Bridging links between solid electrolytes and electrodes: Boosting the electrochemical performance of flame-retardant solid electrolytes with vapor-deposited carbon and gold-sputtered nanolayers DOI
Xuhui Wang,

Zenghui Zhao,

Xinpeng Liu

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: unknown, P. 157741 - 157741

Published: Nov. 1, 2024

Language: Английский

Ionic Gel Electrolytes for Electrochromic Devices DOI

Baoyi Ma,

Liang Tang, Yan Zhang

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(37), P. 48927 - 48936

Published: Sept. 6, 2024

Ionic gels are emerging as a promising solution for improving the functionality of electrochromic devices. They increasingly drawing attention in fields electrochemistry and functional materials due to their potential address issues associated with traditional liquid electrolytes, such volatility, toxicity, leakage. In extreme scenarios and/or design flexible devices, ionic gel electrolytes offer unique invaluable advantages. This perspective delves into application exploring various methods enhance performance. After briefly introducing developments trends key points future development discussed detail.

Language: Английский

Citations

10

A Fiber-Reinforced Poly(ionic liquid) Solid Electrolyte with Low Flammability and High Conductivity for High-Performance Lithium–Metal Batteries DOI
Junyan Tang, En Chen, Dehua Wang

et al.

ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown

Published: March 21, 2025

Construction of polymer-based solid electrolytes with both low flammability and high ionic conductivity for lithium-metal batteries is still a great challenge but highly desirable. Herein, we report on series fiber-reinforced poly(ionic liquid) prepared through an in situ copolymerization liquid monomers (IL) poly(ethylene glycol) diacrylate (PEGDA) units different ratios inside polyacrylonitrile (PAN) fiber membrane. Such PAN/Poly-IL-PEGDA composite demonstrate promising due to the excellent fire-resistant feature employed IL units. Moreover, it remarkable see that optimized PAN/Poly-IL-PEGDA-1 electrolyte also exhibits dense structure thickness (31 μm), (0.32 mS cm-1 at 30 °C), wide electrochemical window (up 4.8 V). As result, LiFePO4//Li NCM//Li full cells such exhibit rate capability cycling stability. This study provides simple strategy preparing polymer high-performance batteries.

Language: Английский

Citations

1

Solid‐State Electrolytes for Lithium Metal Batteries: State‐of‐the‐Art and Perspectives DOI Creative Commons
Jun Huang, Chen Li,

Dongkai Jiang

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 35(1)

Published: Oct. 31, 2024

Abstract The use of all‐solid‐state lithium metal batteries (ASSLMBs) has garnered significant attention as a promising solution for advanced energy storage systems. By employing non‐flammable solid electrolytes in ASSLMBs, their safety profile is enhanced, and the anode allows higher density compared to traditional lithium‐ion batteries. To fully realize potential solid‐state (SSEs) must meet several requirements. These include high ionic conductivity Li + transference number, smooth interfacial contact between SSEs electrodes, low manufacturing cost, excellent electrochemical stability, effective suppression dendrite formation. This paper delves into essential requirements enable successful implementation ASSLMBs. Additionally, representative state‐of‐the‐art examples developed past 5 years, showcasing latest advancements SSE materials highlighting unique properties are discussed. Finally, provides an outlook on achieving balanced improved addressing failure mechanisms solutions, critical challenges such reversibility plating/stripping thermal runaway, characterization techniques, composite SSEs, computational studies, ASS lithium–sulfur lithium–oxygen With this consideration, ASSLMBs can be realized.

Language: Английский

Citations

9

Two-macro-phased fluorinated polymer electrolytes for lithium batteries DOI

Zhuolin Rong,

Yuanyuan Xu,

Jin‐Yuan Wang

et al.

Journal of Power Sources, Journal Year: 2025, Volume and Issue: 630, P. 236151 - 236151

Published: Jan. 2, 2025

Language: Английский

Citations

1

Upgrading Garnet–Polymer Composite Electrolytes for Solid-State Lithium Batteries: The Role of the Hydrogen Bonds and PTFE Fibers DOI
Ning Sun, Haoyu Zhao, Ran Ran

et al.

