Extrusion‐Based Printing of Nanostructured Fatty Acid Gels Incorporated in Hydrogels DOI
Saba Amirfattahi,

Christine Freeman,

Houman Honaryar

et al.

Journal of Applied Polymer Science, Journal Year: 2025, Volume and Issue: unknown

Published: May 19, 2025

ABSTRACT Soft materials with unique nanostructures such as lamellar, hexagonal, and cubic morphologies can replicate complex structures that have potential in various fields, including biomedical industrial applications. However, a key challenge advancing the broader applications of 3D printing for these nanostructured soft is insufficient mechanical properties hinder their printability compromise structural stability final product. In this study, suitability fatty acid‐based lamellar gel evaluated direct extrusion‐based printing. The varying water content integrated photocurable hydrogel to preserve shape prints. Complex 2D design patterns are used assess extrusion behavior, stability, print precision under pressures. Small‐angle X‐ray Scattering (SAXS) measurements reveal formation confirm retention after photocuring gels. Rheological analysis confirms gels exhibit suitable printing, shear‐thinning behavior. Additionally, tensile testing conducted evaluate across cured samples. This study underscores robust versatile platform, facilitating development engineered

Language: Английский

Comparison of Hydrogen Bonded Organic Framework with Reduced Graphene Oxide-Pd Based Nanocatalyst: Which One Is More Efficient for Entrapment of Nitrophenol Pollutants? DOI

Ladan Alehosein,

S. Jafar Hoseini, Mehrangiz Bahrami

et al.

Langmuir, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 29, 2025

In this study, a Pd nanoparticles@hydrogen-bonded organic framework (Pd NPs@HOF) thin film was fabricated at the toluene-water interface. The HOF formed through interaction of trimesic acid (TMA) and melamine (Mel) in water phase, while Pd(0) produced from reduction [PdCl2(cod)] phase. as-synthesized NPs@HOF demonstrated to be an effective catalyst for selective p-nitrophenol o-nitrophenol p-aminophenol o-aminophenol. porous network introduced strong active sites between Mel, TMA, Pd(0). Kinetic studies showed that exhibited enhanced rate comparison with Pd@reduced-graphene oxide (r-GO) rates were 1.7 times faster 1.5 or even 10 than some Pd-based catalysts, maximum conversion 97.1% which attributed higher porosity greater surface-to-volume ratio material. Furthermore, π-π stacking interactions enhance catalytic activity by increasing sites, stabilizing NPs trapping nitrophenols, facilitating electron transfer, providing synergistic effect. Also, contributions hydrogen bonding, van der Waals forces, electrostatic interactions, π-σ noncovalent are reasons better performance Pd/r-GO reduced functional groups.

Language: Английский

Citations

3
Stabilizing Bicontinuous Particle-Stabilized Emulsions formed via Solvent Transfer-Induced Phase Separation DOI Creative Commons

Meyer T. Alting,

Martin F. Haase

Soft Matter, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Bijels are non-equilibrium soft materials with potential applications in catalysis, membrane separations, and energy storage. In this study, we demonstrate the long-term stabilization of STrIPS-bijels, maintaining their structure for several weeks.

Language: Английский

Citations

0
Extrusion‐Based Printing of Nanostructured Fatty Acid Gels Incorporated in Hydrogels DOI
Saba Amirfattahi,

Christine Freeman,

Houman Honaryar

et al.

Journal of Applied Polymer Science, Journal Year: 2025, Volume and Issue: unknown

Published: May 19, 2025

ABSTRACT Soft materials with unique nanostructures such as lamellar, hexagonal, and cubic morphologies can replicate complex structures that have potential in various fields, including biomedical industrial applications. However, a key challenge advancing the broader applications of 3D printing for these nanostructured soft is insufficient mechanical properties hinder their printability compromise structural stability final product. In this study, suitability fatty acid‐based lamellar gel evaluated direct extrusion‐based printing. The varying water content integrated photocurable hydrogel to preserve shape prints. Complex 2D design patterns are used assess extrusion behavior, stability, print precision under pressures. Small‐angle X‐ray Scattering (SAXS) measurements reveal formation confirm retention after photocuring gels. Rheological analysis confirms gels exhibit suitable printing, shear‐thinning behavior. Additionally, tensile testing conducted evaluate across cured samples. This study underscores robust versatile platform, facilitating development engineered

Language: Английский

Citations

0