

et al.

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 354, P. 128694 - 128694

Published: July 5, 2024

Language: Английский

Citations

30

Skillful Promotion of Charge Separation via Defect-Mediated Built-in Electric Field and LSPR Effect for Enhanced Photocatalytic Activity DOI
Hui Guo, Wenxuan Chen, Xiu-Qing Qiao

et al.

Nano Energy, Journal Year: 2025, Volume and Issue: unknown, P. 110672 - 110672

Published: Jan. 1, 2025

Language: Английский

Citations

2

Empowering wastewater treatment with step scheme heterojunction ternary nanocomposites for photocatalytic degradation of nitrophenol DOI Creative Commons
Zhu Liu, Mah Roosh, Ming Lü

et al.

Scientific Reports, Journal Year: 2025, Volume and Issue: 15(1)

Published: Jan. 26, 2025

The ongoing challenge of water pollution necessitates innovative approaches to remove organic contaminants from wastewater. In this work, new two-dimensional S-scheme heterojunction photocatalysts Bi2O3/CdS and MoS2/Bi2O3/CdS that are intended for the effective photocatalytic destruction 4-nitrophenol, a dangerous pollutant, synthesized characterized. Utilizing solvothermal method, successfully generated these ternary nanocomposites, which were characterized through various techniques including X-ray diffraction (XRD), scanning electron microscopy (SEM), photoelectron spectroscopy (XPS), high resolution transmission electronmicroscopy (HRTEM), Brunauer-Emmett-Telle (BET) diffuse reflectance (DRS). Our results demonstrated achieved an 86% degradation rate while composite exhibited exceptional performance, achieving nearly complete (99%) within 120 min under visible light irradiation. Most importantly improved activity originated release internal electric field in heterojunction. This enhanced is attributable synergistic effects heterojunctions facilitate more charge separation generation with OP RP confirmed synthesis using S-scheme. further by XPS, DRS, XPS-VB photocurrent response. These findings highlight promising application advanced real-world wastewater treatment processes, offering sustainable solution combat pollution.

Language: Английский

Citations

2

Π‐Bridge Modulations in D–π–A Conjugated Microporous Polymers to Facilitate Charge Separation and Transfer Kinetics for Efficient Photocatalysis DOI
Chunlei Li,

Hetao Xu,

Hao Xiong

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(44)

Published: May 16, 2024

Abstract The burgeoning field of conjugated microporous polymers (CMPs) has generated widespread interest due to their potential as photocatalysts for hydrogen production from water. Nevertheless, photocatalytic performance is sometimes hindered by inadequate charge separation and transfer, coupled with rapid recombination. Herein, a strategy enhance via the customization π ‐bridges through modulation heteroatoms in series donor‐ ‐acceptor (D‐ ‐A) CMPs proposed. This affords optimized energy levels improved thus boosting efficiency. Among various heteroatom substitutions, S‐doped CMP (10 mg) demonstrates highest evolution rate 203 µmol h −1 (AQY 450nm = 7.4%) under visible light irradiation. Subsequent experimental analysis reveals its superior can be largely related minimized exciton binding energy, facilitated transfer efficiency, impeded recombination among these heteroatom‐doped D‐ ‐A CMPs. research paves way rational design modification organic semiconductors advanced solar‐driven photocatalysis promoting transfer.

Language: Английский

Citations

14

Construction of a In2O3/ultrathin g-C3N4 S-scheme heterojunction for sensitive photoelectrochemical aptasensing of diazinon DOI

Pengcheng Yan,

Jing Huang,

Guanyu Wu

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 679, P. 653 - 661

Published: Oct. 6, 2024

Language: Английский

Citations

11

Heterostructured Photocatalysts for Water Splitting and the Interfacial Charge Transfer DOI
Yazhuo Zheng, Erpeng Wang, Jian Zhou

et al.

ACS Materials Letters, Journal Year: 2024, Volume and Issue: unknown, P. 3572 - 3601

Published: July 15, 2024

Language: Английский

Citations

9

Thiophene-containing conjugated polymers modified Zn0.5Cd0.5S inorganic/organic S-scheme heterojunction for boosting photocatalytic hydrogen production coupled with benzyl alcohol oxidation DOI

Lele Wei,

Ru Song,

Jiarui Song

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 496, P. 154107 - 154107

Published: July 18, 2024

Language: Английский

Citations

9

Optimizing Charge Transport and Light Absorption in CdS Thin Films via Gd Doping for Photodiode Applications DOI

Madeshwaran Mohanraj,

V. Manikandan,

Arun Thirimurugan

et al.

Sensors and Actuators A Physical, Journal Year: 2025, Volume and Issue: unknown, P. 116230 - 116230

Published: Jan. 1, 2025

Language: Английский

Citations

1

Efficient removal of bisphenol A from water using a novel organic–inorganic hybrid heterojunction DOI
Qinwei Lu, Lu Di, Yi Zhou

et al.

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 353, P. 128099 - 128099

Published: May 25, 2024

Language: Английский

Citations

6

Photocatalytic hydrogen production coupled with selective benzyl alcohol oxidation via WOx/CdS S-scheme heterojunction DOI
Jiayu Tian, Xinrui Zhang, Ziying Zhang

et al.

International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 74, P. 31 - 38

Published: June 12, 2024

Language: Английский

Citations

6