Energy & Fuels, Journal Year: 2025, Volume and Issue: unknown

Published: May 15, 2025

Language: Английский

Citations

1

The Research Progress on COF Solid-State Electrolytes for Lithium Batteries DOI

Yimou Wang,

Qinglin Hao,

Qing Lv

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: 60(74), P. 10046 - 10063

Published: Jan. 1, 2024

This review focuses on the role of different COFs as solid-state electrolytes, aiming to guide development electrolyte materials and battery technology.

Language: Английский

Citations

5

Carboxymethyl cellulose organic gel polymer electrolyte enabling high performance of germanium-air batteries in a wide operating temperature range from −10 °C to 80 °C DOI

Ya Fang Han,

Yingjian Yu

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: unknown, P. 158553 - 158553

Published: Dec. 1, 2024

Language: Английский

Citations

3

Nanocellulose-reinforced nanofiber composite poly(aryl ether ketone) polymer electrolyte for advanced lithium batteries DOI
Yangyang Yu, Xiaohui Guo, Yuhan Liu

et al.

International Journal of Biological Macromolecules, Journal Year: 2025, Volume and Issue: 295, P. 139560 - 139560

Published: Jan. 6, 2025

Language: Английский

Citations

0

Advancements in lithium solid polymer batteries: surface modification, in-situ/operando characterization, and simulation methodologies DOI Open Access
Shanshan Guo, Xinpei Li, Zihao Zhang

et al.

Energy Materials, Journal Year: 2025, Volume and Issue: 5(4)

Published: Jan. 24, 2025

The interest in lithium solid-state batteries (LSSBs) is rapidly escalating, driven by their impressive energy density and safety features. However, they face crucial challenges, including limited ionic conductivity, high interfacial resistance, unwanted side reactions. Intensive research has been conducted on polymer electrolytes positioned between the anode cathode, aiming to replace traditional liquid electrolytes. To alleviate resistance mitigate adverse reactions electrodes electrolytes, modification strategy proven enhance of LSSBs. This design process grounded precise elaborate theories, with in-situ /operando techniques simulation methods facilitating interpretation validation structure-property relationships simplifying them. review first outlines recent advancements surface strategies specifically tailored for solid Furthermore, it also provides an overview innovative characterizations featured publications, which can gain a more accurate understanding processes that occur within materials, devices, or chemical as are happening. Lastly, discusses existing challenges presents forward-looking perspective future next-generation

Language: Английский

Citations

0

A Zwitterion Coupled All‐Solid‐State Single Ion Conducting Polymer Electrolyte via Photoinitiated Thiol‐Ene Click Polymerization DOI Open Access

Kun-Yuan Tu,

Jinnan Zhang, Guang–Nan Luo

et al.

Macromolecular Rapid Communications, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 7, 2025

The all-solid-state single ion conducting polymer electrolyte has a bottleneck in ionic conductivity even though it can prevent concentration polarization. Here, lithium 3,3'-(diallylammonio)bis(propane-1-sulfonyl(trifluoromethyl sulfonyl)imide) (LiDAA(PSI)2) with symmetrical "one positive, two negative" structure and unsaturated double bonds for propagation, is synthesized. LiDAA(PSI)2 copolymerized 1,2-ethanedithiol poly(ethylene glycol) diacrylate via photoinitiated thiol-ene click polymerization forms random copolymer, SPZ short. For comparison, 3-(diallylamino)propane-1-sulfonyl(trifluoromethyl (LiDAAPSI) corresponding copolymer SP are 7Li resonance peak position of shifts to low-field compared that LiDAAPSI, indicating weaker electrostatic attraction. responsible the shift, taking effect charge conjugation. Unsurprisingly, 1.69e-5 S cm-1 at 60 °C, which 1.9 times SP. Lithium electroplating stripping 0.0125 mA [email protected] mAh cm-2 °C performed. An metal secondary battery demonstrated. Zwitterion coupled possesses structure, conjugation weaken interaction, inspires design synthesis electrolytes zwitterion effect.

Language: Английский

Citations

0