Unveiling the mysteries of hydrogen spillover phenomenon in hydrogen evolution reaction: Fundamentals, evidence and enhancement strategies
Shan Zhao,
No information about this author
Zhenhong Wang,
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Jingyu Wang
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et al.
Coordination Chemistry Reviews,
Journal Year:
2024,
Volume and Issue:
524, P. 216321 - 216321
Published: Nov. 13, 2024
Language: Английский
Advance in rare earth element modified nanomaterials for enhanced electrocatalytic water splitting
Le Li,
No information about this author
Shuanqiang Liu,
No information about this author
Ying Li
No information about this author
et al.
International Journal of Hydrogen Energy,
Journal Year:
2024,
Volume and Issue:
85, P. 818 - 831
Published: Aug. 28, 2024
Language: Английский
Insight into the effect of d-orbital electron rearrangements induced by Zr–H interactions: first-principles calculations
Tuman Zhang,
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Jianxu Ding,
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Yangyang Jiang
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et al.
Journal of Materials Chemistry A,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
The
study
elucidates
the
differences
in
hydrogen
adsorption
mechanisms
between
zirconium
and
hydride
from
perspective
of
orbital
bonding,
offering
a
theoretical
basis
for
understanding
embrittlement.
Language: Английский
Activating PtRu with rare earth alloying for efficient electrocatalytic methanol oxidation reaction
Catalysis Science & Technology,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
Methanol
molecule
oxidation
catalyzed
by
the
synergistic
effect
of
PtRuSc.
Language: Английский
Rapid Microwave‐Driven Sulfur Sublimation Synthesis of MS2/RuS2 (M = Fe, Co, Ni) for Efficient Alkaline Overall Water Splitting
Xinyu Zhu,
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Minghao Fang,
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Bozhi Yang
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et al.
Small,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 18, 2025
Abstract
Facing
the
complex
application
environment
and
overall
inefficiency
in
complete
water‐splitting
process,
development
of
highly
efficient
stable
catalytic
materials
is
urgently
required.
This
study
innovatively
proposes
for
first
time
implements
a
rapid
synthesis
technique
driven
by
microwave‐induced
sulfur
sublimation,
successfully
preparing
MS
2
/RuS
(M
=
Co,
Fe,
Ni)
heterostructure
interfaces
with
high
structural
stability
uniform
active
site
distribution
within
merely
60
s.
By
incorporating
iron‐group
sulfides,
electronic
structure
pyrite‐type
RuS
effectively
modulated,
enabling
developed
@G
catalyst
to
exhibit
superior
activity
alkaline
environments.
Particularly,
cobalt‐based
sulfide
regulated
(CoS
@G)
achieves
mass
hydrogen
evolution
reaction
(HER)
that
15.4
times
20
wt.%
Pt/C,
oxygen
(OER),
it
surpasses
commercial
IrO
two
orders
magnitude.
research
not
only
provides
new
pathway
enhancing
performance
environmental
adaptability
catalysts
but
also
presents
simple
universal
method
boost
through
synergistic
modulation
strategy.
Language: Английский
Semi-ionic C-F optimizes metal-support interaction of Rh/F, N-codoped porous carbon for efficient all-pH hydrogen production
Jian Guo,
No information about this author
Rui Ding,
No information about this author
Yi Li
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et al.
Nano Energy,
Journal Year:
2025,
Volume and Issue:
unknown, P. 110975 - 110975
Published: April 1, 2025
Language: Английский
Direct seawater electrolysis: Breaking the dependency on noble metal-based electrocatalysts
Mi Gyoung Lee,
No information about this author
Seoungyeon Kim,
No information about this author
Yong-Kul Lee
No information about this author
et al.
International Journal of Hydrogen Energy,
Journal Year:
2025,
Volume and Issue:
130, P. 89 - 107
Published: April 25, 2025
Language: Английский
High-entropy catalysts for electrocatalytic reduction reaction
Shaoyu Zhang,
No information about this author
Shuanqiang Liu,
No information about this author
Donglei Yang
No information about this author
et al.
Journal of Alloys and Compounds,
Journal Year:
2024,
Volume and Issue:
1009, P. 176970 - 176970
Published: Oct. 11, 2024
Language: Английский
Synthesis Framework for Designing PtPdCoNiMn High‐Entropy Alloy: A Stable Electrocatalyst for Enhanced Alkaline Hydrogen Evolution Reaction
Small,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Nov. 16, 2024
Abstract
High
entropy
alloys
(HEAs)
are
an
emerging
class
of
advanced
materials
characterized
by
their
multifunctionality
and
potential
to
replace
commercial
catalysts
in
electrocatalytic
water
splitting.
The
synergy
among
the
various
alloyed
elements
HEAs
makes
them
particularly
promising
for
applications
electrocatalysis.
However,
preparation
HEA
via
bottom‐up
approaches
avoiding
formation
mono,
di,
tri
metallic
nanoscale
is
challenging.
This
aspect
addressed,
this
study
exploring
logical
selection
solvents,
reducing
agents,
capping
along
with
relative
fractions,
solvothermal
synthesis
comprising
platinum‐palladium‐cobalt‐nickel‐manganese
(PtPdCoNiMn).
It
established
that
capabilities
both
solvent
agent
crucial
reduction
each
metal
form
a
single‐phase
HEA.
synthesized
(20
wt.%)/functionalized
carbon
(FC)
demonstrates
excellent
performance
as
HER
catalyst,
exhibiting
low
overpotential
48.7
mV
at
−10
mA
cm
−2
alkaline
electrolyte.
high
reaction
kinetics
stability
elevated
current
densities.
Furthermore,
catalyst
shows
impressive
simulated
actual
seawater.
development
reduces
reliance
on
platinum
while
enhancing
long‐term
durability
catalytic
efficiency
electrocatalyst.
Language: Английский
Coupling High‐Entropy Core with Rh Shell for Efficient pH‐Universal Hydrogen Evolution
Small,
Journal Year:
2024,
Volume and Issue:
20(47)
Published: Aug. 24, 2024
Constructing
high-entropy
alloys
(HEAs)
with
core-shell
(CS)
nanostructure
is
efficient
for
enhancing
catalytic
activity.
However,
it
extremely
challenging
to
incorporate
the
CS
structure
HEAs.
Herein,
PtCoNiMoRh@Rh
nanoparticles
(PtCoNiMoRh@Rh)
∼5.7
nm
pH-universal
hydrogen
evolution
reaction
(HER)
are
reported
first
time.
The
just
require
9.1,
24.9,
and
17.1
mV
achieve
-10
mA
cm
Language: Английский