Journal of Electroanalytical Chemistry, Journal Year: 2024, Volume and Issue: 974, P. 118704 - 118704
Published: Oct. 9, 2024
Language: Английский
Journal of Electroanalytical Chemistry, Journal Year: 2024, Volume and Issue: 974, P. 118704 - 118704
Published: Oct. 9, 2024
Language: Английский
ACS Catalysis, Journal Year: 2024, Volume and Issue: unknown, P. 18095 - 18106
Published: Nov. 22, 2024
Language: Английский
Citations
14Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 24, 2025
Developing high-performance catalysts for the alcohol electrooxidation reaction is of significant importance practical application direct fuel cells. Herein, a supported catalyst consisting well-dispersive PdCu nanoparticles (NPs) and ultrathin NiZnP nanosheets (NSs) synthesized. The high-surface-area NSs provide platform good dispersion NPs, resulting in stable with large number exposed surface atoms. Compared NPs commercial Pd/C, metal–support interactions contribute to activity durability improvement PdCu/NiZnP nanohybrids. Moreover, promote formation OH species, thereby facilitating removal carbonaceous intermediates ensuring long-term stability This study provides deep insight into comprehensive understanding interactions, offering great opportunities design efficient
Language: Английский
Citations
1Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 23, 2025
Abstract Phase engineering of metal sulfides offers a promising strategy to enhance the catalytic performance by adjusting their atomic arrangement and electronic structure. However, achieving continuous phase‐controlled elucidating structure‐performance relationship remains significant challenge. Herein, for first time, novel class palladium‐sulphur nanosheet aerogels (Pd─S NAs) aimed at enhancing electrocatalytic waste polymer‐derived ethylene glycol oxidation reaction (EGOR) is introduced. Remarkably, benefiting from ordered arrangement, Pd 3 S NAs with 4 phase deliver superior toward EGOR, surpassing both S‐doped (Pd 9 amorphous 1 NAs. Density functional theory calculations reveal that different vital structural descriptor performance, where structure intrinsic contribution excellent Compared other Pd─S NAs, have regular arrangements, which promote carbon monoxide intermediate ( * CO), cause optimal adsorption CH₂OHCOO key intermediates during facilitate selective EG glycolic acid, lower barrier in potential determining step reaction, thus presenting EGOR performance. This study advances synthesis Pd‐based nanomaterials highlights importance phase‐dependent properties electrocatalysis.
Language: Английский
Citations
1Applied Surface Science, Journal Year: 2025, Volume and Issue: 691, P. 162628 - 162628
Published: Feb. 6, 2025
Language: Английский
Citations
0Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 688, P. 403 - 410
Published: Feb. 25, 2025
Language: Английский
Citations
0Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125375 - 125375
Published: April 1, 2025
Language: Английский
Citations
0Chemistry of Materials, Journal Year: 2024, Volume and Issue: unknown
Published: Sept. 20, 2024
Language: Английский
Citations
2Journal of Electroanalytical Chemistry, Journal Year: 2024, Volume and Issue: 974, P. 118704 - 118704
Published: Oct. 9, 2024
Language: Английский
Citations
0