Application of Hard and Soft Acid‐base Theory to Construct Heterometallic Materials with Metal‐oxo Clusters DOI
Xiaowei Qi, YuLong Xie, Jingyang Niu

et al.

Angewandte Chemie, Journal Year: 2024, Volume and Issue: 137(1)

Published: Oct. 24, 2024

Abstract Heterometallic cluster‐based materials offer the potential to incorporate multiple functionalities, leveraging aggregation effects of clusters and translating this heterogeneity complexity into unexpected properties that are more than just sum their components. However, rational construction heterometallic remains challenging due metal cation coordination structural unpredictability. This minireview provides insights a general synthetic strategy based on Hard Soft Acids Bases (HSAB) theory, summarizing its advantages in designed synthesis discrete (intracluster assembly) infinite (intercluster assembly). Furthermore, it emphasizes exploit intrinsic mixed components achieve breakthroughs across broad range applications. The from review expected drive progress controllable predictable manner.

Language: Английский

Application of Hard and Soft Acid‐base Theory to Construct Heterometallic Materials with Metal‐oxo Clusters DOI

Xiao Qi,

YuLong Xie, Jingyang Niu

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 64(1)

Published: Oct. 24, 2024

Heterometallic cluster-based materials offer the potential to incorporate multiple functionalities, leveraging aggregation effects of clusters and translating this heterogeneity complexity into unexpected properties that are more than just sum their components. However, rational construction heterometallic remains challenging due metal cation coordination structural unpredictability. This minireview provides insights a general synthetic strategy based on Hard Soft Acids Bases (HSAB) theory, summarizing its advantages in designed synthesis discrete (intracluster assembly) infinite (intercluster assembly). Furthermore, it emphasizes exploit intrinsic mixed components achieve breakthroughs across broad range applications. The from review expected drive progress controllable predictable manner.

Language: Английский

Citations

6
Accurate Thermal Resection of Atomically Precise Copper Clusters to Achieve Near‐IR Light‐Driven CO2 Reduction DOI

Jian‐Peng Dong,

Jun‐Kang Li,

Huan Zhang

et al.

Advanced Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 13, 2025

Abstract Atomically precise copper clusters are desirable as catalysts for elaborating the structure–activity relationships. The challenge, however, lies in their tendency to sinter when protective ligands removed, resulting destruction of structural integrity model system. Herein, a copper‐sulfur‐nitrogen cluster [Cu 8 (S t Bu) 4 (PymS) ] (denoted Cu SN ) is synthesized by using mixed ligand approach with strong chelating 2‐mercaptopyrimidine (PymSH) and relatively weak monodentate tert‐butyl mercaptan ligands. A thermal‐resection strategy applied selectively peel only targeted off, which induces transformation initial into new more stable Cu–S–N (S) 2 SN‐T ). residual bridging S 2− within metal core forms asymmetric Cu‐S species near‐infrared (NIR) response, endows capability full‐spectrum responsive CO photoreduction, achieving ≈100% ‐to‐CO selectivity. Especially NIR‐driven reduction, it has evolution 42.5 µmol g −1 under λ > 780 nm. Importantly, this work represents first NIR light‐responsive efficient photoreduction opens an avenue manipulation structures via novel thermolysis develop unprecedented functionalized materials.

Language: Английский

Citations

0
Synergistic mechanisms of oxygen evolution reaction in atomically precise LaCo6 clusters with distinct geometries DOI
Jianan Chen,

Zhong‐Hua Pan,

Fu-li Sun

et al.

Science China Chemistry, Journal Year: 2025, Volume and Issue: 68(5), P. 1832 - 1836

Published: March 10, 2025

Language: Английский

Citations

0
Cerium oxide cluster modified nickel sulfide/carbon nitride heterostructure for efficient oxygen evolution reaction DOI
Kexin Sun, Qiang Han,

Sicheng Cui

et al.

Journal of Rare Earths, Journal Year: 2025, Volume and Issue: unknown

Published: March 1, 2025

Citations

0
Water-Stable Al3Ni4 Polynuclear Heterometallic Compound for Near-Infrared Photothermal Conversion DOI
Yanyan Gao, Lixing Zhao,

Qingyu Du

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: April 18, 2025

In this paper, a polynuclear heterometallic compound (H3O)[Al3Ni4(OH)6(MBA-NO2)6(H2O)6] (Al3Ni4, H2MBA-NO2 = 2-hydroxy-3-methoxy-5-nitrobenzoic acid) with seven-star disk metal core has been synthesized by the solvothermal method. Al3Ni4 good stability in water and several organic solvents, its solid powder shows photothermal effect under 980 nm laser irradiation, temperature can reach 138.8 °C within 100 s 1.0 W cm-2 power irradiation. Considering effect, evaporation of was measured. It be further used as material seawater evaporation.

Language: Английский

Citations

0
PdO Reinforced CuO/Al2O3 Mesoporous Nanostructures as High‐Efficiency Electrocatalysts for Hydrazine Oxidation Reaction (HzOR) DOI
Safia Khan, Ifzan Arshad, Saima Aftab

et al.

ChemistrySelect, Journal Year: 2024, Volume and Issue: 9(33)

Published: Aug. 30, 2024

Abstract Direct hydrazine fuel cells (DHFC) insist on the evolved and persistent electrocatalysts for anodic oxidation reaction (HzOR). Herein, PdO promoted CuO heterostructures supported γ‐Al 2 O 3 are depicted as efficient HzOR. is prepared by precipitation method while metal precursors incorporated co‐impregnation technique. Physiochemically characterized PdO‐CuO/Al mesoporous composites displayed large electrochemical active surface area (ECSA) i. e ., 0.18 cm , high current density ( j ) 35.7 mA −2 larger diffusion coefficient (D°) 29.3×10 −4 (cm s −1 ), apparent rate constant (k app 13.2 with low charge transfer resistance (R ct 3.6 kΩ shown best catalyst 1 % . Cyclic voltammetry indicated that fabricated working electrodes offer efficiency towards HzOR in alkaline medium such a way produced 600 times higher than CuO/Al composite. Owing to stability reproducibility, modified would achieve huge catalytic significance multiple reactions economic ecological benefits.

Language: Английский

Citations

0
Application of Hard and Soft Acid‐base Theory to Construct Heterometallic Materials with Metal‐oxo Clusters DOI
Xiaowei Qi, YuLong Xie, Jingyang Niu

et al.

Angewandte Chemie, Journal Year: 2024, Volume and Issue: 137(1)

Published: Oct. 24, 2024

Abstract Heterometallic cluster‐based materials offer the potential to incorporate multiple functionalities, leveraging aggregation effects of clusters and translating this heterogeneity complexity into unexpected properties that are more than just sum their components. However, rational construction heterometallic remains challenging due metal cation coordination structural unpredictability. This minireview provides insights a general synthetic strategy based on Hard Soft Acids Bases (HSAB) theory, summarizing its advantages in designed synthesis discrete (intracluster assembly) infinite (intercluster assembly). Furthermore, it emphasizes exploit intrinsic mixed components achieve breakthroughs across broad range applications. The from review expected drive progress controllable predictable manner.

Language: Английский

Citations

0