Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 142462 - 142462
Published: April 1, 2025
Language: Английский
Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 142462 - 142462
Published: April 1, 2025
Language: Английский
Electrochimica Acta, Journal Year: 2025, Volume and Issue: unknown, P. 145637 - 145637
Published: Jan. 1, 2025
Language: Английский
Citations
0Small, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 3, 2025
Abstract Environmental‐friendly aqueous Zn−CO 2 batteries present bifunctional potentials of achieving carbon neutrality and energy storage. Nonetheless, anode corrosions derived from H O molecules high risks volatilization leakage hinder the advancement batteries. In this work, polyvinyl alcohol (PVA)‐based hydrogel electrolyte with fast ion diffusion kinetics, mechanical strength, flexibility is developed to replace liquid electrolyte. Since hydroxyl radicals in polymer chain can interact Zn 2+ , electrode corrosion free active around significantly inhibited, facilitating uniform deposition cations. The introduction an ionic plasticizer further enhances interaction between backbone, as well amorphous extent possesses adequate self‐healing ability, whose conductivity reaches 7.95 × 10 −3 S cm −1 . symmetric metal containing remain steady for >2000 h under different current densities. Furthermore, battery based on Ru nanoparticles cathode realizes a discharge capacity 6028 mAh g stable cyclicity 90 times. reaction path electrolyte‐based that CO reduced ZnCO 3 C species followed by reversible decomposition products recharge.
Language: Английский
Citations
0Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: 368, P. 125133 - 125133
Published: Feb. 6, 2025
Language: Английский
Citations
0Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown
Published: March 4, 2025
Abstract Constructing high‐efficiency platinum (Pt)‐based catalysts for methanol oxidation reaction (MOR) by suppressing the intermediate CO ads generation is strongly desired and remains a grand challenge. Herein, concept of holding O‐bridged triple sites documented to strengthen “non‐CO” pathway selectivity forming HCOO − species during MOR. The obtained Ga‐O‐PtPd via grafting single‐atomic Ga on PtPd nanosheets achieves high current density 3.05 mAcm −2 MOR, which 5.65 times higher than commercial Pt/C (0.54 ), as well remarkably stability poison resistance. diffuse reflectance infrared Fourier transform spectroscopy (CO‐DRIFTS) results reveal that present weak binding ability, reducing intermediate. In addition, Ga‐O‐PtPd‐based Zn‐methanol‐air batteries an excellent activity compared with catalysts.
Language: Английский
Citations
0Energy & Fuels, Journal Year: 2025, Volume and Issue: unknown
Published: March 18, 2025
Language: Английский
Citations
0Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 161736 - 161736
Published: March 1, 2025
Language: Английский
Citations
0Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 142462 - 142462
Published: April 1, 2025
Language: Английский
Citations
0