Dynamic Dance of Chirality and Morphology: Interplay of Solvent-Sensitive Self-Assembly in Topological Evolution and Chirality Amplification DOI

Gaurav Kumar,

Manoj Kumar, Vandana Bhalla

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(45), P. 62988 - 62998

Published: Oct. 31, 2024

The building block Pyra-Chol has been designed and synthesized, which exhibits different achiral morphologies in good solvents, forming nanospheres THF nanoflowers 1,4-dioxane. In the presence of water as a poor cosolvent, demonstrates an agnostic behavior, generating left-handed superhelices water:THF (80:20) solvent system. However, when is switched to 1,4-dioxane, change chirality observed water:1,4-dioxane (30:70) system, resulting formation fused nanospheres. Interestingly, cosolvent changed from MCH THF, chiral pattern remains unchanged, but morphology changes completely. Supported by collective spectroscopic microscopic analysis, present study efficaciously remarkable control hydrophobic over sense also highlights fascinating influence well supporting distinct molecular packing.

Language: Английский

Binaphthyl‐Aniline‐Based Chiral Magnetic Polymer DOI Creative Commons
Ryo Miyashita, Kunio Kimura, Reiji Kumai

et al.

Journal of Polymer Science, Journal Year: 2025, Volume and Issue: unknown

Published: March 18, 2025

ABSTRACT Magnetoactive polymers based on 1,1′‐binaphthyl‐2,2′‐diamine with axial chirality were synthesized through cross‐coupling polycondensation of the Buchwald–Hartwig reaction and subsequent oxidation m ‐chloroperoxybenzoic acid. The characterized optical spectroscopy, electron spin resonance, superconducting quantum interference device, synchrotron X‐ray diffraction. Circular dichroism measurements revealed that exhibited activity. Magnetic further showed are organic chiral materials weak antiferromagnetism owing to presence solid oxygen low‐dimensional ordering.

Language: Английский

Citations

0
Dynamic Dance of Chirality and Morphology: Interplay of Solvent-Sensitive Self-Assembly in Topological Evolution and Chirality Amplification DOI

Gaurav Kumar,

Manoj Kumar, Vandana Bhalla

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(45), P. 62988 - 62998

Published: Oct. 31, 2024

The building block Pyra-Chol has been designed and synthesized, which exhibits different achiral morphologies in good solvents, forming nanospheres THF nanoflowers 1,4-dioxane. In the presence of water as a poor cosolvent, demonstrates an agnostic behavior, generating left-handed superhelices water:THF (80:20) solvent system. However, when is switched to 1,4-dioxane, change chirality observed water:1,4-dioxane (30:70) system, resulting formation fused nanospheres. Interestingly, cosolvent changed from MCH THF, chiral pattern remains unchanged, but morphology changes completely. Supported by collective spectroscopic microscopic analysis, present study efficaciously remarkable control hydrophobic over sense also highlights fascinating influence well supporting distinct molecular packing.

Language: Английский

Citations

0